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Ion dynamics in single and mixed former glasses: Correlation between microscopic lengths and network structure

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Abstract

We have investigated ion dynamics in several single and mixed former glasses in wide composition and temperature ranges. The ionic conductivity of these glasses depends strongly on the dopant salt content as well as on the mixed former ratio. The characteristic lengths for ion dynamics, such as mean square displacement and spatial extent of sub-diffusive motion of lithium ions, have been determined from the ac conductivity and dielectric spectra respectively. Ionic conductivity and the characteristic lengths have been correlated with the modification of the glass network structure.

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Acknowledgments

Financial assistance for the work by the DST, Govt. of India (through grant no. SR/S2/CMP-0093/2010) is thankfully acknowledged. AS acknowledges CSIR, India for providing him with Research Fellowship (file no. 09/080(0704)/2010-EMR-I).

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Author notes

  1. B. Deb

    Present address: Department of Physics, Ramkrishna Mahavidyalaya, Tripura (Unakoti), 799277, India

  2. S. Kabi

    Present address: Department of Physics, Sikkim Manipal University, SMIT campus, Majitar, Rangpo, East Sikkim, 737132, India

Authors and Affiliations

  1. Department of Solid State Physics, Indian Association for the Cultivation of Science, Jadavpur, Kolkata, 700032, India

    A. Shaw, B. Deb, S. Kabi & A. Ghosh

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  1. A. Shaw
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  2. B. Deb
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Correspondence to A. Ghosh.

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Shaw, A., Deb, B., Kabi, S. et al. Ion dynamics in single and mixed former glasses: Correlation between microscopic lengths and network structure. J Electroceram 34, 20–27 (2015). https://doi.org/10.1007/s10832-014-9932-2

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  • DOI: https://doi.org/10.1007/s10832-014-9932-2

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