Skip to main content
SpringerLink
Log in

Spectroscopic Studies of MnO2 and SiO2 Containing Soil-Active Phosphate Glasses

  • Published:
Journal of Applied Spectroscopy Aims and scope

FT-IR and Raman spectra were measured and structurally interpreted for glasses of the 41P2O5·8SiO2·6K2O·(26 – x) MgO·(19 – y)CaO·(x+y)MnO2 system where 0 ≤ x+y ≤ 40 mol.%, acting as slow-release fertilizers. It was shown that increasing the amount of MnO2 in the structure of the investigated glasses causes their gradual depolymerization, as is particularly apparent in the case of the phospho-oxygen subnetwork. Spectroscopic methods, on the other hand, showed no influence of manganese ions on the silicate subnetwork. Research on the chemical activity of the analyzed glasses conducted under conditions simulating a natural soil environment showed their low solubility with a simultaneous gradual increase in solubility occurring with an increasing number of manganese ions in the glass composition. It was found that this behavior resulted from the formation of less chemically stable bonds of the P–O–Mn2+ type, as compared with bonds of the P–O–Ca2+ and P–O–Mg2+ types. This is consistent with the depolymerizing influence of manganese ions on the analyzed vitreous structure as shown by the FT-IR and Raman spectroscopy and, thus, its weakening.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Karabulut, E. Metwalli, D. E. Day, and R. K. Brow, J. Non-Cryst. Solids, 328, 199–206 (2003).

  2. D. Toloman, L. M. Giurgiu, and I. Ardelean, Physica B, 404, 4198–4201 (2009).

    Article  ADS  Google Scholar 

  3. S. P. Singh, R. P. S. Chakradhar, J. L. Rao, and B. Karmakar, Physica B, 405, 2157–2161 (2010).

    Article  ADS  Google Scholar 

  4. S. P. Singh, R. P. S. Chakradhar, J. L. Rao, and B. Karmakar, J. Alloys Compd., 493, 256–262 (2010).

    Article  Google Scholar 

  5. T. Sankarappa, G. B. Devidas, M. P. Kumar, S. Kumar, and B. V. Kumar, J. Alloys Compd., 469, 576–579 (2009).

    Article  Google Scholar 

  6. K. Srilatha, K. Sambasiva Rao, Y. Gandhi, V. Ravikumar, and N. Veeraiah, J. Alloys Compd., 507, 391–398 (2010).

    Article  Google Scholar 

  7. R. K. Singh and A. Srinivasan. J. Magn. Magn. Mater., 322, 2018–2022 (2010).

    Article  ADS  Google Scholar 

  8. P. Pascuta, G. Borodi, A. Popa, V. Dan, and E. Culea, Mater. Chem. Phys., 123, 767–771 (2010).

    Article  Google Scholar 

  9. P. Pascuta, G. Borodi, N. Jumate, I. Vida-Simiti, D. Viorel, and E. Culea, J. Alloys Compd., 504, 479–483 (2010).

    Article  Google Scholar 

  10. I. Bratu, I. Ardelean, A. Barbu, V. Mih, D. Maniu, and G. Botezan, J. Mol. Struct., 482-483, 689–692 (1999).

  11. N. Krishna Mohan, M. Rami Reddy, C. K. Jayasankar, and N. Veeraiah, J. Alloys Compd., 458, 66–76 (2008).

    Article  Google Scholar 

  12. M. Sava, B. A. Sava, L. Boroica, A. Diaconu, L. D. Ursu, and M. Elisa, Efficiency of Vitreous Phospha to-Potassium Fertilizers on Autumn Crops, Scientific Papers, UASVM Bucharest, Series A, Vol. LIII, 2010.

  13. G. Hazra, T. Das, and A. Global, J. Sci. Frontier Res. B: Chemistry, 14, No. 4, Version 1.0 (2014).

  14. H. Kwan Lee, S. Jian Hwang, and W. Ho Kang, Mater. Sci. Forum, 486–487, 407–410 (2005).

  15. S. Patterson, The Role of Manganese in Plants — How to Fix Manganese Deficiencies, http://www.gardeningknowhow.com.

  16. J. Zarzycki, Glass and Vitreous State, Pergamon Press, Oxford (1991).

    Google Scholar 

  17. R. Hill, J. Mater. Sci. Lett., 15, 1122–1125 (1996).

  18. J. Oliveira, R. Correia, M. Fernandes, Biomaterials, 23, 371–379 (2002).

    Article  Google Scholar 

  19. Ö. H. Andersson, Guizhi Liu, K. H. Karlsson, L. Niemi, J. Miettinen, J. Juhanoja. J. Mater. Sci., 1, 219–227 (1990).

  20. O. Andersson, A. Sodergard, J. Non-Cryst. Solids, 246, 9–15 (1999).

  21. S. Kapoor et all, Acta Biomater., 10, 3264–3278 (2014).

  22. M. Handke, W. Mozgawa, and M. Nocuń, J. Mol. Struct., 325, 129–136 (1994).

  23. T. Litynski, H. Jurgowska, and E. Gorlach, Chemical Analysis for Agriculture, PWN, Warsaw (1976) (in Polish).

  24. A. Bartecki and J. Burgess, The Colour of Metal Compounds, Gordon and Breach Science (1993).

  25. R. K. Brow, J. Non-Cryst. Solids, 263&264, 1–28 (2000).

  26. S. W. Martin, Eur. J. Solid State Inorg. Chem., 28, 163–205 (1991).

    Google Scholar 

  27. S. Y. Marzouk, Mater. Chem. Phys., 114, 188–193 (2009).

    Article  Google Scholar 

  28. L. Abbas, L. Bih, A. Nadii, and Y. Elamraui, J. Therm. Anal. Calorim., 90, 453–458 (2007).

  29. M. Elisa, B. A. Sava, R. Iordanescu, I. Feraru, C. Vasiliu, M. Calin, A. Diaconu, L. D. Ursu, L. Boroica, Z. Plaiasu, F. Nastase, C. Nastase, A. Dumitru. J. Optoelectron. Adv. Mater., 4, 1301–1303 (2010).

    Google Scholar 

  30. F. H. ElBatal, Y. M. Hamdy, and S. Y. Marzouk, J. Non-Cryst. Solids, 355, 2439–2447 (2009).

  31. I. R. Chakraborty and R. A. Condrate, Phys. Chem. Glasses, 26, 68–73 (1985).

    Google Scholar 

  32. A. F. Wells, Structural Inorganic Chemistry, Vol. 1, Univ. Press, Oxford (1986).

  33. L. Stoch and T. Aboud, Ceramics 43, Polish Ceram. Bull., 5, 267–274 (1993).

  34. M. Szumera, Spectrochim. Acta A: Mol. Biomol. Spectrosc., 129, 601–608 (2014).

    Article  ADS  Google Scholar 

  35. I. Ardelean, S. Cora, R. C. Lucacel, and O. Hulpus, Solid State Sci., 7, 1438–1442 (2005).

    Article  ADS  Google Scholar 

  36. J. Sułowska, I. Wacławska, and Z. Olejniczak, Vib. Spectrosc., 65, 44–49 (2013).

    Article  Google Scholar 

  37. M. Sitarz, J. Mol. Struct., 887, 237–248 (2008).

    Article  ADS  Google Scholar 

  38. M. Sitarz, J. Non-Cryst. Solids, 357, 1603–1608 (2011).

  39. W. Jastrzębski, M. Sitarz, M. Rokita, and K. Bułat, Spectrochim. Acta A: Mol. Biomol. Spectrosc., 79, 722–727 (2011).

    Article  ADS  Google Scholar 

  40. J. Šubcík, L. Koudelka, P. Mošner, L. Montagne, G. Tricot, L. Delevoye, and I. Gregora, J. Non-Cryst. Solids, 356, 2509–2516 (2010).

  41. M. El Hezzat, M. Et-Tabirou, L. Montagne, E. Bekaert, G. Plavit, A. Mazzah, and P. Dhamelincourt, Mater. Lett., 58, 60–66 (2003).

    Article  Google Scholar 

  42. A. Šantic, A. Moguš-Milankovic, K. Furic, V. Bermanec, C. W. Kim, and D. E. Day, J. Non-Cryst. Solids, 353, 1070–1077 (2007).

  43. S. Sreehari Sastry, and B. Rupa Venkateswara Rao, Bull. Mater. Sci., 38, 475–482 (2015).

  44. S. Agathopoulos, D.U. Tulyaganov, J. M. G. Ventura, S. Kannan, A. Saranti, M. A. Karakassides, and J. M. F. Ferreira, J. Non-Cryts. Solids, 352, 322–328 (2006).

  45. M. Szumera, I. Wacławska, and J. Sułowska, J. Therm. Anal. Cal., 123, 1083–1089 (2016).

  46. R. K. Brow, D. R. Tallant, Sharon T. Myers, and C. C. Phifer, J. Non-Cryst. Solids, 191, 45–55 (1995).

  47. L. Koudelka, I. Rösslerová, J. Holubová, P. Mošner, L. Montagne, and B. Revel, J. Non-Cryst. Solids, 357, 2816–2821 (2011).

  48. N. Santos, K. Yukimitu, A. R. Zanata, and A. C. Hernandes, Nucl. Instrum. Methods, B, 246, 374–378 (2006).

  49. C. M. Julien, M. Massot, and C. Poinsignon, Spectrochim. Acta A, 60, 689–700 (2004).

    Article  ADS  Google Scholar 

  50. F. H. ElBatal, M. A. Ouis, R. M. Morsi, and S. Y. Marzouk, Philos. Mag., 90, 2905–2924 (2010).

    Article  ADS  Google Scholar 

  51. E. Görlich, The Effective Charges and the Electronegativity, Polish Academy of Art and Science, Krakow (1997).

    Google Scholar 

  52. L. Stoch, Ceramics, 61, 47–55 (2000).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. AGH University of Science and Technology, Krakow, Poland

    M. Szumera & B. Łagowska

Authors
  1. M. Szumera
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. Łagowska
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. Szumera.

Additional information

Published in Zhurnal Prikladnoi Spektroskopii, Vol. 83, No. 6, pp. 898–905, November–December, 2016.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Szumera, M., Łagowska, B. Spectroscopic Studies of MnO2 and SiO2 Containing Soil-Active Phosphate Glasses. J Appl Spectrosc 83, 951–958 (2017). https://doi.org/10.1007/s10812-017-0389-3

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10812-017-0389-3

Keywords

Search

Navigation