Abstract
Superhydrophobic surfaces with a high contact angle and a low sliding angle are promising candidates for corrosion resistance. In general, an excellent chemical and mechanical stability is the most critical property for superhydrophobic surfaces. In this paper, we proposed a facile, effective and environment friendly method using a simple solution immersion method to fabricate a superhydrophobic surface on copper mesh. The as-fabricated superhydrophobic surface possessing dendritic rough structure and low surface energy displayed a high contact angle of 155.5°. The excellent anti-fouling and self-cleaning properties were demonstrated. The mechanical stability was also exhibited when it was subjected to an impact by a continuous stream of water. In addition, the excellent chemical stability both in acidic and alkaline solutions and the outstanding anti-corrosion effect were showed in electrochemical test due to the air pockets formed between the superhydrophobic surface and water which can well block corrosive medium. This method is facile, timing-saving and environment friendly, which can play a crucial role in practical industries application of superhydrophobic surface.
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References
Wen QY, Guo F, Peng YB, Guo ZG (2018) Simple fabrication of superamphiphobic copper surfaces with multilevel structures. Colloid Surf A 539:11–17
Cai JY, Wang TYY, Hao W, Ling HQ, Hang T, Chung Y-W, Li M (2019) Fabrication of superamphiphobic Cu surfaces using hierarchical surface morphology and fluorocarbon attachment facilitated by plasma activation. Appl Surf Sci 464:140–145
Cao CY, Cheng J (2018) Fabrication of superhydrophobic copper stearate@Fe3O4 coating on stainless steel meshes by dip-coating for oil/water separation. Surf Coat Technol 349:296–302
Li GQ, Mai ZH, Shu X, Chen DZ, Liu M, Xu WL (2019) Superhydrophobic/superoleophilic cotton fabrics treated with hybrid coatings for oil/water separation. Adv Compos Hybrid Mater 2:254–265. https://doi.org/10.1007/s42114-019-00092-w
Sun SJ, Zhu LY, Liu XH, Wu LL, Dai K, Liu CT, Shen CY, Guo XK, Zheng GQ, Guo ZH (2018) superhydrophobic shish-kebab membrane with self-cleaning and oil/water separation properties. ACS Sustain Chem Eng 6:9866–9875
Li ZZ, Wang B, Qin XM, Wang YK, Liu CT, Shao Q, Wang N, Zhang JX, Shen CY, Guo ZH (2018) Superhydrophobic/superoleophilic polycarbonate/carbon nanotubes porous monolith for selective oil adsorption from water. ACS Sustain Chem Eng 6:13747–13755
Wang P, Zhang D, Qiu R, Wan Y, Wu JJ (2014) Green approach to fabrication of a super-hydrophobic film on copper and the consequent corrosion resistance. Corros Sci 80:366–373
Fan YH, Chen ZJ, Liang J, Wang Y, Chen H (2014) Preparation of superhydrophobic films on copper substrate for corrosion protection. Surf Coat Technol 244:1–8
Li H, Yu SR, Han XX (2016) Fabrication of CuO hierarchical flower-like structures with biomimetic superamphiphobic, self-cleaning and corrosion resistance properties. Chem Eng J 283:1443–1454
Zeng YW, Qin ZL, Hua QH, Min YL, Xu QJ (2019) Sheet-like superhydrophobic surfaces fabricated on copper as a barrier to corrosion in a simulated marine system. Surf Coat Technol 362:62–71
Ding SB, Xiang TF, Li C, Zheng SL, Wang J, Zhang MX, Dong CD, Chan WM (2016) Fabrication of self-cleaning super-hydrophobic nickel/graphene hybrid film with improved corrosion resistance on mild steel. Mater Des 117:280–288
Liu MJ, Wang ST, Jiang L (2017) Nature-inspired superwettability systems. Nat Rev Mater 2:17036. https://doi.org/10.1038/natrevmats.2017.36
Ferrari M, Benedetti A (2015) Superhydrophobic surfaces for applications in seawater. Adv Colloid Interface 222:291–304
Yang ZQ, Wang LD, Sun W, Li SJ, Zhu TZ, Liu W, Liu GC (2017) Superhydrophobic epoxy coating modified by fluorographene used for anti-corrosion and self-cleaning. Appl Surf Sci 401:146–155
Deng WS, Long MY, Miao XR, Wen N, Deng WL (2017) Eco-friendly preparation of robust superhydrophobic Cu(OH)2 coating for self-cleaning, oil–water separation and oil sorption. Surf Coat Technol 325:14–21
Bai WB, Xu J, Guan MQ, He YF, Xu YL, Lin JH (2019) Preparation of superhydrophobic polyimide microstructural layer on copper mesh for oil/water separation. J Taiwan Inst Chem Eng 95:71–77
Yuan SJ, Chen C, Raza A, Song RX, Zhang T-J, Pehkonen SO, Liang B (2017) Nanostructured TiO2/CuO dual-coated copper meshes with superhydrophilic, underwater superoleophobic and self-cleaning properties for highly efficient oil/water separation. Chem Eng J 1328:497–510
Wu L-K, Zhang X-F, Hu J-M (2014) Corrosion protection of mild steel by one-step electrodeposition of superhydrophobic silica film. Corros Sci 85:482–487
Liu Y, Yin XM, Zhang JJ, Yu SR, Han ZW, Ren LQ (2014) A electro-deposition process for fabrication of biomimetic super-hydrophobic surface and its corrosion resistance on magnesium alloy. Electrochim Acta 125:395–403
She ZX, Li Q, Wang ZW, Li LQ, Chen FN, Zhou JC (2013) Researching the fabrication of anticorrosion superhydrophobic surface on magnesium alloy and its mechanical stability and durability. Chem Eng J 228:415–424
Yang Z, Liu XP, Tian YL (2019) Fabrication of super-hydrophobic nickel film on copper substrate with improved corrosion inhibition by electrodeposition process. Colloid Surf A 560:205–212
Li CL, Sun YC, Cheng M, Sun SQ, Hu SQ (2018) Fabrication and characterization of a TiO2/polysiloxane resin composite coating with full-thickness super-hydrophobicity. Chem Eng J 333:361–369
Lu Z, Wang P, Zhang D (2015) Super-hydrophobic film fabricated on aluminium surface as a barrier to atmospheric corrosion in a marine environment. Corros Sci 91:287–296
Yu TL, Lu SX, Xu WG, Boukherroub R (2019) Preparation of superhydrophobic/superoleophilic copper coated titanium mesh with excellent ice-phobic and water-oil separation performance. Appl Surf Sci 476:353–362
Qian HC, Xu DK, Du CW, Zhang DW, Li XG, Huang LY, Deng LP, Tu YC, Mol JMC, Terryn HA (2017) Dual-action smart coatings with a self-healing superhydrophobic surface and anti-corrosion properties. J Mater Chem A 5(5):2355–2364
Yang Z, Tian YL, Yang CJ, Wang FJ, Liu XP (2017) Modification of wetting property of Inconel 718 surface by nanosecond laser texturing. Appl Surf Sci 464:140–145
Yang Z, Liu XP, Tian YL (2018) Insights into the wettability transition of nanosecond laser ablated surface under ambient air exposure. J Colloid Interface Sci 533:268–277
Yang Z, Liu XP, Tian YL (2019) Hybrid laser ablation and chemical modification for fast fabrication of bio-inspired super-hydrophobic surface with excellent self-cleaning, stability and corrosion resistance. J Bionic Eng 16:13–26
Wan YX, Chen MJ, Liu W, Shen XX, Min YL, Xu QJ (2018) The research on preparation of superhydrophobic surfaces of pure copper by hydrothermal method and its corrosion resistance. Electrochim Acta 270:310–318
Wang H, Dong SL, Wang ZL (2018) One-step fabrication of superhydrophobic surface on beryllium copper alloys and corrosion protection application. Colloid Surf A 556:291–298
Zhu GY, Cui XK, Zhang Y, Dong MY, Liu H, Shao Q, Ding T, Wu SD, Guo ZH (2019) Poly (vinyl butyral)/graphene oxide/poly (methylhydrosiloxane) nanocomposite coating for improved aluminum alloy anticorrosion. Polymer 172:415–422
Lin ZP, Lin B, Wang ZP, Chen SG, Wang CW, Dong MY, Gao Q, Shao Q, Ding T, Liu H, Wu SD, Guo ZH (2019) Facile preparation of 1T/2H-Mo(S1−xSex)2 nanoparticles for boosting hydrogen evolution reaction. Chemcatchem 11:2217–2222
Lin B, Lin ZP, Chen SG, Yu MY, Li W, Gao Q, Dong MY, Shao Q, Wu SD, Ding T, Guo ZH (2019) Surface intercalated spherical MoS2xSe2(1−x) nanocatalysts for highly efficient and durable hydrogen evolution reactions. Dalton Trans 48:8276–8287. https://doi.org/10.1039/c9dt01218d
Li JF, Ge SS, Wang JX, Du HY, Song KN, Fei ZY, Shao Q, Guo ZH (2018) Water-based rust converter and its polymer composites for surface anticorrosion. Colloid Surf A 537:334–342
Chen FZ, Song JL, Lu Y, Huang S, Liu X, Sun J, Carmalt CJ, Parkin IP, Xu WJ (2015) Creating robust superamphiphobic coatings for both hard and soft materials. J Mater Chem A 3(42):20999–21008
Wang N, Wang Q, Xu SS, Zheng X, Zhang MY (2019) Facile fabrication of amphiphobic surfaces on copper substrates with a mixed modified solution. RSC Adv 9:17366–17372
Khosravi M, Azizian S (2017) Preparation of superhydrophobic and superoleophilic nanostructured layer on steel mesh for oil–water separation. Sep Purif Technol 172:366–373
Fu J, Yang FC, Guo ZG (2019) Facile fabrication of superhydrophobic filter paper with high water adhesion. Mater Lett 236:732–735
Cao Z-F, Lu F, Qiu P, Yang F, Liu GY, Wang S, Zhong H (2018) Formation of a hydrophobic and corrosion resistant coating on manganese surface via stearic acid and oleic acid diethanolamide. Colloid Surf A 555:372–380
Kang H, Cheng Z, Lai H, Ma H, Liu Y, Mai X, Wang Y, Shao Q, Xiang L, Guo X, Guo Z (2018) Superlyophobic anti-corrosive and self-cleaning titania robust mesh membrane with enhanced oil/water separation. Sep Purif Technol 201:193–204
Wang WH, Hao XP, Chen SG, Yang ZQ, Wang CY, Yan R, Zhang X, Liu H, Shao Q, Guo ZG (2018) pH-responsive Capsaicin@chitosan nanocapsules for antibiofouling in marine applications. Polymer 158:223–230
Cui XK, Zhu GY, Pan YF, Shao Q, Zhao C, Dong MY, Zhang Y, Guo ZH (2018) Polydimethylsiloxane–titania nanocomposite coating: Fabrication and corrosion resistance. Polymer 138:203–210
Acknowledgements
This work was supported by the Taishan Scholar Project of Shandong Province (No. TSHW20130956) and Natural Science Foundation of Shandong Province, China (No. ZR2017MA013).
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SX, NW and XZ conducted the experiments and data analysis under the advice of QW; SX and QW wrote the manuscript.
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Xu, S., Wang, Q., Wang, N. et al. Fabrication of superhydrophobic green surfaces with good self-cleaning, chemical stability and anti-corrosion properties. J Mater Sci 54, 13006–13016 (2019). https://doi.org/10.1007/s10853-019-03789-x
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DOI: https://doi.org/10.1007/s10853-019-03789-x