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Synthesis of some heptazine derivatives

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Chemistry of Heterocyclic Compounds Aims and scope

New derivatives of heptazine were prepared from 2,5,8-trichloroheptazine by a Friedel–Crafts reaction and Pd-catalyzed amination. New triamino-substituted heptazine derivative represents a soluble carbon nitride monomeric unit suitable for the assembly of metal–organic and covalent–organic frameworks. Aromatic substituents in heptazine ring can be displaced by an alkylamine in a pseudo-nucleophilic substitution reaction.

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This work was supported by the European Regional Development Fund (agreement No. 1.1.1.1/16/A/288).

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Authors and Affiliations

  1. Latvian Institute of Organic Synthesis, 21 Aizkraukles St., Riga, LV-1006, Latvia

    Kristīne Krūkle-Bērziņa, Kārlis Bērziņš & Kirill Shubin

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  1. Kristīne Krūkle-Bērziņa
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  2. Kārlis Bērziņš
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  3. Kirill Shubin
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Correspondence to Kirill Shubin.

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Published in Khimiya Geterotsiklicheskikh Soedinenii, 2019, 55(12), 1281–1284

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Krūkle-Bērziņa, K., Bērziņš, K. & Shubin, K. Synthesis of some heptazine derivatives. Chem Heterocycl Comp 55, 1281–1284 (2019). https://doi.org/10.1007/s10593-019-02614-2

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  • DOI: https://doi.org/10.1007/s10593-019-02614-2

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