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Highly Efficient Mesoporous V2O5/WO3–TiO2 Catalyst for Selective Catalytic Reduction of NOx: Effect of the Valence of V on the Catalytic Performance

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Abstract

Mesoporous WO3–TiO2 support was synthesized by hydrothermal method, mesoporous V2O5/WO3–TiO2 catalyst was synthesized by impregnation method and used for selective catalytic reduction (SCR) of NOx with a excellent NOx conversion at a wider operating temperature ranging from 200 to 460 °C. In the range of 260–440 °C, NOx conversion reached to 98.6%, and nearly a complete conversion. Even with the existence of 300 ppm SO2, NOx conversion was only a little decline. The catalyst was characterized by a series of techniques, such as XRD, BET, XPS, TEM, Raman and H2-TPR. It was concluded that V2O5/WO3–TiO2 catalyst was ascribe to antase TiO2, and also the high crystallinity of anatase TiO2 could improve the SCR performance. More interested, V2O5/WO3–TiO2 catalyst exhibited the typical mesoporous structure according to the BET results. In addition, the TEM results indicated that the active components of V and W were well-dispersed on the surface of TiO2, while the enhancement of dispersion could improve the activity of catalysts. More importantly, the concentration ratio of V4+/(V5+ + V4+ + V3+) performed the key role in improving the activity of V2O5/WO3–TiO2 catalyst.

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Acknowledgements

The financial support of Science and Technology Service Network Initiative (STS) of Chinese Academy of Science (KFJ-SW-STS-149), The National Basic Research Program of China (2013CB933200), The National Natural Science Foundation of China (21407154, 21507137), and West Light Foundation of The Chinese Academy of Sciences is gratefully acknowledged.

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Authors and Affiliations

  1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China

    Luyao Zong, Fang Dong, Guodong Zhang, Weiliang Han & Zhicheng Tang

  2. School of petroleum and chemical, Lanzhou university of technology, Lanzhou, 730050, China

    Luyao Zong & Jiyi Zhang

Authors
  1. Luyao Zong
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  2. Fang Dong
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  3. Guodong Zhang
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  4. Weiliang Han
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  5. Zhicheng Tang
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  6. Jiyi Zhang
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Correspondence to Zhicheng Tang or Jiyi Zhang.

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Zong, L., Dong, F., Zhang, G. et al. Highly Efficient Mesoporous V2O5/WO3–TiO2 Catalyst for Selective Catalytic Reduction of NOx: Effect of the Valence of V on the Catalytic Performance. Catal Surv Asia 21, 103–113 (2017). https://doi.org/10.1007/s10563-017-9229-y

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