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Use of Chemical and Microbiological Methods to Synthesize Natural Polyacetylenes

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Chemical and microbiological methods for synthesizing polyacetylenes were studied. The reaction of 1,4-dibromobutyne with monosubstituted acetylene alcohols (propargyl alcohol and dimethylethynylcarbinol) in the presence of a catalytic system formed the corresponding unconjugated polyacetylene diols, from which polyacetylene derivatives were prepared. Polyacetylenes containing several triple and double bonds were also synthesized using biosyntheses by basidial fungi such as Ganoderma lucidum, Pleurotus ostreatus, Laetiporus sulphureus, and Trametes hirsuta.

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Acknowledgment

The work was financially supported by the Science and Technology Center of Ukraine (STCU) in the framework of Project No. 5784.

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Authors and Affiliations

  1. Institute of Polymer Materials, National Academy of Sciences of Azerbaijan, 124 S. Vurguna St., AZ 5004, Sumgait, Azerbaijan

    M. I. Shatirova & N. R. Bektashi

  2. Institute of Microbiology, National Academy of Sciences of Azerbaijan, 103 Mikaila Mushfiga St., AZ 1073, Baku, Azerbaijan

    P. Z. Muradov

Authors
  1. M. I. Shatirova
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  2. P. Z. Muradov
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  3. N. R. Bektashi
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Corresponding author

Correspondence to M. I. Shatirova.

Additional information

Translated from Khimiya Prirodnykh Soedinenii, No. 1, January–February, 2022, pp. 5–9.

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Shatirova, M.I., Muradov, P.Z. & Bektashi, N.R. Use of Chemical and Microbiological Methods to Synthesize Natural Polyacetylenes. Chem Nat Compd 58, 1–5 (2022). https://doi.org/10.1007/s10600-022-03586-0

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  • DOI: https://doi.org/10.1007/s10600-022-03586-0

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