Abstract
Ramie is of low cost, non-toxic, degradable but the use of ramie in garments manufacturing is limited due to a large amount of hairiness bringing scratchiness to skin. Herein, a facile and efficient surface micro-dissolution technology was used to eliminate the hairiness of ramie fabrics. SEM, Mirrorless Digital Camera, FTIR, XRD, and TG were used to investigate the morphology and structure of treated ramie fabrics. Softness, hydrophilicity, breaking strength, whiteness, moisture absorption, dye uptake, and air permeability were also studied. The results proved that surface micro-dissolution technology eliminate hairiness effectively while its physical properties were retained. In particular, the softness of the fabric was well maintained, which makes it suitable for clothing production. The surface micro-dissolution technology of ramie fabric based on copper ammonia solution system has the advantages of short treatment time and low process requirements, which provides a new idea for improving the wearability of ramie fabric.
Similar content being viewed by others
Availability of data and material
The data is availability.
References
Burchard W, Seger B, Habermann N et al (1994) Cellulose in Schweizers Reagens: ein stabiler, polymerer Metallkomplex hoher Kettensteifheit. Angew Chem 106:936–939. https://doi.org/10.1002/ange.19941060826
Byrne N, Setty M, Blight S et al (2016) Cellulose-derived carbon fibers produced via a continuous carbonization process: investigating precursor choice and carbonization conditions. Macromol Chem Phys 217:2517–2524. https://doi.org/10.1002/macp.201600236
Cai J, Zhang L (2006) Unique gelation behavior of cellulose in NaOH/urea aqueous solution. Biomacromolecules 7:183–189. https://doi.org/10.1021/bm0505585
Chen X, Burger C, Wan F et al (2007) Structure study of cellulose fibers wet-spun from environmentally friendly NaOH/urea aqueous solutions. Biomacromolecules 8:1918–1926. https://doi.org/10.1021/bm061186i
Cheng H (2017) Effect of low temperature softening treatment on the structure and properties of ramie fiber. Shanghai Text Sci Technol 45:25–27. https://doi.org/10.16549/j.cnki.issn.1001-2044.2017.12.008
Fan T, Hu R, Zhao Z et al (2017) Surface micro-dissolve method of imparting self-cleaning property to cotton fabrics in NaOH/urea aqueous solution. Appl Surf Sci 400:524–529. https://doi.org/10.1016/j.apsusc.2016.12.184
Fan T, Qian Q, Hou Z et al (2018) Preparation of smart and reversible wettability cellulose fabrics for oil/water separation using a facile and economical method. Carbohydr Polym 200:63–71. https://doi.org/10.1016/j.carbpol.2018.07.040
French AD (2014) Idealized powder diffraction patterns for cellulose polymorphs. Cellulose 21:885–896
Hosseinzadeh H, Mohammadi S (2014) Synthesis of a novel hydrogel nanocomposite coated on cotton fabric for water-oil separation. Water Air Soil Pollut. https://doi.org/10.1007/s11270-014-2115-6
Hu R, Dong Q, Pu Q, Lu M (2017a) The research progress of eliminating ramie fabric scratchiness. Dye Finish Technol. https://doi.org/10.16481/j.cnki.ctl.2017.02.019
Hu R, Zhao Z, Zhou J et al (2017b) Surface micro-dissolution of ramie fabrics with NaOH/urea to eliminate hairiness. Cellulose 24:5251–5259. https://doi.org/10.1007/s10570-017-1492-6
Hu R, Zhao Z, Zhou J et al (2019) Ultrasound assisted surface micro-dissolution to embed nano TiO2 on cotton fabrics in ZnCl2 aqueous solution. Ultrason Sonochem 56:160–166. https://doi.org/10.1016/j.ultsonch.2019.04.006
Hu R, Fan T, Yang J et al (2020a) Ultrasound and microwave technology for flake-TiO2 growth and immobilization on cotton fabrics in micro-dissolution process. Mater Chem Phys 249:123036. https://doi.org/10.1016/j.matchemphys.2020.123036
Hu R, Yang J, Li S et al (2020b) Fabrication of special wettability functionalized Mg(OH)2@cotton fabric for oil/water mixtures and emulsions separation. Cellulose. https://doi.org/10.1007/s10570-020-03315-2
Hu R, Yang J, Yang P et al (2020c) Fabrication of ZnO@Cotton fabric with anti-bacterial and radiation barrier properties using an economical and environmentally friendly method. Cellulose 27:2901–2911. https://doi.org/10.1007/s10570-019-02965-1
Isogai A, Atalla RH (1998) Dissolution of cellulose in aqueous NaOH solutions. Cellulose 5:309–319. https://doi.org/10.1023/A:1009272632367
Jia B, Mei Y, Cheng L et al (2012) Preparation of copper nanoparticles coated cellulose films with.pdf. Am Chem Soc Appl Mater Interfaces 4:2897–2902
Jia B, Yu L, Fu F et al (2014) Preparation of helical fibers from cellulose-cuprammonium solution based on liquid rope coiling. RSC Adv 4:9112–9117. https://doi.org/10.1039/c3ra47031h
Kusmono, Affan MN (2020) Isolation and characterization of nanocrystalline cellulose from ramie fibers via phosphoric acid hydrolysis. J Nat Fibers 00:1–12. https://doi.org/10.1080/15440478.2020.1821292
Łaszkiewicz B (1998) Solubility of bacterial cellulose and its structural properties. J Appl Polym Sci 67:1871–1876. https://doi.org/10.1002/(sici)1097-4628(19980314)67:11%3c1871::aid-app5%3e3.0.co;2-i
Liu J, Wei S, Liu C, Yang H (2006) The study of ramee fabric. Tianjin Text Technol 3:18–21,29
Lu M, Li L, Xie R et al (2017) Preparation of magnetic cotton fabric by surface micro-dissolution treatment. Cellulose 24:1099–1106. https://doi.org/10.1007/s10570-016-1152-2
Lv W, Nie K, Song Y et al (2020) Improving ramie fibers softness using ionic liquid treatment. J Nat Fibers 00:1–8. https://doi.org/10.1080/15440478.2020.1848719
Qi H, Chang C, Zhang L (2008) Effects of temperature and molecular weight on dissolution of cellulose in NaOH/urea aqueous solution. Cellulose 15:779–787. https://doi.org/10.1007/s10570-008-9230-8
Saalwächter K, Burchard W, Klüfers P et al (2000) Cellulose solutions in water containing metal complexes. Macromolecules 33:4094–4107. https://doi.org/10.1021/ma991893m
Sen S, Losey BP, Gordon EE et al (2016) Ionic liquid character of zinc chloride hydrates define solvent characteristics that afford the solubility of cellulose. J Phys Chem B 120:1134–1141. https://doi.org/10.1021/acs.jpcb.5b11400
Singh A, Varghese LM, Battan B et al (2020) Eco-friendly scouring of ramie fibers using crude xylano-pectinolytic enzymes for textile purpose. Environ Sci Pollut Res 27:6701–6710. https://doi.org/10.1007/s11356-019-07424-9
Viju S, Thilagavathi G (2020) Characterization of surface modified nettle fibers for composite reinforcement. J Nat Fibers. https://doi.org/10.1080/15440478.2020.1788491
Wang K, Yi H (2016) Study on sizing technology of ramie. J Chengdu Text Coll 33:65–68. https://doi.org/10.5151/cidi2017-060
Wang M, Peng M, Zhu J et al (2020) Mussel-inspired chitosan modified superhydrophilic and underwater superoleophobic cotton fabric for efficient oil/water separation. Carbohydr Polym 244:116449. https://doi.org/10.1016/j.carbpol.2020.116449
Xiong Y, Zhang B, Yu C et al (2017) The softening property of ramie fiber treated by DMSO/TEAC. Plant Fiber Sci China 39:4–9
Yu W, Wang C, Yi Y et al (2020) Direct pretreatment of raw ramie fibers using an acidic deep eutectic solvent to produce cellulose nanofibrils in high purity. Cellulose. https://doi.org/10.1007/s10570-020-03538-3
Zhang L, Zhu J (2009) Study on cellulase used to improve the itching sensation of ramie fabric. Prod Technol 31:9–12
Zhang M, Wang C, Wang H et al (2017) Carbonized cotton fabric for high-performance wearable strain sensors. Adv Funct Mater. https://doi.org/10.1002/adfm.201604795
Zhou J, Zhang L, Cai J, Shu H (2002) Cellulose microporous membranes prepared from NaOH/urea aqueous solution. J Memb Sci 210:77–90. https://doi.org/10.1016/S0376-7388(02)00377-0
Zhou J, Zhang L, Cai J (2004) Behavior of cellulose in NaOH/urea aqueous solution characterized by light scattering and viscometry. J Polym Sci Part B Polym Phys 42:347–353. https://doi.org/10.1002/polb.10636
Zhou J, Qin Y, Liu S, Zhang L (2006) Homogenous synthesis of hydroxyethylcellulose in NaOH/urea aqueous solution. Macromol Biosci 6:84–89. https://doi.org/10.1002/mabi.200500148
Acknowledgments
This work was financially supported by Government Sponsored Visiting Scholar Research Program (201908505032, 202006995001) and Southwest University Undergraduate Innovation and Entrepreneurship Training Program (X202010635408).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Consent for publication
The manuscript has been approved by all authors for publication.
Conflict of interest
No conflict of interest appears for the manuscript submission.
Ethical approval
We declare that there is no financial or personal relationship between us and other people or organizations that may have an inappropriate impact on our work. All procedures performed in studies involving human participants were in accordance with the ethical standards of the institutional and/or national research committee and with the 1964 Helsinki declaration and its later amendments or comparable ethical standar ds. This article does not contain any studies with animals performed by any of the authors. Informed consent was obtained from all individual participants included in the study.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Yang, J., Yang, P., Wu, Z. et al. Eliminating the hairiness of ramie fabrics by micro-dissolution technology in copper ammonia solution. Cellulose 28, 8177–8185 (2021). https://doi.org/10.1007/s10570-021-04023-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10570-021-04023-1