Abstract
We have carried out the theoretical and experimental time evolution and amplitude study of the photothermal mirror signal generated by focusing a laser beam on the surface of a suite of solid samples. Based on a theoretical model that resolves the thermal diffusivity equation and the equation for thermo-elastic deformations simultaneously, we have calculated the transient time evolution and amplitude of the signal. We observe the same time evolution pattern for samples as diverse as glass, quartz, metals, and synthetic ceramic oxides. The data have yielded a linear dependence between the time build-up of the thermal mirror and the inverse of the thermal diffusivity for all the samples. For moderate power levels, we also observe a linear behavior between the stationary value of the signal and the thermally induced phase shift value. From the calibration curves, we have determined the thermally induced phase and the thermal diffusivity coefficients of two prospective nuclear reactor control rod materials, dysprosium titanate (\(\hbox {Dy}_{2}\hbox {TiO}_{5}\)) and dysprosium dititanate (\(\hbox {Dy}_{2}\hbox {Ti}_{2}\hbox {O}_{7}\)) to be \(D = (7.0 \pm 0.4) \times 10^{-7} \mathrm{m^{2}\cdot s^{-1}}\).
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References
P. Kuo, M. Munidasa, Single-beam interferometry of a thermal bump. Appl. Opt. 29, 5326–5331 (1990)
B.C. Li, Z. Zhen, S. He, Modulated photothermal deformation in solids. J. Phys. D Appl. Phys. 24, 2196–2201 (1991)
T. Elperin, G. Rudin, Thermal mirror method for measuring physical properties of multilayered coatings. Int. J. Thermophys. 28, 60–82 (2007)
N.G.C. Astrath, L.C. Malacarne, P.R.B. Pedreira, A.C. Bento, M.L. Baesso, J. Shen, Time-resolved thermal mirror for nanoscale surface displacement detection in low absorbing solids. Appl. Phys. Lett. 91, 191908 (2007)
F. Sato, L.C. Malacarne, P.R.B. Pedreira, M.P. Belancon, R.S. Mendes, M.L. Baesso, N.G.C. Astrath, J. Shen, Time-resolved thermal mirror method: a theoretical study. J. Appl. Phys. 104, 053520 (2008)
N.G.C. Astrath, L.C. Malacarne, V.S. Zanuto, M.P. Belancon, R.S. Mendes, M.L. Baesso, C. Jacinto, Finite-size effect on the surface deformation thermal mirror method. J. Opt. Soc. Am. B 28, 1735–1739 (2011)
L.C. Malacarne, N.G.C. Astrath, G.V.B. Lukasievicz, E.K. Lenzi, M.L. Baesso, S.E. Bialkowski, Time-resolved thermal lens and thermal mirror spectroscopy with sample-fluid heat coupling: a complete model for material characterization. Appl. Spectrosc. 65, 99–104 (2011)
G.V.B. Lukasievicz, L.C. Malacarne, N.G.C. Astrath, V.S. Zanuto, L.S. Herculano, S.E. Bialkowski, A theoretical and experimental study of time-resolved thermal mirror with non-absorbing heat coupling fluids. Appl. Spectrosc. 66, 1461–1467 (2012)
O.S. Aretegui, P.Y.N. Poma, L.S. Herculano, G.V.B. Lukasievicz, F.B. Guimaraes, L.C. Malacarne, M.L. Baesso, S.E. Bialkowski, N.G.C. Astrath, Combined photothermal lens and photothermal mirror characterization of polymers. Appl. Spectrosc. 68, 777–783 (2014)
A. Marcano, G. Gwanmesia, M. King, D. Caballero, Determination of thermal diffusivity of opaque materials using the photothermal mirror method. Opt. Eng. 53, 127101 (2014). doi:10.1117/1.OE.53.12.127101
A. Marcano, H. Cabrera, M. Guerra, R.A. Cruz, C. Jacinto, T. Catunda, Optimizing and calibrating a mode-mismatched thermal lens experiment for low absorption measurement. J. Opt. Soc. Am. B 23, 1408–1413 (2006)
A. Marcano, C. Loper, N. Melikechi, Pump probe mode mismatched Z-scan. J. Opt. Soc. Am. B 19, 119–124 (2002)
J. Shen, R.D. Lowe, R.D. Snook, A model for cw laser induced mode-mismatched dual-beam thermal lens spectrometry. Chem. Phys. 165, 385–396 (1992). doi:10.1016/0301-0104(92)87053-C
M.L. Baesso, J. Shen, R.D. Snook, Three dimensional model for cw laser-induced mode-mismatched dual-beam thermal lens spectrometry and time resolved measurements of thin-film spectra. J. Appl. Phys. 75, 3738–3748 (1994). doi:10.1063/1.356045
D.R. Lide (ed.), CRC handbook of chemistry and physics, 86th edn. (CRC Press, Boca Raton, 2005) ISBN 0-8493-0486-5
B.H.W.S. De Jong, R.G.C. Beerkens, P.A. van Nijnatten, Glass. Ullmann’s encyclopedia of industrial chemistry (2000). doi:10.1002/14356007.a12_365 ISBN3-527-30673-0
R.H. Perry, D.W. Green (eds.), Perry’s chemical engineers’ handbook, 7th edn. (McGraw-Hill, New York, 1997). Table 1–4. ISBN 978-0-07-049841-9
Y. Takahashi, E.F. Westrum Jr., Glassy carbon low-temperature thermodynamic properties. J. Chem. Thermodyn. 2, 847–854 (1970)
http://www.tokaicarbon.co.jp/en/products/fine_carbon/gc/html
C. Garion, Mechanical properties for reliability analysis of structures in glassy carbon. World J. Mech. 4, 79–89 (2014). doi:10.4236/wjm.2014.43009
G. Panneerselvam, R.V. Krishnan, M.P. Antony, K. Nagarajan, T. Vasudevan, P.R.V. Rao, Thermophysical measurements on dysprosium and gadolinium titanates. J. Nucl. Sci. 327, 220–225 (2004)
V.D. Risovany, E.E. Varlashova, D.N. Suslov, Dysprosium titanate as an absorber material for control rods. J. Nucl. Sci. 281, 84–89 (2000)
Acknowledgements
The synthetic polycrystalline dysprosium specimens, used in this study, were hot-pressed using the large-volume, Kawai-type multi-anvil high-pressure apparatus in the High-Pressure laboratory at the Mineral Physics Institute (MPI), in the Geosciences Department at the Stony Brook University, in New York.
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Marcano, A., Gwanmesia, G. & Workie, B. Photothermal Mirror Method for the Study of Thermal Diffusivity and Thermo-Elastic Properties of Opaque Solid Materials. Int J Thermophys 38, 136 (2017). https://doi.org/10.1007/s10765-017-2276-9
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DOI: https://doi.org/10.1007/s10765-017-2276-9