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Local fields in Co and Mn Co-doped ZnO

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Abstract

The magnetic properties of ZnO co-doped with 5 at. % Co and 5 at. % Mn(Zn0.90Co0.05Mn0.05O) synthesized by a solid-state reaction were investigated by means of 57Co emission Mössbauer spectroscopy. The majority of the probe ions (80 %) residing in defect-free substitutional Zn sites take the oxidation state of 57Fe 2+, and the others presumably form local defects taking the state of 57Fe 3+ at room temperature. Both components show doublets, and RT ferromagnetism was thus absent in the sample. For the measurement at 10 K, spectral broadening was observed, implying a possible presence of a weak magnetic component.

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Authors and Affiliations

  1. Institute of Science and Engineering, Kanazawa University, Kakumamachi, Kanazawa, Ishikawa, 920-1192, Japan

    W. Sato

  2. Graduate School of Natural Science and Technology, Kanazawa University, Kakumamachi, Kanazawa, Ishikawa, 920-1192, Japan

    W. Sato, Y. Kano, T. Suzuki & M. Nakagawa

  3. Department of Engineering Science, The University of Electro-Communications, Chofugaoka, Chofu, Tokyo, 182-8585, Japan

    Y. Kobayashi

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  1. W. Sato
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  2. Y. Kano
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  3. T. Suzuki
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  4. M. Nakagawa
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  5. Y. Kobayashi
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Correspondence to W. Sato.

Additional information

This article is part of the Topical Collection on Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2015), Hamburg, Germany, 13–18 September 2015

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Sato, W., Kano, Y., Suzuki, T. et al. Local fields in Co and Mn Co-doped ZnO. Hyperfine Interact 237, 28 (2016). https://doi.org/10.1007/s10751-016-1231-7

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  • DOI: https://doi.org/10.1007/s10751-016-1231-7

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