This study aimed to investigate the molecular mobility of crude oils using the linewidth of the free radical electron paramagnetic resonance signal (EPR) as a molecular mobility probe. For this, aromatic and paraffinic crude oil samples were analyzed by X-band EPR spectroscopy, NMR experiments in time domain (TD-NMR), and rheometry. The variations on the half height linewidth with temperature presented a similar behavior for both samples, being related to different molecular mobility regimes. EPR results were compared to the variation of viscosity with temperature obtained by rheometry and TD-NMR. The results showed changes in the decrease trend of viscosity for the paraffinic sample at a temperature close to the range in which it is observed the transition from rigid to liquid regime in the EPR analysis. EPR technique showed more detailed information about the regime transition for the oil samples studied, which is in agreement with the results obtained by rheometry and TD-NMR.
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T. F. Yen, J. G. Erdman, and A. J. Saraceno, Anal. Chem., 34, 694–700 (1962).
L. Montanari, M. Clericuzio, G. Del Piero, and R. Scotti, Appl. Magn. Res., 14, 81–100 (1998).
L. Artok, Y. Su, Y. Hirose, M. Hosokawa, S. Murata, and M. Nomura, Energy Fuels, 13, 287–296 (1999).
J. G. Speight and B. Ozum, Petroleum Refining Processes, Marcel Dekker, New York (2002).
J. S. Buckley, Energy Fuels, 13, 328–332 (1999).
I. N. Evdokimov, N. Y. Eliseev, and B. R. Akhmetov, Fuel, 82, 817–823 (2003).
A. Ahmadpour, K. Sadeghy, and S. R. Maddah-Sadatieh, J. Non-Newton Fluid Mech., 205, 16–27 (2014).
J. A. Carrillo and L. M. Corredor, Fuel Proc. Technol., 109, 156–162 (2013).
G. T. Chala, S. A. Sulaiman, and A. Japper-Jaafar, J. Non-Newton Fluid Mech., 251, 69–87 (2018).
J. Uebersfeld, A. Étienne, and J. Combrisson, Nature, 174, 614 (1954).
C. L. Barbosa Guedes, E. Di Mauro, V. Antunes, and A. S. Mangrich, Mar. Chem., 84, 105–112 (2003).
M. T. Piccinato, C. L. B. Guedes, and E. Di Mauro, In: Analytical Characterization Methods for Crude Oiland Related Products, Ed. K. Shukla, John Wiley & Sons Ltd., ISBN 9781119286318, New Jersey (2018), pp. 77–99.
N. M. Khasanova, D. T. Gabdrakhmanov, G. P. Kayukova, A. N. Mikhaylova, and V. P. Morozov, Magn. Res. Solids, 19, No. 17102, 1–11 (2017).
G. K. Wong and T. F. Yen, J. Pet. Sci. Eng., 28, 55–64 (2000).
T. B. Biktagirov, M. R. Gafurov, M. A. Volodin, G. V. Mamin, A. A. Rodionov, V. V. Izotov, A. V. Vakhin, D. R. Isakov, and S. B. Orlinskii, Energy Fuels, 28, 6683–6687 (2014).
M. S. Hernández, D. S. Coll, and P. J. Silva, Energy Fuels, 33, 990–997 (2019).
M. R. Gafurov, M. A. Volodin, A. A. Rodionov, A. T. Sorokina, M. Y. Dolomatov, A. V. Petrov, A. V. Vakhin, G. V. Mamin, and S. B. Orlinskii, J. Pet. Sci. Eng., 166, 363–369 (2018).
I. Ahmad, S. M. Sohail, H. Khan, W. Ahmad, K. Gul, R. Khan, and A. Yasin, Energy Fuels, 32, 181–190 (2018).
H. Y. Carr and E. M. Purcell, Phys. Rev., 94, 630–638 (1954).
S. Meiboom and D. Gill, Rev. Sci. Instrum., 29, 688–691 (1958).
Z. Yang, Z. Ma, Y. Luo, Y. Zhang, H. Guo, and W. Lin, Geofluids, Article ID 9542152 (2018).
M. Ikeya, New Applications of Electron Spin Resonance: Dating, Dosimetry and Microscopy, WSPC, ISBN 978-981-02-1200-1, Osaka University, Japan (1993).
E. Di Mauro, C. L. B. Guedes, and O. R. Nascimento, Appl. Magn. Res., 29, 569–575 (2005).
M. Turini, C. L. Barbosa Guedes, and E. Di Mauro, in: Crude Oil Emulsions – Composition, Stability, Characterization, Ed. M. El-Sayed Abdel Raouf, 147–168, InTech, ISBN 978-953-51-0220-5, Rijeka, Croatia (2012).
D. E. O'Reilly, J. Chem. Phys., 29, 1188–1189 (1958).
F. Gerson and W. Huber, Electron Spin Resonance Spectroscopy of Organic Radicals, Wiley-VCH, ISBN 978-3-527-30275-8, Weinheim, Germany (2003).
J. R. Fanchi and R. L. Christiansen, Introduction to Petroleum Engineering, Wiley, New Jersey (2017).
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Abstract of article is published in Zhurnal Prikladnoi Spektroskopii, Vol. 89, No. 1, p. 138, January–February, 2022.
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Khan, A., Valezi, D.F., Picinato, M.T. et al. Molecular Mobility of Crude Oils Via Electron Paramagnetic Resonance of Organic Free Radicals. J Appl Spectrosc 89, 186–190 (2022). https://doi.org/10.1007/s10812-022-01342-4
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DOI: https://doi.org/10.1007/s10812-022-01342-4