Abstract
Optically active helical polyurea@attapulgite (HPUA@ATP) composites were prepared after the surface modification of the rod-like attapulgite (ATP). Composites were characterized by Fourier-transform infrared spectroscopy, X-ray diffraction and thermogravimetric analysis. The results indicate that the helical polyureas have been successfully grafted onto the surfaces of the modified ATP (A-ATP) without destroying the original crystalline structure of ATP. The rod-like nanoparticles were confirmed by transmission electron microscopy. The dielectric constant and infrared emissivity have been investigated, and the results indicate that the dielectric constant value of HPUA@ATP composite has been increased to 33.62 from 25.35 (the value of bare ATP), while the infrared emissivity value of HPUA@ATP composite has been reduced to 0.39 from 0.93 (the value of bare ATP), due to the interfacial interactions between organics and inorganics and the ordered stereostructures of optically active helical polymers.
Similar content being viewed by others
References
I.M. Reaney et al., J. Am. Ceram. Soc. 89, 2063–2072 (2006)
D. Maurya et al., Sci. Rep. 5, 15144 (2015). doi:10.1038/srep15144
N.D. Orloff et al., Sci. Rep. 5, 17019 (2015). doi:10.1038/srep17019
T. Rojac, M. Kosec, D. Damjanovic, J. Am. Ceram. Soc. 94, 4108–4111 (2011)
H.A. Avila, L.A. Ramajo, M.S. Goes, M.M. Reboredo, M.S. Castro, R. Parra, ACS Appl. Mater. Interfaces 5, 505–510 (2013)
Q. Wang, L. Zhu, J. Polym. Sci. Part B Polym. Phys. 49, 1421–1429 (2011)
J. Li, S. Seok, B. Chu, F. Dogan, Q. Zhang, Q. Wang, Adv. Mater. 21, 217–221 (2009)
Z.M. Dang, J.K. Yuan, J.W. Zha, T. Zhou, S.T. Li, G.H. Hu, Prog. Mater. Sci. 57, 660–723 (2012)
F. Wen, Z. Xu, W.M. Xia, X.Y. Wei, Z.C. Zhang, Polym. Eng. Sci. 53, 897–904 (2013)
C.W. Beier, J.M. Sanders, R.L. Brutchey, J. Phys. Chem. C 117, 6958–6965 (2013)
S.P. Mahulikar, H.R. Sonawane, G.A. Rao, Prog. Aerosp. Sci. 43, 218–245 (2007)
P.K. Biswas et al., Mater. Lett. 57, 2326–2332 (2003)
B. Lin, J. Tang, H. Liu, Y. Sun, C. Yuan, J. Solid State Chem. 78, 650–654 (2005)
B. Lin, H. Liu, S. Zhang, C. Yuan, J. Solid State Chem. 177, 3849–3852 (2004)
J. Yi, X. He, Y. Sun, Y. Li, M. Li, Appl. Surf. Sci. 253, 7100–7103 (2007)
S. Zulfiqar, A. Kausar, M. Rizwan, M.I. Sarwar, Appl. Surf. Sci. 255, 2080–2086 (2008)
P. Fardim, B. Holmbom, Appl. Surf. Sci. 249, 393–407 (2005)
Y. Song, Y. Yao, C. Chen, K. Cui, L. Wang, Appl. Surf. Sci. 254, 3306–3312 (2008)
L. Wang, J. Sheng, Polymer 46, 6243–6249 (2005)
M. Ren et al., Appl. Surf. Sci. 254, 7314–7320 (2008)
E.H. Smith, T. Vengris, Crit. Rev. Anal. Chem. 28, 13–18 (1998)
J.J. Li, P. Khanchaitit, K. Han, Q. Wang, Chem. Mater. 22, 5350–5357 (2010)
A. Maliakal, H. Katz, P. Cotts, S. Subramoney, P. Mirau, J. Am. Chem. Soc. 127, 14655–14662 (2005)
Y. Song, Y. Shen, H.Y. Liu, Y.H. Lin, M. Li, C.W. Nan, J. Mater. Chem. 22, 16491–16498 (2012)
J. Chon, S. Ye, K.J. Cha, S.C. Lee, Y.S. Koo, J.H. Jung, Y.K. Kwon, Chem. Mater. 22, 5445–5452 (2010)
J. Li, J. Claude, L. Norena-Franco, S. Seok, Q. Wang, Chem. Mater. 20, 6304–6306 (2008)
D.N. McCarthy, H. Stoyanov, D. Rychkov, H. Ragusch, M. Melzer, G. Kofod, Compos. Sci. Technol. 72, 731–736 (2012)
K. Yang, X.Y. Huang, L.Y. Xie, C. Wu, P.K. Jiang, T. Tanaka, Macromol. Rapid Commun. 33, 1921–1926 (2012)
M.N. Tchoul, S.P. Fillery, H. Koerner, L.F. Drummy, F.T. Oyerokun, P.A. Mirau, M.F. Durstock, R.A. Vaia, Chem. Mater. 22, 1749–1759 (2010)
B. Balasubramanian, K. Kraemer, N. Reding, R. Skomski, S. Ducharme, D. Sellmyer, ACS Nano 4, 1893–1900 (2010)
K. Yang, X. Huang, Y. Huang, L. Xie, P. Jiang, Chem. Mater. 25, 2327–2338 (2013)
L.T. Vo, S.H. Anastasiadis, E.P. Giannelis, Macromolecules 44, 6162–6171 (2011)
H.B. Bradl, Colloid Interface Sci. 277, 1–18 (2004)
S.S. Gupta, K.G. Bhattacharyya, Colloid Interface Sci. 295, 21–32 (2006)
S.V. Vinogradov, T.K. Bronich, A.V. Kabanov, Adv. Drug Deliv. Rev. 54, 135–147 (2002)
R.X. Zhao, P. Torley, P.J. Halley, J. Mater. Sci. 43, 3058–3071 (2008)
P. Kim et al., ACS Nano 3, 2581–2592 (2009)
W. Yan, Z.J. Han, B.T. Phung, K. Ostrikov, ACS Appl. Mater. Interfaces 4, 2637–2642 (2012)
H. Takele et al., Eur. Phys. J. Appl. Phys. 33, 83–89 (2006)
J. Cao, N.F. Yang, J.C. Li, L.W. Yang, Polym. Bull. 59, 481–490 (2007)
G.L. Yuan, F. Zou, S. Yin, N. Kuramoto, Polym. Bull. 61, 705–711 (2008)
R. Nishiyabu, P. Anzenbacher Jr., J. Am. Chem. Soc. 127, 8270–8271 (2005)
A. Buryak, K. Severin, J. Am. Chem. Soc. 127, 3700–3701 (2005)
Y. Liu, P. Liu, Z. Su, Synth. Met. 157, 585–591 (2007)
J.P. Zhang, Q. Wang, A.Q. Wang, Carbohydr. Polym. 68, 367–374 (2007)
P. Liu, J.S. Guo, Colloids Surf. A Physicochem. Eng. Asp. 282, 498–503 (2006)
P. Liu, T. Wang, Ind. Eng. Chem. Res. 46, 97–102 (2007)
N. Guo, S.A. DiBenedetto, P. Tewari, M.T. Lanagan, M.A. Ratner, T.J. Marks, Chem. Mater. 22, 1567–1578 (2010)
Z. Li, L.A. Fredin, P. Tewari, S.A. DiBenedetto, M.T. Lanagan, M.A. Ratner, T.J. Marks, Chem. Mater. 22, 5154–5164 (2010)
Y. Shen, Y.H. Lin, M. Li, C.W. Nan, Adv. Mater. 19, 1418–1422 (2007)
H.M. Jung, J.H. Kang, S.Y. Yang, J.C. Won, Y.S. Kim, Chem. Mater. 22, 450–456 (2010)
Acknowledgments
The authors are grateful to the National Nature Science Foundation of China (21104037), Natural Science Foundation of Zhejiang (Y4110586), Natural Science Foundation of Ningbo (2013A610014) and Scientific research project of Zhejiang Education Department (Y201016076).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wang, Z., Wang, B. & Xu, Z. Optically active helical polyurea@attapulgite composites with high dielectric constant and low infrared emissivity. J Mater Sci: Mater Electron 27, 10276–10281 (2016). https://doi.org/10.1007/s10854-016-5109-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-016-5109-x