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Efficient Syngas-to-Olefins Conversion via Kaolin Modified SAPO-34 Catalyst

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Abstract

The preparation circumstances and effects of the kaolin-modified SAPO-34 molecular sieves were studied in order to support the industrial application of the cutting-edge technology for producing light olefins from syngas catalyzed by bifunctional catalyst. Additionally, their apparent morphology, crystal structure, structural features, and acid strength were tested. The results demonstrated that kaolin-based molecular sieves are thinly layered and have an acid strength and pore structure that are more conducive to reactions. The effect of the mass ratio of the oxide to the molecular sieve, the hydrogen to carbon ratio of the feed gas, and other reaction conditions on the catalytic activity of the bifunctional catalyst was investigated using modified molecular sieves. Under the reaction conditions of the oxide to molecular sieve mass ratio of 2:1, feed gas composition of n(H2)/n(CO) = 2, 400 °C, and 3 MPa, a CO conversion of 50.11% with a low CO2 selectivity of 17.01% and a light olefins yield of 24.18% could be achieved.

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Acknowledgements

The authors are grateful for the financial support provided by Sichuan Coal Industry Group Limited Liability Company for Development of Coal-coupled Methane Plasma for Synthesis of Ethylene and Acetylene (No. 2019H0449), and the National Natural Science Foundation of China (No. 22178236, No. 21878194).

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Authors and Affiliations

  1. College of Chemical Engineering, Sichuan University, Chengdu, 610065, People’s Republic of China

    Luyao Mao & Jianhua Tang

  2. Sichuan Coal Industry Group Limited Liability Company, Chengdu, 610091, People’s Republic of China

    Heping Zheng, Daqiang Xiao & Yu Ren

  3. Panzhihua Coal United Coking Limited Liability Company, Panzhihua, 617000, People’s Republic of China

    Longteng Ran

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  1. Luyao Mao
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Correspondence to Heping Zheng.

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Mao, L., Zheng, H., Xiao, D. et al. Efficient Syngas-to-Olefins Conversion via Kaolin Modified SAPO-34 Catalyst. Catal Lett 154, 664–673 (2024). https://doi.org/10.1007/s10562-023-04336-9

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