Absorption, fluorescence excitation, and fluorescence spectra and the fluorescence polarization as a function of emission wavelength were measured at 77 K for glassy EtOH solutions of 2,3-diazabicyclo[2.2.2]oct-2-ene and 1,4-dimethyl-(2,3-diazabicyclo[2.2.2]oct-2-ene). It was concluded from an analysis of the results that two excited electronic states were responsible for the emission of these compounds. The transition dipole moment vectors from the ground state into the excited ones were mutually perpendicular so that the corresponding spectra were shifted.
Similar content being viewed by others
References
A. P. Lugovskii, V. A. Povedailo, V. A. Tolkachev, and D. L. Yakovlev, Opt. Spektrosk., 114, No. 3, 390–395 (2013).
P. P. Feofilov, Polarized Luminescence of Atoms, Molecules, and Crystals [in Russian], Gos. Izd. Fiz.-Mat. Lit., Moscow (1959).
V. A. Gaisenok and A. M. Sarzhevskii, Absorption and Luminescence Anisotropy of Polyatomic Molecules [in Russian], Universitetskoe, Minsk (1986).
J. Mohanty and W. M. Nau, Photochem. Photobiol. Sci., 3, 1026–1031 (2004).
S. L. Murov, I. Carmichael, and G. L. Hug, Handbook of Photochemistry, Marcel Dekker, New York (1993).
B. S. Solomon, T. F. Thomas, and C. Steel, J. Am. Chem. Soc., 90, No. 9, 2249–2258 (1968).
H. Rau, H. Durr, and H. Bouas-Laurent, Photochromism, Elsevier Science, Amsterdam (2003), pp. 165–192.
K. N. Solov’ev, L. L. Gladkov, A. S. Starukhin, and S. F. Shkirman, Spectroscopy of Porphyrins: Vibrational States [in Russian], Nauka i Tekhnika, Minsk (1985).
N. A. Borisevich, V. A. Povedailo, and D. L. Yakovlev, Opt. Spekstrosk., 100, No. 3, 393–399 (2006).
E. Lippert, W. Luder, F. Moll, W. Nagele, H. Boos, H. Prigge, and I. Seybold-Blankenstein, Angew. Chem., 73, 695–699 (1961).
I. E. Zalesskii, V. N. Kotlo, K. N. Solov’ev, and S. F. Shkirman, Zh. Prikl. Spektrosk., 20, No. 6, 1010–1015 (1974).
S. S. Dvornikov, V. N. Knyukshto, K. N. Solovjov, and M. P. Tsvirko, J. Lumin., 18–19, 491–495 (1978).
B. Valeur and G. Weber, Photochem. Photobiol., 25, 441–444 (1977).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 81, No. 3, pp. 356–360, May–June, 2014.
Rights and permissions
About this article
Cite this article
Lugovskii, A.P., Povedailo, V.A. & Yakovlev, D.L. Anisotropy of Dual Fluorescence of 2,3-Diazabicyclo[2.2.2]Oct-2-Ene and 1,4-Dimethyl-(2,3-Diazabicyclo[2.2.2]Oct-2-Ene). J Appl Spectrosc 81, 377–380 (2014). https://doi.org/10.1007/s10812-014-9940-7
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10812-014-9940-7