Skip to main content
Log in

Stimulated Emission and Optical Properties of Solid Solutions of Cu(In,Ga)Se2 Direct Band Gap Semiconductors

  • Published:
Journal of Applied Spectroscopy Aims and scope

Stimulated emission, optical properties, and structural characteristics of non-irradiated and proton-irradiated Cu(In,Ga)Se2 thin films deposited on soda lime glass substrates using co-evaporation of elements in a multistage process were investigated. X-ray diffraction analysis, scanning electron microscopy, X-ray spectral analysis with energy dispersion, low-temperature photoluminescence, optical transmittance and reflectance were used to study the films. Stimulated emission at low temperatures of ~20 K was found in non-irradiated and proton-irradiated Cu(In,Ga)Se2 thin films upon excitation by laser pulses of nanosecond duration with a threshold power density of ~20 kW/cm2. It was shown that the appearance and parameters of the stimulated emission depend strongly on the concentration of ion-induced defects in Cu(In,Ga)Se2 thin films.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. A. Green, Y. Hishikawa, W. Warta, E. D. Dunlop, D. H. Levi, J. Hohl-Ebinger, and A. W. Y. Ho-Baillie, Prog. Photovolt. Res. Appl., 25, No. 7, 668–676 (2017).

  2. T. Feurer, P. Reinhard, E. Avancini, B. Bissing, J. Luckinger, P. Fuchs, R. Carron, T. P. Weiss, J. Perrenond, S. Stutterheim, S. Buecheler, and A. N. Tiwari, Prog. Photovolt. Res. Appl., 25, No. 7, 645–667 (2017).

    Article  Google Scholar 

  3. A. Polman, M. Knight, E. C. Garnett, B. Ehrler, and W. C. Sinke, Science, 352, No. 6283, aad4424 (2016).

    Article  Google Scholar 

  4. P. Jackson, R. Wuerz, D. Hariskos, E. Lotter, W. Witte, and M. Powalla, Phys. Status Solidi (Rapid Res. Lett.), 10, No. 8, 583–586 (2016).

    Article  ADS  Google Scholar 

  5. K. Yoshikawa, H. Kawasaki, W. Yoshida, T. Irie, K. Konishi, K. Nakano, T. Uto, D. Adachi, M. Kanematsu, H. Uzu, and K. Yamamoto, Nature Energy, 2, No. 5, 17032 (2016).

    Article  ADS  Google Scholar 

  6. C. Battagliam, A. Cuevas, and S. D. Wolf, Energy Environ. Sci., 9, No. 5, 1552–1576 (2016).

    Article  Google Scholar 

  7. S. Shirakata, Phys. Status Solidi B, 252, No. 6, 1211–1218 (2015).

    Article  ADS  Google Scholar 

  8. A. V. Korotkii, A. V. Mudryi, M. V. Yakushev, F. Luckert, and R. Martin, Zh. Prikl. Spektrosk., 77, No. 5, 725–731 (2010) [A. V. Korotkii, A. V. Mudryi, M. V. Yakushev, F. Luckert, and R. Martin, J. Appl. Spectrosc., 77, No. 5, 668–674 (2010)].

  9. N. Refakhati, A. V. Mudryi, V. D. Zhivul′ko, M. V. Yakushev, and R. Martin, Zh. Prikl. Spektrosk., 81, No. 3, 378–385 (2014) [N. Refahati, A. V. Mudryi, V. D. Zhivulko, M. V. Yakushev, and R. Martin, J. Appl. Spectrosc., 81, No. 3, 404–410 (2014)].

  10. J. Mattheis, U. Rau, and J. H. Werner, J. Appl. Phys., 101, No. 11, 113519 (2007).

    Article  ADS  Google Scholar 

  11. L. Gutay and G. H. Bauer, Thin Solid Films, 487, Nos. 1–2, 8–13 (2005).

    Article  ADS  Google Scholar 

  12. H. Zachmann, S. Puttnins, M. V. Yakushev, F. Luckert, R. W. Martin, A. V. Karotki, V. F. Gremenok, and A. V. Mudryi, Thin Solid Films, 519, No. 21, 7264–7267 (2011).

    Article  ADS  Google Scholar 

  13. D. Shin, J. Kim, T. Gershon, R. Mankad, M. Hopstaken, S. Guha, B. T. Ahn, and B. Shin, Sol. Energy. Mater. Sol. Cells, 157, 695–702 (2016).

    Article  Google Scholar 

  14. I. E. Svitsiankou, V. N. Pavlovskii, E. V. Lutsenko, G. P. Yablonskii, A. V. Mudryi, V. D. Zhivulko, M. V. Yakushev, and R. W. Martin, J. P. Phys. D: Appl. Phys., 49, No. 9, 095106 (2016).

    Article  ADS  Google Scholar 

  15. M. Moret, O. Briot, B. Gil, T. Lepetit, L. Arzel, and N. Barreau, Proc. SPIE, 9358, 93581A1 (2015).

    Article  Google Scholar 

  16. A. Jasenek and U. Rau, J. Appl. Phys., 90, No. 2, 650–658 (2001).

    Article  ADS  Google Scholar 

  17. B. Dimmler, M. Powalla, and H. W. Schock, Prog. Photovolt. Res. Appl., 10, No. 2, 149–157 (2002).

    Article  Google Scholar 

  18. T. Tinoco, C. Rincon, M. Quintero, and G. Sanchez Perez, Phys. Status Solidi A, 124, No. 2, 427–434 (1991).

    Article  ADS  Google Scholar 

  19. E. J. Friedrich, R. Fernandez-Ruiz, J. M. Merino, and M. Leon, Powder Diffraction, 25, No. 3, 253–257 (2010).

    Article  ADS  Google Scholar 

  20. M. Contreras, J. Tuttle, D. Du, Y. Qi, A. Swartzlander, A. Tennant, and R. Noufi , Appl. Phys. Lett., 63, No. 13, 1824–1826 (1993).

    Article  ADS  Google Scholar 

  21. E. Avancini, R. Carron, B. Bessig, P. Reinhard, R. Menozzi, G. Sozzi, S. Di Napoli, T. Feurer, S. Nishiwaki, S. Buecheler, and A. N. Tiwari, Prog. Photovolt., 25, No. 3, 233–241 (2017).

    Article  Google Scholar 

  22. H. Neumann, W. Horig, P. A. Jones, G. Lippold, H. Sobotta, R. D. Tomlinson, and M. Y. Yakushev, Cryst. Res. Technol., 29, No. 5, 719–726 (1994).

    Article  Google Scholar 

  23. J. I. Pankove, Optical Processes in Semiconductors, Englewood Cliffs, New Jersey (1971).

    Google Scholar 

  24. J. P. Biersack and L. G. Haggmark, Nucl. Instr. Meth., 174, 257–269 (1980).

    Article  Google Scholar 

  25. A. V. Mudryi, V. F. Gremenok, A. V. Karotki, V. B. Zalesski, M. V. Yakushev, F. Luckert, and R. Martin, Zh. Prikl. Spektrosk., 77, No. 3, 400–406 (2010) [A. V. Mudryi, V. F. Gremenok, A. V. Karotki, V. B. Zalesski, M. V. Yakushev, F. Luckert, and R. Martin, J. Appl. Spectr., 77, 371–377 (2010)].

  26. G. W. El Haj Moussa, M. Ajaka, M. El. Tahchi, E. Eid, and C. Linares, Phys. Status Solidi A, 202, No. 3, 469–475 (2005).

  27. S. Theodoropoulou, D. Papadimitriou, N. Rega, S. Siebentritt, and M. Ch. Lux-Steiner, Thin Solid Films, 511–512, 690–694 (2005).

  28. J. Krustok, H. Collan, M. Yakushev, and K. Hjelt, Physica Scripta, 79, 179–182 (1999).

    Article  Google Scholar 

  29. M. V. Yakushev, R. W. Martin, J. Krustok, A. V. Mudryi, D. Holman, H. W. Schock, R. D. Pilkington, A. E. Hill, and R. D. Tomlinson, Thin Solid Films, 387, 201–204 (2001).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. N. Pavlovskii.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 85, No. 2, pp. 248–255, March–April, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Svitsiankou, I.E., Pavlovskii, V.N., Lutsenko, E.V. et al. Stimulated Emission and Optical Properties of Solid Solutions of Cu(In,Ga)Se2 Direct Band Gap Semiconductors. J Appl Spectrosc 85, 267–273 (2018). https://doi.org/10.1007/s10812-018-0643-3

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10812-018-0643-3

Keywords

Navigation