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Bifunctional electrocatalysts for oxygen reduction/evolution reactions derived from NiCoFe LDH materials

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Abstract

Materials obtained from thermal treatment of thermally treated NiCoFe-layered double hydroxides (LDH) with different Ni:Co ratios were evaluated as bifunctional catalysts for Oxygen Reduction Evolution and Evolution Reduction Reactions in alkaline media. The structural properties of synthesized materials were characterized by X-ray diffraction, Fourier-transform infrared, Raman, and X-ray photoelectron spectroscopies, whereas the basicity of each material was evaluated by temperature-programmed desorption of carbon dioxide. The results revealed the presence of inverse spinel structure with different compositions and a NiO phase with different amounts in the sample, while the electrochemical results showed a high activity towards oxygen reactions. The sample with higher amount of NiO and the lowest substitution grade on tetrahedral sites in the spinel-type structure exhibited the best catalytic activity.

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Acknowledgements

The authors would like to thank the Instituto Politécnico Nacional for the financial support received through the multidisciplinary project 1820, and also the CONACYT project CEMIE-Ocean-249795: Transversal Line I-LT1.

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Authors and Affiliations

  1. Laboratorio de Electroquímica y Corrosión, Departamento de Ingeniería Química Instituto Politécnico Nacional, ESIQIE, UPALM Edif. 7 P.B. Zacatenco, GAM, 07738, Mexico, DF, Mexico

    M. Oliver-Tolentino & R. de G. Gonzalez-Huerta

  2. Laboratorio Nacional de Conversión y Almacenamiento de Energía, Instituto Politécnico Nacional, CICATA, Calzada Legaria 694, Col. Irrigación, 11500, Mexico, DF, Mexico

    J. Vazquez-Samperio

  3. Laboratorio de Física Avanzada, Instituto Politécnico Nacional, ESFM, UPALM Edif. 9 Zacatenco, GAM, 07738, México, DF, Mexico

    M. Tufiño-Velázquez

  4. Área de Química de Materiales, Universidad Autónoma Metropolitana-Azcapotzalco, Av.SanPablo180, Col. Reynosa Tamaulipas, 02200, Mexico, DF, Mexico

    J. Flores-Moreno

  5. Centro de Nanociencias y Micro y Nanotecnología (CNMN), Instituto Politécnico Nacional, Luis Enrique Erro s/n, UPALM, Col. Zacatenco, GAM, 07738, Mexico, DF, Mexico

    L. Lartundo-Rojas

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  1. M. Oliver-Tolentino
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  3. M. Tufiño-Velázquez
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  5. L. Lartundo-Rojas
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  6. R. de G. Gonzalez-Huerta
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Correspondence to M. Oliver-Tolentino or R. de G. Gonzalez-Huerta.

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Oliver-Tolentino, M., Vazquez-Samperio, J., Tufiño-Velázquez, M. et al. Bifunctional electrocatalysts for oxygen reduction/evolution reactions derived from NiCoFe LDH materials. J Appl Electrochem 48, 947–957 (2018). https://doi.org/10.1007/s10800-018-1210-6

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  • DOI: https://doi.org/10.1007/s10800-018-1210-6

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