Novel amorphous perfluorinated polymers are synthesized and characterized using terahertz (THz) and x-ray spectra. The polymerization of such polymers in which all H atoms are replaced by F is examined. Their optical properties in the THz range show a record low index of refraction for solids in this range. The minimal possible index of refraction for such polymers is estimated. These materials are demonstrated to be highly transparent. The position of a weak absorption maximum in the range 1–2 THz is compared with the characteristic distance between the polymer structural elements that is obtained from an x-ray diffraction analysis of these materials.
Similar content being viewed by others
References
B. Ung and M. Scorobogatiy, in: Handbook of Terahertz Technology for Imaging, Sensing and Communications, D. Saeedkia (Ed.), Woodhead Publishing Series in Electronic and Optical Materials, No. 34 (2013), pp. 28–62.
M. S. Kitai and M. M. Nazarov, Izv. Vyssh. Uchebn. Zaved., Radiofiz., accepted for publication (2018) (Fractal absorption spectra of polymers in the low-frequency terahertz range).
V. I. Sokolov, V. E. Boiko, I. O. Goryachuk, S. M. Igumnov, S. I. Molchanova, Yu. E. Pogodina, and E. V. Polunin, Izv. Akad. Nauk, Ser. Khim., No. 7, 1284–1289 (2017).
A. A. Zharov and I. A. Guzyaeva, Izv. Akad. Nauk, Ser. Khim., No. 6, 1199–1205 (2010).
A. A. Zharov, I. B. Konovalova, and E. V. Polunin, Izv. Akad. Nauk, Ser. Khim., No. 1, 233–236 (2016).
I. Pupeza, R. Wilk, and M. Koch, Opt. Express, 15, No. 7, 4335–4350 (2007).
M. S. Kitai, M. M. Nazarov, D. A. Sapozhnikov, V. I. Bykov, M. V. Bermeshev, S. A. Bulgakova, and B. F. Shklyaruk, Izv. Vyssh. Uchebn. Zaved., Radiofiz., 57, No. 12, 984–994 (2014).
E. P. J. Parrot and J. A. Zeitler, Appl. Spectrosc., 69, No. 1, 1–25 (2015).
L. D. Landau and E. M. Lifshits, Electrodynamics of Complicated Media [in Russian], Nauka, Moscow (1982), 386–393.
J. Ostrovska and A. Narebska, Colloid Polym. Sci., 261, 93–98 (1983).
B. N. Tarasevich, IR Spectra of Main Classes of Organic Compounds, Reference Materials [in Russian], MGU, Moscow (2012), p. 38.
A. Kh. Kuptsov and G. N. Zhizhin, Fourier–Raman and Fourier–IR Spectra of Polymers, Section 1.1.3 [in Russian], Fizmatlit, Moscow (2001).
L. N. Ignat’eva and V. M. Buznik, Zh. Ross. Khim. O′va im. D. I. Mendeleeva, LII, No. 3, 139–146 (2008).
L. N. Ignat’eva, A. K. Tsvetnikov, A. N. Lifshits, V. I. Saldin, and V. M. Buznik, Zh. Strukt. Khim., 43, No. 1, 69–73 (2002).
M. K. Yang, R. H. French, and E. W. Tokarsky, J. Micro/Nanolithogr., MEMS, MOEMS, 7, No. 3, 033010-1–033010-8 (2008).
A. Lacraz, M. Polis, A. Theodosiou, C. Koutsides, and K. Kalli, IEEE Photonics Technol. Lett., 27, No. 7, 693–696 (2015).
G. de los Reyes, A. Quema, C. Ponseca, Jr., R. Pobre, R. Quiroga, S. Ono, H. Murakami, E. Estacio, N. Sarukura, K. Aosaki, Y. Sakane, and H. Sato, Appl. Phys. Lett., 89, 211119-1–211119-3 (2006).
V. N. Korneev, V. A. Shlektarev, A. V. Zabelin, V. M. Aul’chenko, B. P. Tolochko, N. I. Ariskin, L. F. Lanina, and A. A. Vazina, J. Surf. Invest.: X-ray Synchrotron Neutron Technol., 6, 849–864 (2012).
A. P. Hammersley, J. Appl. Crystallogr., 49, 646–652 (2016).
S. F. Kwan, F. C. Chen, and C. L. Choy, Polymer, 16, 481–488 (1975).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 85, No. 3, pp. 364–371, May–June, 2018.
Rights and permissions
About this article
Cite this article
Kitai, M.S., Volkov, W.W., Zharov, A.A. et al. Optical Properties of Amorphous Perfluorinated Polymers in the Terahertz Range. J Appl Spectrosc 85, 374–380 (2018). https://doi.org/10.1007/s10812-018-0660-2
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-018-0660-2