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Effects of graphene on MoO2-MoS2 composite as anode material for lithium-ion batteries

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Abstract

The electrochemical properties of MoO2-MoS2/graphene electrode were compared with those of MoO2-MoS2, bulk MoS2, and graphene electrode. MoO2-MoS2 composite was prepared by a hydrothermal reaction of molybdenum (VI) oxide with sodium sulfide. MoO2-MoS2/graphene composite was obtained by the mechanical mixing of prepared MoO2-MoS2 composite with graphene. MoO2-MoS2/graphene and graphene electrodes exhibited good cycling stability, while MoO2-MoS2 and bulk MoS2 electrodes showed a decrease of capacity during cycling. Especially, the MoO2-MoS2/graphene composite anode showed a high discharge capacity (974 mAh/g) after 20th cycle and superior high-rate capability. Such excellent reversible capability and cycle performance may be attributed to the good combination of MoO2, MoS2, and graphene.

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Acknowledgments

This work was supported by the 2013 Research Fund of the University of Ulsan, Ulsan, Korea.

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Authors and Affiliations

  1. Department of Chemistry, University of Ulsan, Ulsan, 680-749, Republic of Korea

    Moon-Jin Hwang & Kwang-Sun Ryu

  2. Research Section of Power Control Devices, Electronics and Telecommunications Research Institute (ETRI), Daejeon, 305-700, Republic of Korea

    Kwang Man Kim

Authors
  1. Moon-Jin Hwang
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  3. Kwang-Sun Ryu
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Correspondence to Kwang-Sun Ryu.

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Hwang, MJ., Kim, K.M. & Ryu, KS. Effects of graphene on MoO2-MoS2 composite as anode material for lithium-ion batteries. J Electroceram 33, 239–245 (2014). https://doi.org/10.1007/s10832-014-9956-7

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  • DOI: https://doi.org/10.1007/s10832-014-9956-7

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