Enamel coatings for protecting ozonizer electrodes were obtained in the system PbO–B2O3–Sb2O3–SiO2 with variable content of silicon oxide and antimony oxide. The results showed that enamel with antimony oxide content 5 wt.% possesses the best combination of thermal, thermomechanical, and electrical properties in combination with the required covering power.
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References
V. V. Lunin, M. P. Popovich, and S. N. Tkachenko, Physical Chemistry of Ozone [in Russian], Izd. MGU, Moscow (1998).
Proceedings of the 1st All-Russia Conference on Ozone and Other Environmentally Friendly Oxidants. Science and Technology, Dedicated to the 250th Anniversary of Lomonosov Moscow State University [in Russian], Knizhnii dom Universitet, Moscow (2005).
E. N. Kablov, Tendencies and Turning Points for the Innovative Development of Russia: Collection of Articles: Collection of Informative Articles [in Russian], VIAM, Moscow (2015).
E. N. Kablov, “New-generation materials: the basis of innovation, technological leadership, and national security of Russia,” Intelekt i Tekhnologii, No. 2(14), 16 – 21 (2016).
E. N. Kablov, “Innovative development work at FGUP VIAM GNTs RF on implementation of ‘Strategic directions for the development of materials and their processing technologies for the period up to 2030’,” Aviats. Mater. Tekhnol., No. 1, 3 – 33 (2015); https://doi.org/10.18577/2071-9140-2015-0-1-3-33.
D. V. Grashchenkov, “Development strategy for nonmetallic materials, metal composite materials and thermal protection,” Aviats. Mater. Tekhnol., No. S, 264 – 271 (2017); https://doi.org/10.8577/2071-9140-2017-0-S264-271.
E. N. Kablov, “Role of fundamental research in the creation of new generation materials,” in: Abstracts of the 21st Mendeleev Congress on General and Applied Chemistry, Vol. 2a [in Russian], St. Petersburg (2019).
A. Petzold and G. Peshman, Handbook of Enamel and Enameling [in Russian], Moscow (1990), pp. 72 – 74.
S. S. Solntsev, V. S. Denisova, A. B. Agarkov, and S. V. Gavrilov, “Effect of glass additives from the BaO–Al2O3–SiO2 system on the properties of reaction-cured coatings for protection of nickel alloys,” Tr. VIAM: Elektron. Nauch.-Tekhn. Zh., No. 1, Art. 11 (2018); URL: http://www.viam-works.ru (date of access: 06.23.2021); https://doi.org/10.18577/2307-6046-2018-0-1-11-11.
G. A. Malinina, S. V. Stefanovskii, O. I. Stefanovskaya, et al., “Structural position of samarium in glass-ceramic materials,” Tr. VIAM: elektron. Nauch.-tekhn. Zh., No. 6, Art. 03 (2019); URL: http://www.viam-works.ru (date of access: 06.23.2021); https://doi.org/10.18577/2307-6046-2019-0-6-20-31.
G. A. Malinina, V. S. Denisova, S. S. Solntsev, and M. L. Vaganova, “Study of the effect of oxide additives on the properties of heat-resistant glass-crystalline coating,” Tr. VIAM: Elektron. Nauch.-Tekhn. Zh., No. 5, Art. 09 (2021), No. 5, Art. 09 (2021); URL: http://www.viam-works.ru (date of access: 06.23.2021); https://doi.org/10.18577/2307-6046-2021-0-5-87-95.
A. G. Chigvintsev and T. M. Malygina, “Ground-coat enamel for steel, Pat. SU 1470685 A1 USSR, No. 4244247,” Byull. Izobr. Polezn. Modeli, No. 13 (1989), appl. 05/13/1987, publ. 04/07/1989.
A. S. Eskov,M. I. Oleinik, E. A. Shabrova, et al., “Enamel coating for ozonizer electrodes, Pat. SU 823330 A1 USSR, No. 2761488,” Byull. Izobr. Polezn. Modeli, No. 15 (1981), appl. 04/28/1979, publ. 04/23/1981.
N. M. Bobkova, M. P. Glasova, and E. S. Kashuba, “Frit for enamel coating on steel, Pat. SU 1539174 A1 SSSR, No. 4304341,” Byull. Izobr. Polezn. Modeli (1990), appl. 09/11/1987, publ. 01/30/1990.
M. A. Semin and N. Yu. Khmelnova, “Electrical insulating enamel for stainless steel parts, Pat. 2203233 RF, No. 99107068/03,” Byull. Izobr. Polezn. Modeli (2003), declared 04/15/1999, publ. 04/27/2003.
V. V. Danilin, M. P. Kokurkin, M. A. Semin, and A. I. Smorodin, “Electrical insulating enamel for stainless steel parts, Pat. 2264994 RF, No. 2004112723/03,” Byull. Izobr. Polezn. Modeli, No. 33 (2005), declared 04/26/2004, publ. November 27, 2005.
N. I. Puresev, O. A. Pureseva, E. A. Gordeenya, et al., “Electrical insulating glass enamel for stainless steel products, Pat. 2526445 RF, No. 2012149064/03,” Byull. Izobr. Polezn. Modeli, No. 23 (2014), declared 11/20/2012, publ. 08/20/2014.
A. V. Dorofeeva and M. A. Semin, “Protective glass coatings for steel,” Usp. Khim. Khim. Tekhnol., No. 8, 43 – 46 (2014).
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Translated from Steklo i Keramika, No. 11, pp. 16 – 22, November, 2021.
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Kulikova, O.V., Shchegoleva, N.E., Lebedeva, Y.E. et al. Insulating Enamel Based on Lead-Borate Glass. Glass Ceram 78, 436–441 (2022). https://doi.org/10.1007/s10717-022-00427-y
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DOI: https://doi.org/10.1007/s10717-022-00427-y