Four new flavonoids that were identified using chemical transformations and UV, MS, PMR, and 13C NMR spectroscopy were isolated from flower heads of Calendula officinalis (Asteraceae). The compounds were quercetin 3-O-(4″-α-L-rhamnopyranosyl)-β-D-glucopyranoside (calendoside I), quercetin 3-O-(3″-α-Lrhamnopyranosyl)-β-D-glucopyranoside (calendoside II), isorhamnetin 3-O-(4″-α-L-rhamnopyranosyl)-β-D-glucopyranoside (calendoside III), and isorhamnetin 3-O-(3″-α-L-rhamnopyranosyl)-β-D-glucopyranoside (calendoside IV).
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Acknowledgment
The work was supported financially by the SB RAS program “Centers of New Medical Technologies.”
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Translated from Khimiya Prirodnykh Soedinenii, No. 4, July–August, 2014, pp. 549–553.
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Olennikov, D.N., Kashchenko, N.I. Calendosides I–IV, New Quercetin and Isorhamnetin Rhamnoglucosides from Calendula officinalis . Chem Nat Compd 50, 633–637 (2014). https://doi.org/10.1007/s10600-014-1041-6
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DOI: https://doi.org/10.1007/s10600-014-1041-6