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New oxazole to oxazole recyclization

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Chemistry of Heterocyclic Compounds Aims and scope

(4-Cyanooxazol-5-ylamino)acetates and (4-cyanooxazol-5-ylamino)acetamides after treatment with trifluoroacetic acid undergo recyclization to the mixture of corresponding 5-aminooxazoles, 5-trifluoroacetylaminooxazoles, and oxazolopyrimidinones. The structures have been confirmed for certain products which have been isolated in pure form.

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References

  1. Chumachenko, S. A.; Shablykin, O. V.; Brovarets, V. S. Chem. Heterocycl. Compd. 2015, 50, 1727.

    Article  CAS  Google Scholar 

  2. Shablykin, O. V.; Brovarets, V. S. Russ. J. Gen. Chem. 2007, 77, 1480.

    Article  CAS  Google Scholar 

  3. Shablykin, O. V.; Brovarets, V. S.; Rusanov, E. B.; Drach, B. S. Heteroat. Chem. 2007, 18, 782.

    Article  CAS  Google Scholar 

  4. Golovchenko, A. V.; Pil'o, S. G.; Brovarets, V. S.; Chernega, A. N.; Drach, B. S. Russ. J. Gen. Chem. 2005, 75, 425.

    Article  CAS  Google Scholar 

  5. Golovchenko, A. V.; Solomyannyi, R. N.; Brovarets, V. S. Russ. J. Gen. Chem. 2010, 80, 723.

    Article  CAS  Google Scholar 

  6. Merzhyievskyi, D. O.; Shablykin, O. V.; Shablykina, O. V.; Kozytskiy, A. V.; Rusanov, E. B.; Moskvina, V. S.; Brovarets, V. S. Eur. J. Org. Chem. 2021, 6511.

  7. Zhao, G.; Sun, X.; Bienayme, H.; Zhu, J. J. Am. Chem. Soc. 2001, 123, 6700.

    Article  CAS  PubMed  Google Scholar 

  8. Sheldrick, G. M. Acta Crystallogr., Sect. A: Found. Crystallogr. 2008, A64, 112.

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Authors and Affiliations

  1. V. P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, 1 Akademika Kukharya St., Kyiv, 02094, Ukraine

    Oleh V. Shablykin, Danylo O. Merzhyievskyi & Volodymyr S. Brovarets

  2. State Scientific Institution “Institute for Single Crystals”, National Academy of Sciences of Ukraine, 60 Nauky Ave., Kharkiv, 61001, Ukraine

    Svitlana V. Shishkina

Authors
  1. Oleh V. Shablykin
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  2. Danylo O. Merzhyievskyi
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  3. Volodymyr S. Brovarets
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  4. Svitlana V. Shishkina
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Corresponding author

Correspondence to Volodymyr S. Brovarets.

Additional information

Published in Khimiya Geterotsiklicheskikh Soedinenii, 2023, 59(6/7), 521–524

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Shablykin, O.V., Merzhyievskyi, D.O., Brovarets, V.S. et al. New oxazole to oxazole recyclization. Chem Heterocycl Comp 59, 521–524 (2023). https://doi.org/10.1007/s10593-023-03226-7

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  • DOI: https://doi.org/10.1007/s10593-023-03226-7

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