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Photoelectric Properties of Film Composites Based on Poly(Vinyl Butyral) and Heterometallic Complexes

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Journal of Applied Spectroscopy Aims and scope

Photosensitive polymeric film composites based on nonphotoconducting poly(vinyl butyral) doped with heterometallic Cu/M complexes (M = Ca, Sr) were synthesized and investigated. These composites possessed photoconducting and photovoltaic properties and electron-type photoconductivity. The greater photocurrent for composites with complexes having shorter distances between the nearest Cu metal centers was attributed to the greater probability of electron transfer between these centers.

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References

  1. S. Ohkoshi, H. Tokoro, T. Hozumi, and Y. Zhang, J. Am. Chem. Soc., 128, No. 1, 270–277 (2006).

    Article  Google Scholar 

  2. J. M. Herrera, V. Marvaud, M. Verdaguer, J. Marrot, M. Kalisz, and C. Mathoniere, Angew. Chem. Int. Ed., 43, No. 41, 5468–5471 (2004).

    Article  Google Scholar 

  3. B. J. Coe and N. R. M. Curati, Comments Inorg. Chem., 25, Nos. 5–6, 147–184 (2004).

    Article  Google Scholar 

  4. L. Li, S.-Y. Niu, J. Jin, Q. Meng, Y.-X. Chi, Y.-H. Xing, and G.-N. Zhang, J. Solid State Chem., 184, 1279–1285 (2011).

    Article  ADS  Google Scholar 

  5. M. Liao, Y. Koide, and J. Alvarez, Phys. Rev. B: Condens. Matter Mater. Phys., 78, 045112–045116 (2008).

    Article  ADS  Google Scholar 

  6. P.-C. Wei, S. Chattopadhyay, M.-D. Yang, J.-L. Shen, C.-Y. Lu, H.-C. Shih, L.-C. Chen, and K.-H. Chen, Phys. Rev. B: Condens. Matter Mater. Phys., 81, 045306–045310 (2010).

    Article  ADS  Google Scholar 

  7. N. S. Allen (Ed.), Photochemistry and Photophysics of Polymeric Materials, John Wiley & Sons, Inc., Hoboken (2010).

    Google Scholar 

  8. K. Mertens and G. Roth, Photovoltaics: Fundamentals, Technology and Practice, Wiley, Chichester, England (2014).

    Google Scholar 

  9. N. A. Davidenko, I. I. Davidenko, V. N. Kokozei, S. L. Studzinskii, S. R. Petrusenko, and N. I. Plyuta, Zh. Prikl. Spektrosk., 82, No. 5, 692–696 (2015) [N. A. Davidenko, I. I. Davidenko, V. N. Kokozay, S. L. Studzinsky, S. R. Petrusenko, and N. I. Plyuta, J. Appl. Spectrosc., 82, No. 5, 750–754 (2015)].

  10. M. Nonnenmacher, M. P. O’Boyle, and H. K. Wichramasinghe, Appl. Phys. Lett., 58, 2921–2923 (1991).

    Article  ADS  Google Scholar 

  11. T. Blythe and D. Bloor, Electrical Properties of Polymers, CUP, Cambridge, UK (2005).

    Google Scholar 

  12. N. A. Davidenko, V. N. Kokozei, M. V. Pavlyuk, V. G. Makhan’kova, S. L. Studzinskii, and I. I. Davidenko, Khim. Vys. Energ., 46, No. 4, 277–279 (2012).

    Google Scholar 

  13. N. A. Davidenko, V. N. Kokozei, M. V. Pavlyuk, V. G. Makhan’kova, S. L. Studzinskii, and I. I. Davidenko, Zh. Prikl. Spektrosk., 80, No. 2, 252–256 (2013) [N. A. Davidenko, V. N. Kokozay, M. V. Pavliuk, V. G. Makhankova, S. L. Studzinsky, and I. I. Davidenko, J. Appl. Spectrosc., 80, 244–248 (2013)].

  14. M. Lampert and P. Mark, Current Injection in Solids, Academic Press, New York and London (1970).

    Google Scholar 

  15. V. G. Shevchenko and A. T. Ponomarenko, Usp. Khim., LII, No. 8, 1336–1349 (1983).

    Google Scholar 

  16. W. Brutting (Ed.), Physics of Organic Semiconductors, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim (2012).

    Google Scholar 

  17. V. Balzani (Ed.), Electron Transfer in Chemistry, Vol. 5, Wiley-VCH, Weinheim–New York (2001).

  18. D. M. Roundhill, Photochemistry and Photophysics of Metal Complexes, Springer, New York (2013).

    Google Scholar 

  19. M. Pope and C. E. Swenberg, Electronic Processes in Organic Crystals and Polymers, Oxford University Press, (1999).

  20. N. A. Davidenko, S. V. Dekhtyarenko, V. N. Kokozei, A. V. Kozinets, O. V. Nesterova, V. A. Skryshevskii, S. L. Studzinskii, O. V. Tretyak, and E. N. Chigorin, Fiz. Tverd. Tela, 52, No. 6, 1223–1226 (2010).

    Google Scholar 

  21. S. M. Ryvkin, Photoelectric Effects in Semiconductors [in Russian], Fizmatgiz, Moscow (1963).

    Google Scholar 

  22. Yu. G. Gurevich and A. V. Meriuts, Phys. Lett. A, 377, No. 38, 2673–2675 (2013).

    Article  ADS  Google Scholar 

  23. G. A. Nabiev, Fiz. Tekh. Poluprovodn., 43, No. 7, 924–925 (2009).

    Google Scholar 

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Correspondence to N. A. Davidenko.

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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 84, No. 6, pp. 982–986, November–December, 2017.

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Davidenko, N.A., Kokozay, V.N., Studzinsky, S.L. et al. Photoelectric Properties of Film Composites Based on Poly(Vinyl Butyral) and Heterometallic Complexes. J Appl Spectrosc 84, 1056–1060 (2018). https://doi.org/10.1007/s10812-018-0586-8

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  • DOI: https://doi.org/10.1007/s10812-018-0586-8

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