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Mechanochemical synthesis of cerium(IV)-phosphonates

  • Mechanochemical Synthesis
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Abstract

The syntheses and crystal structures of two cerium(IV) phosphonates are presented. Cerium(IV) bis(phenylphosphonate) Ce(O3PC6H5)2 1 can be formed from precipitation and mechanochemical reaction, whereas cerium(IV) bis(carboxymethylphosphonate) monohydrate Ce(O3PCH2COOH)2 · H2O 2 is only accessible via ball milling. All reactions proceed very fast and are completed within a short time span. In situ measurements for the syntheses of 1 show that the product occurs within seconds or a few minutes, respectively. The structures were solved from powder X-ray diffraction data.

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Acknowledgements

The authors are grateful for the funding received from the DFG program “Crystalline non-equilibrium compounds” (Grant No. Em198/3-2). Manuel Wilke has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 701647.

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Authors and Affiliations

  1. Swiss Light Source, Material Science Beamline, Paul Scherrer Institute, 5232, Villigen PSI, Switzerland

    Manuel Wilke

  2. BAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Straße 11, 12489, Berlin, Germany

    Manuel Wilke, Irina Akhmetova & Franziska Emmerling

  3. Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, 12489, Berlin, Germany

    Klaus Rademann

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  1. Manuel Wilke
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Correspondence to Franziska Emmerling.

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Wilke, M., Akhmetova, I., Rademann, K. et al. Mechanochemical synthesis of cerium(IV)-phosphonates. J Mater Sci 53, 13733–13741 (2018). https://doi.org/10.1007/s10853-018-2507-x

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