Abstract
The Bozgai open quarry in the Muntele Mare granite massif offers an excellent opportunity to investigate the influence of alteration processes on granitic rock, especially owing to the extensive exposure of granite and specific mineral assemblages of hydrothermal genesis to atmospheric conditions. The alteration processes generated secondary minerals located on the primary minerals of the affected rocks or deposited as infill material along the granite discontinuities. Natural and oriented samples of the Bozgai quarry of the infill material were investigated using polarized light microscopy, X-ray diffraction, and scanning electron microscopy to obtain images and identify their mineralogical composition. The hydrothermal vein material consists of kaolinite, illite, pyrite, marcasite, quartz, iron hydroxides, albite, and microcline. Jarosite and gypsum were also formed by the oxidization of pyrite and marcasite exposed to atmospheric oxygen and meteoric water. The secondary minerals play a particularly important role in the reduced rock slope stability in the Bozgai quarry.
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References
Afolagboye LO, Owoyemi OO, Akinola OO (2023) Effect of pH condition and different solution on the slake durability of granitic rocks. Geotech Geol Eng 41:897–906. https://doi.org/10.1007/s10706-022-02312-5
Anton DC (1999) Petrographical, geochemical and isotopic study of Mt. Mare Granitoids, North Apuseni Mountains - Evolution of paraluminous magma. Dissertation, University of Tokyo.
Balintoni I, Balica C, Cliveti M, Li L-Q, Hann H-P, Chen F, Schuller V (2009) The emplacement age of the Muntele Mare Variscan granite (Apuseni Mountains, Romania). Geol Carpath 60:495–504
Braga S, Paquet H, Begonha A (2002) Weathering of granites in a temperate climate (NW Portugal): granitic saprolites and arenization. Catena 49(1):41–56
Bustin RM, Matthews WH (1979) Selective weathering of granitic clasts. Can J Earth Sci 16:216–223
Cravotta III CA (1994). Secondary iron-sulfate minerals as sources of sulfate and acidity. In: Alpers CN, Blowes DW (eds) Environmental geochemistry of sulfide oxidation. American Chemical Society Symposium Series, vol 550, pp 345–364
Dimitrescu R (1966) Muntele Mare. A geologic and petrographic study. An Com Geol 35:165–239 ((in Romanian))
Dixon JE, Young RW (1981) Character and origin of deep arenaceous weathering mantles on the Bega Batholith, southeastern Australia. CATENA 8:97–109
Forray FL, Smith AML, Drouet C, Navrotsky A, Wright K, Hudson-Edwards KA, Dubbin WE (2010) Synthesis, characterization and thermochemistry of a Pb-jarosite. Geochim Cosmochim Ac 74:215–224
Hammarstrom JM, Seal II RR, Ouimette AP, Foster SA (2001). Sources of metals and acidity at the Elizabeth and Ely mines, Vermont: geochemistry and mineralogy of solid minewaste and the role of secondary minerals in metal recycling. In: Hammarstrom JM, Seal II RR (eds) Environmental geochemistry and mining history of massive sulfide deposits in the Vermont copper belt. Society of economic geologists guidebook series, vol 35, no II, pp 213–248
Har N, Lăzărean A, Iliescu M, Ciont N, Abrudan IF (2019) Degradation processes of iron-sulfides and calcite containing aggregates from asphaltic mixtures. Constr Build Mater 212:745–754
Hill SM (1996) The differential weathering of granitic rocks in Victoria, Australia. AGSO J Aust Geol Geophys 16:271–276
Hochella J, Michael F, Moore JN, Putnis CV, Putnis A, Kasama T, Eberl DD (2005) Direct observation of heavy metal–mineral association from the Clark Fork River Superfund Complex: implications for metal transport and bioavailability. Geochim Cosmochim Ac 69:1651–1663
Kirschbaum A, Martínez E, Pettinari G, Herrero S (2005) Weathering profiles in granites, Sierra Norte (Córdoba, Argentina). J South Am Earth Sci 19:479–493
Lebedev AL, Kosorukov VL (2017) Gypsum solubility in water at 25 °C. Geochem Int 55:205–210
Lee SY, Kim SJ, Baik MH (2008) Chemical weathering of granite under acid rainfall environment, Korea. Environ Geol 55:853–862
McGregor RG, Blowes DW, Jambor JL, Robertson WD (1998) Mobilization and attenuation of heavy metals within a nickel mine tailings impoundment near Sudbury, Ontario, Canada. Environ Geol 36:305–319
Meunier A, Velde B (1982) Phengitization, sericitization and potassium-beidellite in a hydrothermally altered granite. Clay Miner 17(3):285–299
Nordstrom DK (1982) Aqueous pyrite oxidation and the consequent formation of secondary minerals. In: Acid sulfate weathering. Soil Science Society of America, Madison, pp 37–56
Oberhardt N (2013) Granite weathering, saprolitization and the formation of secondary clay particles, SW Bornholm. Master Thesis, Department of Geosciences, Faculty of Mathematics and Natural Sciences, University of Oslo, pp 1–139
Pană D (1998) Petrogenesis and tectonics of the basement rocks of the Apuseni Mountains. Significance for the Alpine tectonics of the Carpathian-Pannonian region. Ph.D. Thesis, Univ. Alberta, Canada, pp 1–356
Panova EG, Vlasov DY, Luodes H, Vlasov AD, Popova TA, Zelenskaya MS (2016) Granite weathering in urban environments. Biog Abiog Interact Nat Anthropog Syst. https://doi.org/10.1007/978-3-319-24987-2_27,345-356
Săndulescu M (1984) Geotectonics of Romania. Ed. Tehnica, Bucuresti, pp 1–336 (in Romanian)
Ştefan A, Lazăr C, Berbeleac I, Udubaşa G (1988) Evolution of banatitic magmatism in the Apuseni Mountains and associated metallogenesis. DS Inst Geol 72–73:195–213
Sun M, Yu J, Wu X, Ding Y, Fu T, Yang Y, Jiang J (2021) Mechanical behavior of weathered granite exposed to water. Appl Sci 11(21):10356. https://doi.org/10.3390/app112110356
Wilson MJ (2004) Weathering of the primary rock-forming minerals: processes, products and rates. Clay Miner 39:233–266
Whitney DL, Evans BW (2010) Abbreviations for names of rock-forming minerals. Am Mineral 95:185–187
Wyllie DC, Mah CW (2004) Rock slope engineering: civil and mining, 4th edn. London, Spon Press
Young RW, Dixon JE (1983) Weathering and hydrothermal alteration: critique of Ollier’s argument. Catena 10:439–440
Acknowledgements
We thank Esther Posner, PhD, from Liwen Bianji, Edanz Editing China (www.liwenbianji.cn/ac), for editing the English text of a draft of this manuscript.
Funding
This study was financially supported by Babeş-Bolyai University of Cluj-Napoca through research Contract No. 35525/26.11.2019, internal competition “Special scholarships for scientific activities for students based on the research projects and dissemination of the results”.
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Har, N., Gheorghiu, R.I. Nature of Infill Material on the Discontinuities of the Muntele Mare Granite (Romania). Geotech Geol Eng 41, 4041–4055 (2023). https://doi.org/10.1007/s10706-023-02504-7
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DOI: https://doi.org/10.1007/s10706-023-02504-7