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Dielectric properties of manganese-doped TiO2 with different alkali-free glass contents for energy storage application

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Abstract

The dielectric properties and microstructures of 0.05 mol% manganese (Mn)-doped TiO2 with different alkali-free glass (BaO–B2O3–Al2O3–SiO2) contents were investigated. The alkali-free glass which coated Mn-doped TiO2 ceramic powders was prepared by sol–gel method, all samples were sintered at 1100 °C for 6 h. Microstructure observation indicated that the grain size greatly reduced and microstructure uniformity was improved by adding 15 wt% alkali-free glass. The alkali-free glass did not only decrease the dielectric loss (<0.01), but also significantly enhanced the frequency/temperature stability of dielectric properties. The energy density of 15 wt% glass–ceramics could achieve 1.15 J/cc with average breakdown electric field (Eb) of 50.17 kV/mm, the polarization–electric field (P–E) hysteresis loops showed that glass–ceramic composites had a very low energy loss.

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Acknowledgments

The research work was supported by the State Key Program of National Natural Science of China (Grant Nos. 50932002 and 51172035).

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Authors and Affiliations

  1. State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, People’s Republic of China

    Jianfeng Liu, Jihua Zhang, Meng Wei, Zongying Yao, Hongwei Chen & Chuanren Yang

  2. Collaboration Innovation Center of Electric Materials and Devices, University of Electronic Science and Technology of China, Chengdu, 610054, Sichuan, People’s Republic of China

    Jianfeng Liu, Jihua Zhang, Meng Wei, Zongying Yao, Hongwei Chen & Chuanren Yang

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  1. Jianfeng Liu
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  2. Jihua Zhang
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Correspondence to Jihua Zhang.

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Liu, J., Zhang, J., Wei, M. et al. Dielectric properties of manganese-doped TiO2 with different alkali-free glass contents for energy storage application. J Mater Sci: Mater Electron 27, 7680–7684 (2016). https://doi.org/10.1007/s10854-016-4753-5

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