Abstract
Novel ZnO core/shell nanostructures were constructed by depositing a porous ZnO layer directly on the surfaces of pre-fabricated ZnO nanowires through a facile chemical method. The morphology and structure of the obtained products have been investigated by field-emission scanning electron microscopy, high-resolution transmission electron microscopy and X-ray diffraction analysis. In these unique nanostructures, the porous overlayer exhibits a large surface area for sufficient dye loading to enhance light harvesting and the ZnO nanowire cores provide direct conduction pathways for the photogenerated electron transport to diminish the chance of electron recombination. The obtained ZnO nanostructures were used as photoanode material in dye-sensitized solar cell which showed an increase in performance of 141 % compared with an equivalent solar cell employing ZnO nanowire arrays as photoanode. This result was achieved mainly due to an increase in photogenerated current density directly resulting from improved light harvesting of the porous layer.
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References
M. Thambidurai, N. Muthukumarasamy, D. Velauthapillai, C. Lee, J. Mater. Sci.: Mater. Electron. 24, 1921 (2013)
P. Jayabal, V. Sasirekha, J. Mayandi, K. Jeganathan, V. Ramakrishnan, J. Alloys Compd. 586, 456 (2014)
M. Dadkhah, M. Salavati-Niasari, Mater. Sci. Semicond. Process. 20, 41 (2014)
I.Y. Bu, M.T. Cole, Mater. Lett. 90, 56 (2013)
T. Ganesh, S.S. Bhande, R.S. Mane, S.H. Han, Scripta Mater. 69, 291 (2013)
S. He, X. Zou, Z. Sun, G. Teng, Mater. Lett. 91, 258 (2013)
R.T. Ginting, C.C. Yap, M. Yahaya, M. Mat, Salleh. J. Alloys Compd. 585, 696 (2014)
I.Y. Bu, Mater. Sci. Semicond. Process. 16, 1730 (2013)
E. Tsuji, N. Hirata, Y. Aoki, H. Habazaki, Mater. Lett. 91, 39 (2013)
M. Thambidurai, N. Muthukumarasamy, D. Velauthapillai, C. Lee, J. Mater. Sci.: Mater. Electron. 24, 2367 (2013)
S. Zhu, X. Chen, F. Zuo, M. Jiang, Z. Zhou, D. Hui, J. Solid State Chem. 197, 69 (2012)
A. Tubtimtae, M.W. Lee, Superlattices Microstruct. 52, 987 (2012)
S. Vanalakar, S. Mali, R. Pawar, D. Dalavi, A. Mohalkar, H. Deshamukh, P. Patil, Ceram. Int. 38, 6461 (2012)
S. Zhu, X. Tian, L. Shan, Z. Ding, Z. Kan, X. Xu, Z. Zhou, L. Wang, Ceram. Int. 39, 9637 (2013)
A. Al-Kahlout, Thin Solid Films 520, 1814 (2012)
P. Teesetsopon, S. Kumar, J. Dutta, Int. J. Electrochem. Sci. 7, 4988 (2012)
C. Xu, P. Shin, L. Cao, D. Gao, J. Phys. Chem. C 114, 125 (2009)
H. Wang, C. Xie, D. Zeng, Z. Yang, J. Colloid Interface Sci. 297, 570 (2006)
Acknowledgments
This work was supported by the Natural Science Foundation of Jiangsu Province (BK2012244), the National Natural Science Foundation of China (51202081), the National Major Basic Research Project (2012CB934302) and the College Natural Science Foundation of Jiangsu Province (12KJB430003).
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Zhu, Y., Deng, F., Ni, C. et al. Boosting ZnO nanowire dye-sensitized solar cell efficiency by coating a porous ZnO layer on the nanowires. J Mater Sci: Mater Electron 25, 4547–4552 (2014). https://doi.org/10.1007/s10854-014-2202-x
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DOI: https://doi.org/10.1007/s10854-014-2202-x