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Synthesis and characterization of low cost willemite based glass–ceramic for opto-electronic applications

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Abstract

This paper presents a comprehensive study on thermal, structural and optical properties of novel willemite glass–ceramics. The precursor glass in the ZnO–SLS glass system was successfully prepared using conventional melt-quenching technique and willemite (Zn2SiO4) glass–ceramics were derived from this precursor glass by a control crystallization process. The effect of heat-treatment temperature on the phase transformation, morphology and size of Zn2SiO4 crystal phase was examined using X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM) techniques. Furthermore, fourier transform infrared reflection (FTIR) spectroscopy was used to evaluate the Zn2SiO4 crystal structural evolution. The average size of Zn2SiO4 crystallite obtained from calculation of XRD is found to be in the range 30–60 nm, whereas the grain size observed in FESEM is in range of 200–400 nm. The appearance of SiO2, ZnO4 and Zn–O–Si bands detected from FTIR indicate the formation of Zn2SiO4 crystal phase. Besides, the study of the optical band gap has found that optical band gap of the glass–ceramics decreased as the heat treatment temperature increased. The photoluminescence spectra of willemite glass–ceramics exhibit two different emissions around 525 nm (green) and 585 nm (yellow); exhibit a characteristic of broad absorption band around 260 nm. These two different spectra reveal that the luminescence performance of the willemite glass–ceramics was enhanced with the progression of heat treatment temperature due to different located energy levels of the β-Zn2SiO4 and α-Zn2SiO4 crystalline phase. Such luminescent glass–ceramics was expected to find potential applications in phosphors and opto-electronic devices.

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References

  1. E. Bernardo, L. Esposito, E. Rambaldi, A. Tucci, S. Hreglich, Recycle of waste glass into “glass–ceramic stoneware”. J. Am. Ceram. Soc. 91(7), 2156–2162 (2008)

    Article  Google Scholar 

  2. M. Takesue, H. Hayashi, R.L. Smith, Thermal and chemical methods for producing zinc silicate (willemite): a review. Prog. Cryst. Growth Charact. Mater. 55(3), 98–124 (2009)

    Article  Google Scholar 

  3. I.P. Sahu, D.P. Bisen, N. Brahme, R.K. Tamrakar, Studies on the luminescence behavior of SrCaMgSi2O7: Eu3+ phosphor by solid state reaction method. J. Mater. Sci.: Mater. Electron. 27(2), 1828–1839 (2016)

    Google Scholar 

  4. E. Yousef, M. Hotzel, C. Rüssel, Effect of ZnO and Bi2O3 addition on linear and non-linear optical properties of tellurite glasses. J. Non-Cryst. Solids 353(4), 333–338 (2007)

    Article  Google Scholar 

  5. S. Rosmawati, H.A.A. Sidek, A.T. Zainal, H. Mohd Zobir, Effect of zinc on the physical properties of tellurite glass. J. Appl. Sci. 8, 1956–1961 (2008)

    Article  Google Scholar 

  6. H.A. Abo-Mosallam, H. Darwish, S.M. Salman, Crystallization characteristic and properties of some zinc containing soda lime silicate glasses. J. Mater. Sci.: Mater. Electron. 21(9), 889–896 (2010)

    Google Scholar 

  7. A. Tarafder, A.R. Molla, C. Dey, B. Karmakar, Thermal, structural, and enhanced photoluminescence properties of Eu3+-doped transparent willemite glass–ceramic nanocomposites. J. Am. Ceram. Soc. 96(8), 2424–2431 (2013)

    Article  Google Scholar 

  8. Y. Yu, Y. Wang, D. Chen, P. Huang, E. Ma, F. Bao, Enhanced emissions of Eu3+ by energy transfer from ZnO quantum dots embedded in SiO2 glass. Nanotechnology 19(5), 1–5 (2008)

    Article  Google Scholar 

  9. L. Hou, G. Zuo, Y. Shen, Y. Meng, H. Li, Effects of the replacing content of ZnBr2 on the properties of ZnO–B2O3–SiO2:Mn2+ glass–ceramics. Ceram. Int. 40(8), 13097–13103 (2014)

    Article  Google Scholar 

  10. A.R. Boccaccini, M. Bücker, J. Bossert, K. Marszalek, Glass matrix composites from coal fly ash and waste glass. Waste Manag 17(1), 39–45 (1997)

    Article  Google Scholar 

  11. L. Barbieri, A.C. Bonamartini, I. Lancellotti, Alkaline and alkaline-earth silicate glasses and glass–ceramics from municipal and industrial wastes. J. Eur. Ceram. Soc. 20(14), 2477–2483 (2000)

    Article  Google Scholar 

  12. R.D. Rawlings, J.P. Wu, A.R. Boccaccini, Glass–ceramics: their production from wastes-a review. J. Mater. Sci. 41(3), 733–761 (2006)

    Article  Google Scholar 

  13. S.M. Salman, S.N. Salama, E.A. Mahdy, The effect of strontium oxide replacing calcium oxide on the crystallization and thermal expansion properties of Li2O–CaO–SiO2 glasses. Ceram. Int. 41(1), 137–143 (2015)

    Article  Google Scholar 

  14. J. Sheng, K. Kadono, Y. Utagawa, T. Yazawa, X-ray irradiation on the soda-lime container glass. Appl. Radiat. Isot. 56(4), 621–626 (2002)

    Article  Google Scholar 

  15. E.D. Zanotto, Surface crystallization kinetics in soda-lime-silica glasses. J. Non-Cryst. Solids 129(1), 183–190 (1991)

    Article  Google Scholar 

  16. S. Petrescu, M. Constantinescu, E.M. Anghel, I. Atkinson, M. Olteanu, M. Zaharescu, Structural and physico-chemical characterization of some soda lime zinc alumino-silicate glasses. J. Non-Cryst. Solids 358(23), 3280–3288 (2012)

    Article  Google Scholar 

  17. N. Marinoni, D. D’Alessio, V. Diella, A. Pavese, F. Francescon, Effects of soda-lime-silica waste glass on mullite formation kinetics and micro-structures development in vitreous ceramics. J. Environ. Manag. 124, 100–107 (2013)

    Article  Google Scholar 

  18. B.E. Yekta, P. Alizadeh, L. Rezazadeh, Synthesis of glass–ceramic glazes in the ZnO–Al2O3–SiO2–ZrO2 system. J. Eur. Ceram. Soc. 27(5), 2311–2315 (2007)

    Article  Google Scholar 

  19. A. Tarafder, A.R. Molla, S. Mukhopadhyay, B. Karmakar, Fabrication and enhanced photoluminescence properties of Sm3+-doped ZnO–Al2O3–B2O3–SiO2 glass derived willemite glass–ceramic nanocomposites. Opt. Mater. 36(9), 1463–1470 (2014)

    Article  Google Scholar 

  20. G.Q. Xu, H.T. Xu, Z.X. Zheng, Y.C. Wu, Preparation and characterization of Zn2SiO4:Mn phosphors with hydrothermal methods. J. Lumin. 130(10), 1717–1720 (2010)

    Article  Google Scholar 

  21. M. Takesue, H. Hayashi, R.L. Smith, Thermal and chemical methods for producing zinc silicate (willemite): a review. Prog. Cryst. Growth Charact. Mater. 55(3), 98–124 (2009)

    Article  Google Scholar 

  22. V. Sivakumar, A. Lakshmanan, S. Kalpana, R.S. Rani, R.S. Kumar, M.T. Jose, Low-temperature synthesis of Zn2SiO4:Mn green photoluminescence phosphor. J. Lumin. 132(8), 1917–1920 (2012)

    Article  Google Scholar 

  23. K. Omri, J. El Ghoul, A. Alyamani, C. Barthou, L. El Mir, Luminescence properties of green emission of SiO2/Zn2SiO4:Mn nanocomposite prepared by sol–gel method. Phys. E 53, 48–54 (2013)

    Article  Google Scholar 

  24. Y.C. Kang, I.W. Lenggoro, S.B. Park, K. Okuyama, Photoluminescence characteristics of YAG: Tb phosphor particles with spherical morphology and non-aggregation. J. Phys. Chem. Solids 60(11), 1855–1858 (1999)

    Article  Google Scholar 

  25. R. Stefan, E. Culea, P. Pascuta, The effect of copper ions addition on structural and optical properties of zinc borate glasses. J. Non-Cryst. Solids 358(4), 839–846 (2012)

    Article  Google Scholar 

  26. E.M.A. Khalil, F.H. El Batal, Y.M. Hamdy, H.M. Zidan, M.S. Aziz, A.M. Abdelghany, Infrared absorption spectra of transition metals-doped soda lime silica glasses. Phys. B 405(5), 1294–1300 (2010)

    Article  Google Scholar 

  27. J. Williamson, F.P. Glasser, Crystallisation of zinc silicate liquids and glasses. Phys. Chem. Glasses 5(1), 52–59 (1964)

    Google Scholar 

  28. H. Yang, R.M. Hazen, R.T. Downs, L.W. Finger, Structural change associated with the incommensurate-normal phase transition in akermanite, Ca2MgSi2O7, at high pressure. Phys. Chem. Miner. 24(7), 510–519 (1997)

    Article  Google Scholar 

  29. A.R. Molla, A. Tarafder, B. Karmakar, Synthesis and properties of glasses in the K2O–SiO2–Bi2O3–TiO2 system and bismuth titanate (Bi4Ti3O12) nano glass–ceramics thereof. J. Mater. Sci. 46(9), 2967–2976 (2011)

    Article  Google Scholar 

  30. R. Casasola, J.M. Rincón, M. Romero, Glass–ceramic glazes for ceramic tiles: a review. J. Mater. Sci. 47(2), 553–582 (2012)

    Article  Google Scholar 

  31. N.F. Syamimi, K.A. Matori, W.F. Lim, H.A.A. Sidek, M.H.M. Zaid, Effect of sintering temperature on structural and morphological properties of europium (III) oxide doped willemite. J. Spectrosc. 2014(1), 1–7 (2014)

    Article  Google Scholar 

  32. G.V. Sarrigani, K.A. Matori, W.F. Lim, A. Kharazmi, H.J. Quah, H.R. Bahari, M. Hashim, Structural and optical properties of erbium-doped willemite-based glass–ceramics. Appl. Opt. 54(33), 9925–9929 (2015)

    Article  Google Scholar 

  33. N.A.S. Omar, Y.W. Fen, K.A. Matori, M.H.M. Zaid, M.R. Norhafizah, M. Nurzilla, M.I.M. Zamratul, Synthesis and optical properties of europium doped zinc silicate prepared using low cost solid state reaction method. J. Mater. Sci.: Mater. Electron. 27(2), 1092–1099 (2015)

    Google Scholar 

  34. L. Barbieri, C. Leonelli, T. Manfredini, C. Siligardi, A.B. Corradi, P. Mustarelli, C. Tomasi, Nucleation and crystallization of a lithium aluminosilicate glass. J. Am. Ceram. Soc. 80(12), 3077–3083 (1997)

    Article  Google Scholar 

  35. C.C. Lin, P. Shen, Sol-gel synthesis of zinc orthosilicate. J. Non-Cryst. Solids 171(3), 281–289 (1994)

    Article  Google Scholar 

  36. P.T. Chao, P. Shen, C.C. Lin, Thermal cycle etching of willemite (0001): effects of surface premelting, dislocation outcrops and polygonization. Mater. Sci. Eng. A 335(1), 191–197 (2002)

    Article  Google Scholar 

  37. A. Tarafder, A.R. Molla, C. Dey, B. Karmakar, Thermal, structural, and enhanced photoluminescence properties of Eu3+-doped transparent willemite glass–ceramic nanocomposites. J. Am. Ceram. Soc. 96(8), 2424–2431 (2013)

    Article  Google Scholar 

  38. Z.Y. Li, Z.Q. Zhang, Fragility of photonic band gaps in inverse-opal photonic crystals. Phys. Rev. B 62(3), 1516–1519 (2000)

    Article  Google Scholar 

  39. L.S. El-Deen, M.S. Al Salhi, M.M. Elkholy, IR and UV spectral studies for rare earths-doped tellurite glasses. J. Alloys Compd. 465(1), 333–339 (2008)

    Article  Google Scholar 

  40. P.G. Pavani, K. Sadhana, V.C. Mouli, Optical, physical and structural studies of boro-zinc tellurite glasses. Phys. B 406(6), 1242–1247 (2011)

    Article  Google Scholar 

  41. F. El-Diasty, F.A.A. Wahab, M. Abdel-Baki, Optical band gap studies on lithium aluminum silicate glasses doped with Cr3+ ions. J. Appl. Phys. 100(9), 1–7 (2006)

    Article  Google Scholar 

  42. V. Madhuri, J.S. Kumar, M.S. Rao, S. Cole, Investigations on spectral features of tungsten ions in sodium lead alumino borate glass system. J. Phys. Chem. Solids 78, 70–77 (2015)

    Article  Google Scholar 

  43. S. Hasegawa, M. Kitagawa, Effects of annealing on localized states in amorphous Ge films. Solid State Commun. 27(9), 855–858 (1978)

    Article  Google Scholar 

  44. R.S. Chakradhar, B.M. Nagabhushana, G.T. Chandrappa, K.P. Ramesh, J.L. Rao, Solution combustion derived nanocrystalline Zn2SiO4:Mn phosphors: a spectroscopic view. J. Chem. Phys. 121(20), 10250–10259 (2004)

    Article  Google Scholar 

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Acknowledgments

The researchers gratefully acknowledge the financial support for this study from the Malaysian Ministry of Higher Education (MOHE) and Universiti Putra Malaysia through the Fundamental Research Grant Scheme (FRGS) and Inisiatif Putra Berkumpulan (IPB) research grant.

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Authors and Affiliations

  1. Department of Physics, Faculty of Science, Universiti Putra Malaysia, 43400, Serdang, Selangor, Malaysia

    Mohd Hafiz Mohd Zaid, Khamirul Amin Matori, Sidek Hj. Abdul Aziz, Halimah Mohamed Kamari, Zaidan Abdul Wahab & Yap Wing Fen

  2. Materials Synthesis and Characterization Laboratory, Institute of Advanced Technology, Universiti Putra Malaysia, 43400, Serdang, Selangor, Malaysia

    Khamirul Amin Matori & Ibrahim Mustapha Alibe

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  1. Mohd Hafiz Mohd Zaid
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Zaid, M.H.M., Matori, K.A., Abdul Aziz, S.H. et al. Synthesis and characterization of low cost willemite based glass–ceramic for opto-electronic applications. J Mater Sci: Mater Electron 27, 11158–11167 (2016). https://doi.org/10.1007/s10854-016-5234-6

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