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Effect of Acrylate Monomer on the Characteristics of Photopolymerizable Suspensions for Obtaining Ceramic from Stabilized ZrO2

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The effect of the structure and properties of acrylate monomers on the rheology and polymerization of suspensions containing partially stabilized zirconia, a dispersant, and a photoinitiator as a ceramic filler was investigated. It was shown that the addition of DISPERBYK 2013 to 1,6-hexanediol diacrylate, dipropyleneglycol to diacrylate, and tripropyleneglycol to diacrylate makes it possible to obtain suspensions with viscosity < 5 Pa · sec at high filling with TZ-3YS-Z powder (up to 41 vol.%). It was determined that three-dimensional printing of high-density ceramic products with complex geometry is made possible by using the obtained suspensions.

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References

  1. Q. Lian,W. Sui, X.Wu, et al., “Additive manufacturing of ZrO2 ceramic dental bridges by stereolithography,” Rapid Prototyping J., 24(1), 114 – 119 (2018); https://doi.org/10.1108/RPJ-09-2016-0144.

  2. M. Borlaf, A. Serra-Capdevila, C. Colominas, and T. Graule, “Development of UV-curable ZrO2 slurries for additive manufacturing (LCM-DLP) technology,” J. Eurp. Ceram. Soc., 39(13), 3797 – 3803 (2019); https://doi.org/10.1016/j.jeurceramsoc.2019.05.023.

    Article  CAS  Google Scholar 

  3. K. Zhang, R. He, G. Wang, et al. “Photosensitive ZrO2 suspensions for stereolithography,” Ceram. Int., 45(9), 12189 – 12195; https://doi.org/10.1016/j.ceramint.2019.03.123.

  4. K. Zhang, C. Xie, G. Wang, et al., “High solid loading, low viscosity photosensitive Al2O3 slurry for stereolithography based additive manufacturing,” Ceram. Int., 45(1), 203 – 208 (2019); https://doi.org/10.1016/j.ceramint.2018.09.152.

    Article  CAS  Google Scholar 

  5. J. Hostaša, M. Schwentenwein, G. Toci, et al. “Transparent laser ceramics by stereolithography,” Scr. Mater., 187, 194 – 196 (2020); https://doi.org/10.1016/j.scriptamat.2020.06.006.

    Article  CAS  Google Scholar 

  6. L. Ji, W. Chang, M. Cui, et al., “Photopolymerization kinetics and volume shrinkage of 1,6-hexanediol diacrylate at different temperature,” J. Photochem. Photobiol. A: Chem., 252, 216 – 221 (2013); https://doi.org/10.1016/j.jphotochem.2012.12.010.

    Article  CAS  Google Scholar 

  7. IL Camargo, R. Erbereli, H. Taylor, et al., “3Y-TZP DLP additive manufacturing: solvent-free slurry development and characterization,” Mater. Res., 24, e20200457; https://doi.org/10.1590/1980-5373-MR2020-0457.

  8. L. Ma, B. Huang, C. Wei, et al., “Study on volume shrinkage performance of 3D printing materials,” Adv. Graphic Commun., Print. Pack. Technol., 715 – 721 (2020); https://doi.org/10.1007/978-981-15-1864-5 97

  9. Technical Data Sheet, DISPERBYK 2013. URL: https://www.byk.com/en/products/additives-byname/disperbyk-2013 (accessed: 03/06/2022)

  10. J. Bonada, P. Barcelona, M. Casafont, et al., “Analysis of the compression behavior of reinforced photocurable materials used in additive manufacturing processes based on a mask image projection system,” Materials, 14(16), 4605 (2021); https://doi.org/10.3390/ma14164605.

    Article  CAS  Google Scholar 

  11. P. S. Sokolov, D. A. Komissarenko, G. A. Dosovitsky, et al., “Rheological properties of zirconium oxide suspensions in acrylate monomers for use in 3D printing,” Glass Ceram., 75(1 – 2), 55 – 59 (2018); https://doi.org/10.1007/s10717-018-0028-3.

    Article  CAS  Google Scholar 

  12. D. A. Komissarenko, P. S. Sokolov, A. D. Evstigneeva, et al., “DLP 3D printing of scandia-stabilized zirconia ceramics,” J. Eurp. Ceram. Soc., 41(1), 684 – 690 (2021); https://doi.org/10.1016/j.jeurceramsoc.2020.09.010.

    Article  CAS  Google Scholar 

  13. D. A. Komissarenko, P. S. Sokolov, A. D. Evstigneeva, et al., “Rheological and curing behavior of acrylate-based suspensions for the DLP 3D printing of complex zirconia parts,” Materials, 11(12), 2350 (2018); https://doi.org/10.3390/ma11122350.

    Article  CAS  Google Scholar 

  14. I. I. Preobrazhenskiy, A. A. Tikhonov, P. V. Evdokimov, et al., “DLP printing of hydrogel/calcium phosphate composites for the treatment of bone defects,” Open Ceram., 6, 100115 (2021); https://doi.org/10.1016/j.oceram.2021.100115.

  15. P. F. Jacobs, Rapid Prototyping & Manufacturing: Fundamentals of Stereolithography, Society of Manufacturing Engineers, Dearborn (1992).

    Google Scholar 

  16. I. M. Krieger and T. J. Dougherty, “A mechanism for non-Newtonian flow in suspensions of rigid spheres,” Trans. Soc. Rheology, 3(1), 137 – 152 (1959); https://doi.org/10.1122/1.548848.

    Article  CAS  Google Scholar 

  17. A. Einstein, “Berichtigung zu meiner Arbeit: Eine neue Bestimmung der Moleküldimensionen,” Ann. Phys., 339, 591 – 592 (1911); https://doi.org/10.1002/andp.19113390313.

    Article  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Reagents and Highly Pure Chemical Substances, National Research Center Kurchatov Institute, Moscow, Russia

    L. V. Ermakova, D. E. Kuznetsova, D. S. Poplevin, V. G. Smyslova, P. V. Karpyuk, P. S. Sokolov & G. A. Dosovitskii

  2. National Research Center Kurchatov Institute, Moscow, Russia

    L. V. Ermakova, D. E. Kuznetsova, D. S. Poplevin, V. G. Smyslova, P. V. Karpyuk, P. S. Sokolov & G. A. Dosovitskii

  3. D. I. Mendeleev, Russian University of Chemical Technology, Moscow, Russia

    S. V. Chizhevskaya

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  1. L. V. Ermakova
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  2. D. E. Kuznetsova
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  3. D. S. Poplevin
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  4. V. G. Smyslova
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  6. P. S. Sokolov
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  7. G. A. Dosovitskii
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  8. S. V. Chizhevskaya
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Correspondence to L. V. Ermakova.

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Translated from Steklo i Keramika, No. 10, pp. 3 – 10, October, 2022.

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Ermakova, L.V., Kuznetsova, D.E., Poplevin, D.S. et al. Effect of Acrylate Monomer on the Characteristics of Photopolymerizable Suspensions for Obtaining Ceramic from Stabilized ZrO2. Glass Ceram 79, 395–400 (2023). https://doi.org/10.1007/s10717-023-00520-w

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  • DOI: https://doi.org/10.1007/s10717-023-00520-w

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