The structures of enamels with different iron oxide content are investigated. It is shown that the structure changes with increasing iron oxide concentration. The elevated mobility of silicon-oxygen groupings surrounded by iron cations gives rise to the restructuring of the groupings into a crystalline phase possessing minimum energy.
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V. A. Deryabin, M. Yu. Uglinskikh, and E. N. Korotkova, “Capillary motion of gas inclusions during firing of glass-coatings,” Steklo Keram., No. 8, 12 – 14 (2007); V. A. Deryabin, M. Yu. Uglinskikh, and E. N. Korotkova, “Capillary motion of gas inclusions upon annealing of glass-coatings,” Glass Ceram., 64(7 – 8), 267 – 269 (2007).
N. V. Prosvirnina, M. Yu. Uglinskikh, and V. A. Deryabin, “Thermocapillary motion of gaseous inclusions in a layer of enamel during firing,” in: Collection of Scientific Works on Materials Intern. Conf. on Current Problems of Science, Transport, Production and Education and Ways to Solve Them 2009 [in Russian], Odessa (2009), Vol. 4, pp. 66 – 68.
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Translated from Steklo i Keramika, No. 7, pp. 41 – 42, July, 2014.
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Deryabin, V.A., Uglinskikh, M.Y. Change in the Structure of Fired Glass Enamels with Different Iron Oxide Content. Glass Ceram 71, 258–259 (2014). https://doi.org/10.1007/s10717-014-9664-4
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DOI: https://doi.org/10.1007/s10717-014-9664-4