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Quantitative 31P NMR for Simultaneous Trace Analysis of Organophosphorus Pesticides in Aqueous Media Using the Stir Bar Sorptive Extraction Method

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Journal of Applied Spectroscopy Aims and scope

The analysis of pesticides in water samples is of primary concern for quality control laboratories due to the toxicity of these compounds and their associated public health risk. A novel analytical method based on stir bar sorptive extraction (SBSE), followed by 31P quantitative nuclear magnetic resonance (31P QNMR), has been developed for simultaneously monitoring and determining four organophosphorus pesticides (OPPs) in aqueous media. The effects of factors on the extraction efficiency of OPPs were investigated using a Draper–Lin small composite design. An optimal sample volume of 4.2 mL, extraction time of 96 min, extraction temperature of 42°C, and desorption time of 11 min were obtained. The results showed reasonable linearity ranges for all pesticides with correlation coefficients greater than 0.9920. The limit of quantification (LOQ) ranged from 0.1 to 2.60 mg/L, and the recoveries of spiked river water samples were from 82 to 94% with relative standard deviation (RSD) values less than 4%. The results show that this method is simple, selective, rapid, and can be applied to other sample matrices.

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Author information

Authors and Affiliations

  1. Alzahra University, Vanak, Tehran, Iran

    S. Ansari & Z. Talebpour

  2. Faculty of Science, Tarbiat Modarres University, Tehran, Iran

    F. Molaabasi

  3. Tarbiat Modarres University, Tehran, Iran

    H. R. Bijanzadeh

  4. College of Art & Science, Southern Illinois University Edwardsville, Edwardsville, Illinois, USA

    S. Khazaeli

Authors
  1. S. Ansari
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  2. Z. Talebpour
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  3. F. Molaabasi
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  4. H. R. Bijanzadeh
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  5. S. Khazaeli
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Corresponding author

Correspondence to Z. Talebpour.

Additional information

Abstract of article is published in Zhurnal Prikladnoi Spektroskopii, Vol. 83, No. 4, p. 670, July–August, 2016.

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Ansari, S., Talebpour, Z., Molaabasi, F. et al. Quantitative 31P NMR for Simultaneous Trace Analysis of Organophosphorus Pesticides in Aqueous Media Using the Stir Bar Sorptive Extraction Method. J Appl Spectrosc 83, 717–721 (2016). https://doi.org/10.1007/s10812-016-0353-7

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  • DOI: https://doi.org/10.1007/s10812-016-0353-7

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