Abstract
ZnS and transition metal (Mn and Ni) doped ZnS were synthesized by a simple chemical method using alkyl hydroxyl ethyl dimethyl ammonium chloride (HY) as capping agent. The structural and optical properties were studied using various techniques. FTIR and X-ray diffraction (XRD) can be used to identify the chemical bonding and crystal structure. The XRD analysis show that the particles are in cubic structure. The mean size of the nanoparticles calculated through Scherrer equation is in the range of 5–2.5 nm. Elemental dispersive analysis of doped samples reveals the presence of doping ions. The transmission electron microscopic studies show that the synthesized particles are in spherical shape. Optical characterization of both undoped and doped samples was carried out by ultraviolet–visible and photoluminescence spectroscopy. The absorption spectra of all the samples are blue shifted from the bulk ZnS.
Similar content being viewed by others
References
J.M. Hwang, M.O. Oh, I. Kim, J.K. Lee, C.S. Ha, Curr. Appl. Phys. 5, 31–34 (2005)
T. Yamamoto, S. Kishimoto, S. Iida, Phys. B 308, 916–919 (2001)
M. Wang, L. Sun, X. Fu, C. Liao, C. Yan, Solid State Comm. 115, 493 (2000)
A.A. Bol, J. Ferwerda, J.A. Bergwerff, A. Meijerink, J. Lumin. 99, 325–334 (2002)
R. Sharma, H.S. Bhatti, Nanotechnology 18, 465703 (2007)
H. Soni, M. Chawda, D. Bodas, Mater. Lett. 63, 767 (2009)
A.A. Bol, R. Beek, A. Meijerink, Chem. Mater. 14, 1121 (2002)
P. Yang, M. Lu, D. Xu, D. Yuan, J. Chang, G. Zhou, M. Pan, Appl. Phys. A74, 257–259 (2002)
C.S. Pathak, M.K. Mandal, Optoelectron. Adv. Mater. Rapid Commun. 5(3), 211–214 (2011)
E. Ivanov, C. Suryanarayana, J. Mater. Synth. Process. 8(3/4), 235–244 (2000)
P. Balaz, P. Pourghahramani, E. Dutkova, E. Turianicova, J. Kovac, A. Satka, Phys. Status Solidi (C) 5(12), 3756–3758 (2008)
T.T.Q. Hoa, N.D. The, S. McVitie, N.H. Nam, L.V. Vu, T.D. Canh, N.N. Long, Opt. Mater. 33, 308–314 (2011)
M.W. Wang, L.D. Sun, C.H. Liu, C.S. Liao, C.H. Yan, Chin. J. Lumin. 20(3), 247 (1999)
Y. Tong, Z. Jiang, C. Wang, Y. Xin, Z. Huang, S. Liu, C. Li, Mater. Lett. 62, 3385–3387 (2008)
J.F. Xu, H.S. Jiw, Y.W. Tang Du, Appl. Phys. A66, 639 (1998)
N. Murase, R. Jagannathar, Y. Kanematsu, M. Watanable, A. Kurita, K. Hirata, T. Yazawa, T. Kushida, J. Phys. Chem. B 103, 754 (1999)
L.X. Cao, J.H. Zhang, S.L. Ren, S.H. Huang, Appl. Phys. Lett. 80(23), 4300 (2002)
D. Jiang, L. Cao, G. Su, H. Qu, D. Sun, Appl. Surf. Sci. 253, 9330–9335 (2007)
R. Yousefi, A.K. Zak, Mater. Sci. Semicond. Process. 14, 170–174 (2011)
R. Yousefi, M.R. Muhamad, A.K. Zak, Curr. Appl. Phys. 11, 767–770 (2011)
S. Sapra, J. Nanda, A. Anan, S.V. Bhat, D.D. Sarma, J. Nanosci. Nanotech. 3, 392 (2003)
B. Bhattacharjee, D. Ganguli, K. Iakoubovskii, A. Stesmans, S. Chaudhuri, Bull Mater. Sci. 25, 175 (2002)
J.K. Salem, T.M. Hammad, M.A. Draaz, S. Kuhn, R. Hempelmann, J. Mater. Sci. Mater. Electron. 25, 2177 (2014)
H.R. Pouretedal, M.H. Keshavarz, J. Alloys Compd. 501, 130–135 (2010)
O. Khani, H.R. Rajabi, M.H. Yousefi, A.A. Khosravi, M. Jannesari, M. Shamsipur, Spectrochim. Acta A 79, 361–369 (2011)
H.R. Pouretedal, M.H. Keshavarz, M.H. Yosefi, A. Shokrollahi, A. Zali, Iran. J. Chem. Chem. Eng. 28, 13–19 (2009)
Rajesh Sharma, H.S. Bhatti, Nanotechnology 18, 465703 (2007)
A.K. Keshari, M. Kumar, P.K. Singh, A.C. Pandey, J. Nanosci. Nanotechnol. 8, 1221 (2008)
K. Sooklal, B.S. Cullum, S.M. Angel, C.J. Murphy, J. Phys. Chem. 100, 4551 (1996)
R. Sethi, L. Kumar, A.C. Pandey, J. Nanosci. Nanotechnol. 9, 5329 (2009)
R.N. Bhargava, D. Gallagher, Phys. Rev. Lett. 72, 416 (1994)
P. Yang, M.K. Lhu, D. Xu, D. Yuan, J. Chang, G.J. Zhou, M. Pan, Appl. Phys. A74, 257 (2002)
T. Toyoda, M. Unno, N. Nakajima, Phys. B 316–317, 472 (2002)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Salem, J.K., Hammad, T.M., Kuhn, S. et al. Luminescence properties of Mn and Ni doped ZnS nanoparticles synthesized by capping agent. J Mater Sci: Mater Electron 25, 5188–5194 (2014). https://doi.org/10.1007/s10854-014-2287-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-014-2287-2