A multi-ion chromogenic sensor based on a terpyridine moiety was developed for the semiquantitative, visual, and sensitive speciation analysis of Fe2+ and Co2+ ions in water. Each metal ion exhibited a different color, and significant color evolution was observed by the naked eye, resulting in semiquantitative visual detection. A smartphone was used for visual detection by identifying the RGB values of the probe solutions. The application of smartphones shortened the detection time dramatically and reduced the detection cost. This method provides a new strategy for the semiquantitative detection of heavy metal ions in water samples.
Similar content being viewed by others
References
O. M. Acar, O. M. Kalfa, O. Yalcinkaya, and A. R. Turker, Anal. Methods, 5, 748–754 (2013).
M. D. Ioannidou, G. A. Zachariadis, A. N. Anthemidis, and J. A. Stratis, Talanta, 65, 92–97 (2005).
K. Fan, X. Wang, Y. Ma, Y. Li, G. Han, Z. Yin, and J. Song, RSC Adv., 9, 32137–32140 (2019).
J. Qi, B. Li, X. Wang, L. Fu, L. Luo, and L. Chen, Anal. Chem., 90, 11827–11834 (2018).
G. Heo, R. Manivannan, H. Kim, M. J. Kim, K. S. Min, and Y.-A. Son, Sens. Actuat. B, 297, 126723 (2019).
Y. Zhou, X. Huang, C. Liu, R. Zhang, X. Gu, G. Guan, C. Jiang, L. Zhang, S. Du, B. Liu, M.-Y. Han, and Z. Zhang, Anal. Chem., 88, 6105–6109 (2016).
K. Fan, X. Wang, Z. Yin, C. Jia, B. Zhang, L. Zhou, and J. Song, J. Mater. Chem. C, 6, 10192–10196 (2018).
A. W. Martinez, S. T. Phillips, E. Carrilho, S. W. Thomas, H. Sindi, and G. M. Whitesides, Anal. Chem., 80, 3699–3707 (2008).
X. Guan, K. Fan, T. Gao, A. Ma, B. Zhang, and J. Song, Chem. Commun., 52, 962–965 (2016).
Z. Liu, X. Jia, P. Bian, and Z. Ma, Analyst, 139, 585–588 (2014).
A. Maiga, D. Diallo, R. Bye, and B. S. Paulsen, J. Agric. Food Chem., 53, 2316–2321 (2005).
V. Battaglia, A. Compagnone, A. Bandino, M. Bragadin, C. A. Rossi, F. Zanetti, S. Colombatto, M. A. Grillo, and A. Toninello, Int. J. Biochem. Cell Biol., 41, 586–594 (2009).
K. Czarnek, S. Terpiłowska, and A. K. Siwicki, J. Immunol., 40, 236–242 (2015).
Z. Zhang, J. Zhang, T. Lou, D. Pan, L. Chen, C. Qu, and Z. Chen, Analyst, 137, 400–405 (2012).
D. W. Domaille, E. L. Que, and C. J. Chang, Nat. Chem. Biol., 4, 168–175 (2008).
H. Weizman, O. Ardon, B. Mester, J. Libman, O. Dwir, Y. Hadar, Y. Chen, and A. Shanzer, J. Am. Chem. Soc., 118, 12368–12375 (1996).
C. Brugnara, Clin. Chem., 49, 1573–1578 (2003).
X. B. Zhang, G. Cheng, W. J. Zhang, G. L. Shen, and R. Q. Yu, Talanta, 71, 171–177 (2007).
C. Qin, Y. Cheng L. Wang, X. Jing, and F. Wang, Macromolecules, 41, 7798–7804 (2008).
D. Galaris, V. Skiada, and A. Barbouti, Cancer Lett., 266, 21–29 (2008).
S. K. Sahoo, D. Sharma, R. K. Bera, G. Crisponi, and J. F. Callan, Chem. Soc. Rev., 41, 7195–7227 (2012).
K. Fan, X. Wang, H. Yang, L. Gao, G. Han, L. Zhou, and S. Fang, Anal. Methods, 12, 1561–1566 (2020).
J. X. Shi, C. Lu, D. Yan, and L. Ma, Biosens. Bioelectron., 45, 58–64 (2013).
S. M. Kang, S. C. Jang, G. Y. Kim, C. S. Lee, Y. S. Huh, and C. Roh, Sensors, 16, 626–636 (2016).
K. Fan, H. Kong, X. Wang, X. Yang, and J. Song, RSC Adv., 6, 80934–80938 (2016).
Y. W. Choi, G. J. Park, Y. J. Na, H. Y. Jo, S. A. Lee, G. R. You, and C. Kim, Sens. Actuators B, 194, 343–352 (2014).
K. Fan, X. Wang, S. Yu, G. Han, D. Xu, L. Zhou, and J. Song, Polym. Chem., 10, 5037–5043 (2019).
H. Nawaz, W. Tian, J. Zhang, R. Jia, Z. Chen, J. Zhang, and C.-B. Sensor, ACS Appl. Mater. Interfaces, 10, 2114–2121 (2018).
C. Liu, D. Ning, C. Zhang, Z. Liu, R. Zhang, J. Zhao, T. Zhao, B. Liu, and Z. Zhang, ACS Appl. Mater. Interfaces, 9, 18897–18903 (2017).
S. K. A. Kumar, K. Vijayakrishna, A. Sivaramakrishna, C. V. S. Brahmmananda Rao, N. Sivaraman, and S. K. Sahoo, Inorg. Chem., 57, 15270–15279 (2018).
H. Wang, L. Yang, S. Chu, B. Liu, Q. Zhang, L. Zou, S. Yu, and C. Jiang, Anal. Chem., 91, 9292–9299 (2019).
I. J. Kim, M. Ramalingam, and Y. A. Son, Sens. Actuat. B, 246, 319–326 (2017).
D. Gomez-Nicola, K. Riecken, B. Fehse, and V. H. Perry, Sci. Rep., 4, 7520 (2014).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Abstract of article is published in Zhurnal Prikladnoi Spektroskopii, Vol. 89, No. 3, p. 435, May–June, 2022.
Rights and permissions
Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Wang, X., Ma, Y., Li, Z. et al. Colorimetric Detection of Fe(II) and Co(II) by Using Terpyridine-Based Derivative. J Appl Spectrosc 89, 586–592 (2022). https://doi.org/10.1007/s10812-022-01398-2
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-022-01398-2