Abstract
A 3-month air monitoring study was conducted in Washington County, Pennsylvania, at the request of local community members regarding the potential risks resulting from air emissions of pollutants related to hydraulic fracturing operations. Continuous air monitoring for total volatile organic compounds was performed at two sampling sites, including a school and a residence, located within 900 m of a hydraulic fracturing well pad that had been drilled prior to the study. Intermittent 24-hour air samples for 62 individual volatile organic compounds were also collected. The ambient air at both sites was monitored during four distinct periods of unconventional natural gas extraction activity: an inactive period prior to fracturing operations, during fracturing operations, during flaring operations, and during another inactive period after operations. The results of the continuous monitoring during fracturing and flaring sampling periods for total volatile organic compounds were similar to the results obtained during inactive periods. Total volatile organic compound 24-hour average concentrations ranged between 0.16 and 80 ppb during all sampling periods. Several individual volatile compounds were detected in the 24-hour samples, but they were consistent with background atmospheric levels measured previously at nearby sampling sites and in other areas in Washington County. Furthermore, a basic yet conservative screening level evaluation demonstrated that the detected volatile organic compounds were well below health-protective levels. The primary finding of this study was that the operation of a hydraulic fracturing well pad in Washington County did not substantially affect local air concentrations of total and individual volatile organic compounds.
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References
Allegheny County Health Department (ACHD) (2016). Environmental Impact Studies. Retrieved from: http://www.achd.net/shale/. Accessed May 17, 2016.
ATSDR (2005). Public health assessment guidance manual (update). Atlanta: USDH-ATSDR.
Brown, D., Weinberger, B., Lewis, C., & Bonaparte, H. (2014). Understanding exposure from natural gas drilling puts current air standards to the test. Reviews on Environmental Health, 29(4), 277–292.
Bunch, A., Perry, C., Abraham, L., Wikoff, D., Tachovsky, J., Hixon, J., et al. (2014). Evaluation of impact of shale gas operations in the Barnett Shale region on volatile organic compounds in air and potential human health risks. Science of the Total Environment, 468, 832–842.
Eapi, G. R., Sabnis, M. S., & Sattler, M. L. (2014). Mobile measurement of methane and hydrogen sulfide at natural gas production site fence lines in the Texas Barnett Shale. Journal of the Air & Waste Management Association, 64(8), 927–944.
Evans, L. B., Vatavuk, W. M., Stone, D. K., Lynch, S. K., Pandullo, R. F., & Koucky, W. (2000). Chapter 1: flares. EPA/452/B-02-001.
Filella, I., & Penuelas, J. (2006). Daily, weekly, and seasonal time courses of VOC concentrations in a semi-urban area near Barcelona. Atmospheric Environment, 40(40), 7752–7769.
Litovitz, A., Curtright, A., Abramzon, S., Burger, N., & Samaras, C. (2013). Estimation of regional air-quality damages from Marcellus Shale natural gas extraction in Pennsylvania. Environmental Research Letters, 8(1), 014017.
Macey, G. P., Breech, R., Chernaik, M., Cox, C., Larson, D., Thomas, D., et al. (2014). Air concentrations of volatile compounds near oil and gas production: a community-based exploratory study. Environmental Health, 13(1), 82.
McKenzie, L. M., Witter, R. Z., Newman, L. S., & Adgate, J. L. (2012). Human health risk assessment of air emissions from development of unconventional natural gas resources. Science of the Total Environment, 424, 79–87.
Moore, C. W., Zielinska, B., Pétron, G., & Jackson, R. B. (2014). Air impacts of increased natural gas acquisition, processing, and use: a critical review. Environmental Science & Technology, 48(15), 8349–8359.
PADEP (2010). Southwestern Pennsylvania Marcellus Shale short-term ambient air sampling report. In Bureau of Air Quality. Pennsylvania Department of Environmental Protection.
PADEP (2011a). Northcentral Pennsylvania Marcellus Shale short-term ambient air sampling report. Bureau of Air Quality. Pennsylvania Department of Environmental Protection.
PADEP (2011b). Northeastern Pennsylvania Marcellus Shale short-term ambient air sampling report. Bureau of Air Quality. Pennsylvania Department of Environmental Protection.
PADEP (2012). Ambient standards. Retrieved from: http://www.dep.pa.gov/Business/Air/BAQ/PollutantTopics/Pages/Ambient-Standards.aspx#.Vzn81YQrKM8. Accessed May 16, 2016.
PADEP (2015). Reporting services: spud report. Retrieved from: http://www.depreportingservices.state.pa.us/ReportServer/Pages/ReportViewer.aspx?/Oil_Gas/Spud_External_Data. Accessed September 10, 2015.
Roy, A. A., Adams, P. J., & Robinson, A. L. (2014). Air pollutant emissions from the development, production, and processing of Marcellus Shale natural gas. Journal of the Air & Waste Management Association, 64(1), 19–37.
Salonen, H., Pasanen, A., Lappalainen, S., Riuttala, H., Tuomi, T., Pasanen, P., et al. (2009). Volatile organic compounds and formaldehyde as explaining factors for sensory irritation in office environments. Journal of Occupational and Environmental Hygiene, 6(4), 239–247.
Steinzor, N., Subra, W., & Sumi, L. (2013). Investigating links between shale gas development and health impacts through a community survey project in Pennsylvania. New Solutions: A Journal of Environmental and Occupational Health Policy, 23(1), 55–83.
Swarthout, R. F., Russo, R. S., Sive, B. C., Zhou, Y., Miller, B. M., Mitchell, B. L., et al. (2015). Impact of Marcellus Shale natural gas development in Southwest Pennsylvania on volatile organic compound emissions and regional air quality. Environmental Science & Technology, 49(5), 3175–3184.
Tiwari, V., Hanai, Y., & Masunaga, S. (2010). Ambient levels of volatile organic compounds in the vicinity of petrochemical industrial area of Yokohama, Japan. Air Quality, Atmosphere and Health, 3(2), 65–75.
USEPA (2013). EPA needs to improve air emissions data for the oil and natural gas production sector.
USEPA (2015a). Regional screening table user’s guide. Retreived from: http://www.epa.gov/risk/regional-screening-table-users-guide-november-2015. Accessed December 25, 2015.
USEPA (2015b). Screening tools for chemical contaminants. Retrieved from: http://epa-prgs.ornl.gov/cgi-bin/chemicals/csl_search. Accessed December 24, 2015.
Zielinska, B., Campbell, D., & Samburova, V. (2014). Impact of emissions from natural gas production facilities on ambient air quality in the Barnett Shale area: a pilot study. Journal of the Air & Waste Management Association, 64(12), 1369–1383.
Acknowledgments
Work performed by Cardno ChemRisk on behalf of Ft. Cherry School District including air monitoring, sample collection, and data analysis was performed pro bono. Funding for equipment used in the study was provided by Ft. Cherry School District, McDonald, PA. Mention of specific manufacturers and models of equipment in this manuscript does not represent an endorsement for that equipment. The authors thank Ft. Cherry School District and Mr. Robert Fedinetz for use of their property throughout the study. The authors also thank Ms. Carrie Kahn and Ms. Maya McKeown for their comments on the draft manuscript and assistance with figures and tables, and Cardno ChemRisk staff for equipment setup and sampling assistance. One of the authors, Julie M. Panko, has served as an expert witness in hydraulic fracturing zoning matters.
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Maskrey, J.R., Insley, A.L., Hynds, E.S. et al. Air monitoring of volatile organic compounds at relevant receptors during hydraulic fracturing operations in Washington County, Pennsylvania. Environ Monit Assess 188, 410 (2016). https://doi.org/10.1007/s10661-016-5410-4
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DOI: https://doi.org/10.1007/s10661-016-5410-4