Abstract
In this study, the photocatalytic removal of Reactive Red 120 (RR120) dye was examined using zeolite 13X incorporated with Zn-Ce under UV irradiation. The synthesis of Zn-Ce nanoparticles incorporated with zeolite 13X was conducted through the co-precipitation method, and the features of the prepared nanocatalyst were analyzed using various techniques. The SEM and BET analyses indicated successful incorporation of ZnO-Ce oxides on the surface of zeolite 13X and a specific surface area of 359.39 m2/gm, respectively. Further, the average size of crystal grains was 28 nm. The response surface methodology (RSM) approach was employed to optimize operating parameters. The quadratic model suggested by the RSM approach, characterized by a high regression coefficient (R2 = 0.9632), indicates a high level of reliability. Moreover, under optimal conditions (catalyst loading of 4 mg, pH of 3, H2O2 amount of 0.2 mL, UV power of 25 W, and reaction time of 60 min), the highest RR120 dye removal percentage was 99.97%. Kinetic data indicated an increase in the reaction rate constant from 0.0631 to 0.1796 min−1. The zeolite 13X incorporated with Zn-Ce photocatalyst exhibited excellent stability over 5 cycles, with only a 5.50% decrease in RR120 dye removal yield. This study demonstrates the promising potential of zeolite 13X incorporated with Zn-Ce nanoparticles for the removal of RR120 dye from aqueous suspension.
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M. M. is supported by the University of Ilam through the award research fellowship.
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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by Tahereh Yarnazari, Basir Maleki, Mohsen Mansouri, and Hossein Esmaeili. The first draft of the manuscript was written by Mohsen Mansouri and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript. All authors are fully aware of this manuscript and have permission to submit the manuscript for possible publication.
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Yarnazari, T., Maleki, B., Mansouri, M. et al. Zeolite 13X incorporated with Zn-Ce oxide nanocatalyst for removal of Reactive Red 120 dye: RSM-based approach. Environ Monit Assess 196, 344 (2024). https://doi.org/10.1007/s10661-024-12505-5
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DOI: https://doi.org/10.1007/s10661-024-12505-5