Abstract
Multiwalled carbon nanotubes (MWNTs) are fillers of choice for composite reinforcement owing to their outstanding modulus and strength. However, the poor dispersion and load transfer between MWNTs and matrix still limit their potential and further application of MWNTs in mechanical reinforcement. In this paper, we report a facile “one-pot” method for functionalization of MWNTs with PPTA-oligomer (o-PPTA). The obtained o-PPTA functionalized multiwalled carbon nanotubes (MWNTs/o-PPTA) can be well dispersed in DMF solvent. Polyvinyl chloride (PVC) was chosen as a model polymer for investigating the reinforcement effect of MWNTs/o-PPTA. The results of tensile tests illustrated that the Young’s modulus, toughness and yield strength of composite films were obviously improved compared to those of neat PVC film, which were increased by 129%, 262% and 126%, respectively. The factors including molecular weight of loaded o-PPTA and dosage of MWNTs/o-PPTA on PVC reinforcement effect were also studied. The results showed that MWNTs/o-PPTA is promising additive for reinforcing PVC.
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References
Coleman JN, Khan U, Blau WJ et al (2006) Small but strong: a review of the mechanical properties of carbon nanotube-polymer composites. Carbon 44:1624–1652
Abdalla M, Dean D, Theodore M et al (2010) Magnetically processed carbon nanotube/epoxy nanocomposites: morphology, thermal, and mechanical properties. Polymer 51:1614–1620
Byrne MT, Gun’Ko YK (2010) Recent advances in research on carbon nanotube-polymer composites. Adv Mater 22:1672–1688
Shim BS, Zhu J, Jan E, Critchley K, Ho S, Podsiadlo P, Sun K, Kotov NA (2009) Multiparameter structural optimization of single-walled carbon nanotube composites: toward record strength, stiffness, and toughness. ACS Nano 3:1711–1722
Coleman JN, Khan UA, Gun’ko YK (2006) Mechanical reinforcement of polymers using carbon nanotubes. Adv Mater 18:689–706
Moniruzzaman M, Winey KI (2006) Polymer nanocomposites containing carbon nanotubes. Macromolecules 39:5194–5205
Grujicic M, Sun YP, Koudela KL (2007) The effect of covalent functionalization of carbon nanotube reinforcements on the atomic-level mechanical properties of poly-vinyl-ester-epoxy. Appl Surf Sci 253:3009–3021
Dong Q, Nasir MZM, Pumera M (2017) Semi-conducting single-walled carbon nanotubes are detrimental when compared to metallic single-walled carbon nanotubes for electrochemical applications. Phys Chem Chem Phys 19:27320–27325
Costa P, Silva J, Ansón-Casaos A et al (2014) Effect of carbon nanotube type and functionalization on the electrical, thermal, mechanical and electromechanical properties of carbon nanotube/styrene-butadiene-styrene composites for large strain sensor applications. Compos Part B Eng 61:136–146
Beenish Inamuddin, Asiri AM (2017) Electrospun polyaniline/polyvinyl alcohol/multiwalled carbon nanotubes nanofibers as promising bioanode material for biofuel cells. J Electroanal Chem 789:181–187
Yu MF, Lourie O, Dyer MJ, Moloni K, Kelly TF, Ruoff RS (2000) Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load. Science 287:637–640
Wei C, Srivastava D, Cho K (2002) Thermal expansion and diffusion coefficients of carbon nanotube-polymer composites. Nano Lett 2:647–650
Lau KT, Hui D (2002) The revolutionary creation of new advanced materials-carbon nanotube composites. Compos Part B Eng 33:263–277
Peigney A, Laurent C, Flahaut E et al (2001) Specific surface area of carbon nanotubes and bundles of carbon nanotubes. Carbon 39:507–514
Burkholder GL, Kwon YW, Pollak RD (2011) Effect of carbon nanotube reinforcement on fracture strength of composite adhesive joints. J Mater Sci 46:3370–3377. https://doi.org/10.1007/s10853-010-5225-6
Faulkner SD, Kwon YW, Bartlett S, Rasmussen EA (2009) Study of composite joint strength with carbon nanotube reinforcement. J Mater Sci 44:2858–2864. https://doi.org/10.1007/s10853-009-3378-y
Kwon YW, Slaff R, Bartlett S, Greene T (2008) Enhancement of composite scarf joint interface strength through carbon nanotube reinforcement. J Mater Sci 43:6695–6703. https://doi.org/10.1007/s10853-008-2689-8
Yang M, Cao K, Yeom B, Thouless MD (2015) Aramid nanofiber-reinforced transparent nanocomposites. J Compos Mater 49:1873–1879
Cadek M, Coleman JN, Ryan KP, Nicolosi V (2004) Reinforcement of polymers with carbon nanotubes: the role of nanotube surface area. Nano Lett 4:353–356
Bokobza L (2007) Multiwall carbon nanotube elastomeric composites: a review. Polymer 48:4907–4920
Punetha VD, Rana S, Yoo HJ et al (2017) Functionalization of carbon nanomaterials for advanced polymer nanocomposites: a comparison study between CNT and graphene. Prog Polym Sci 67:1–47
Zhao Y, Mannhalter B, Hong H, Welsh JS (2010) Mechanical properties of epoxy nanocomposites reinforced with very low content of amino-functionalized single-walled carbon nanotubes. J Nanosci Nanotechnol 10:5776–5782
Dai Y, Haiping H, Guiver M, Welsh JS (2009) Reinforced films based on cross-linked water-soluble sulfonated carbon nanotubes with sulfonated polystyrene. J Nanosci Nanotechnol 9:5150–5156
Liu M, Younce H, Haiping H, Peterson GP (2019) Polymer nanocomposites with magnetically aligned carbon nano material. Polymer 166:81–87
Yang BX, Pramoda KP, Xu GQ, Goh SH (2007) Mechanical reinforcement of polyethylene using polyethylene-grafted multiwalled carbon nanotubes. Adv Funct Mater 17:2062–2069
Kim JD, Zhu J, Peng H, Margrave JL, Khabashesku VN, Barrera EV (2003) Improving the dispersion and integration of single-walled carbon nanotubes in epoxy composites through functionalization. Nano Lett 3:1107–1113
Sang WK, Kim T, Kim YS, Hong SC, Lim HJ (2012) Surface modifications for the effective dispersion of carbon nanotubes in solvents and polymers. Carbon 50:3–33
Chen J, Ramasubramaniam R, Xue C, Liu H (2006) A versatile, molecular engineering approach to simultaneously enhanced, multifunctional carbon-nanotube-polymer-composites. Adv Funct Mater 16:114–119
O’Connor I, Hayden H, Coleman JN, Gun’ko YK (2009) High-strength, high-toughness composite fibers by swelling Kevlar in nanotube suspensions. Small 5:466–469
Sainsbury T, Erickson K, Okawa D, Zonte CS, Fréchet JMJ, Zettl A (2010) Kevlar functionalized carbon nanotubes for next-generation composites. Chem Mater 22:2164–2171
Wang Y, Shi ZX, Yin J (2011) Kevlar oligomer functionalized graphene for polymer composites. Polymer 52:3661–3670
O’Connor I, Hayden H, O’Connor S, Coleman JN, Gun’Ko YK (2008) Kevlar coated carbon nanotubes for reinforcement of polyvinylchloride. J Mater Chem 18:5585–5588
O’Connor I, Hayden H, O’Connor S, Coleman JN, Gun’Ko YK (2009) Polymer reinforcement with Kevlar-coated carbon nanotubes. J Phys Chem C 113:20184–20192
Fan ZJ, Kai W, Yan J, Wei T, Zhi LJ, Feng J (2011) Facile synthesis of graphene nanosheets via Fe reduction of exfoliated graphite oxide. ACS Nano 5:191–198
Zhao X, Zhang Q, Hao Y, Li Y, Fang Y, Chen D (2010) Alternate multilayer films of poly(vinyl alcohol) and exfoliated graphene oxide fabricated via a facial layer-by-layer assembly. Macromolecules 43:9411–9416
Ramanathan T, Fisher FT, Ruoff RS, Brinson LC (2005) Amino-functionalized carbon nanotubes for binding to polymers and biological systems. Chem Mater 17:1290–1295
Acknowledgements
The authors are grateful for the financial support by the National Natural Science Foundation of China (Grant Nos. 51673089, 51373074, 51073075, 51302127, 51143006) and Scientific and Technological Research Program of Shandong province (No. 2014GGX102027).
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Fu, R., Dong, C., Zhang, Y. et al. PPTA-oligomer functionalized multiwalled carbon nanotubes synthesized by “one-pot” method for reinforcement of polyvinyl chloride. J Mater Sci 54, 11804–11817 (2019). https://doi.org/10.1007/s10853-019-03730-2
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DOI: https://doi.org/10.1007/s10853-019-03730-2