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Hydrogenation of 2-Hydroxytetrahydrofuran to 1,4-Butanediol Over Ni–Fe/SiO2 Bimetallic Catalysts

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Abstract

2-Hydroxytetrahydrofuran (HTHF) is the main by-product of hydrogenation of 1,4-butynediol (BYD) to 1,4-butanediol (BDO) in industry, which is difficult to be effectively removed in the subsequent distillation process and seriously affects the product quality. Here, a series of silica-supported bimetallic Ni–Fe catalysts with different Fe/Ni weight ratios were prepared by using incipient wetness impregnation method and investigated the effect of Fe on the catalyst performance in the hydrogenation of HTHF to BDO. In comparison with monometallic Ni and Fe catalysts, bimetallic Ni–Fe catalysts exhibited better performance for HTHF hydrogenation due to the formation of Ni–Fe alloy phase identified by XRD, TEM, STEM-EDS, H2-TPR, NH3/H2-TPD, Pyridine FTIR and XPS, etc. A mechanism is proposed to explain the promoting effect of Fe, which can be assigned to the synergism between nickel sites with high ability to activate/overflow hydrogen and Fe-containing sites with strong oxophilicity for the activation of the O-C-O bond over the tetrahydrofuran ring.

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Acknowledgements

We are grateful for financial support from the National Natural Science Foundation of China (22178202, 21603127, U1710221) and Scientific and Technological Innovation Programs (STIP) of Higher Education Institutions in Shanxi of China (2020L0018).

Funding

This study is supported by the National Natural Science Foundation of China (22178202, 21603127, U1710221) and Scientific and Technological Innovation Programs (STIP) of Higher Education Institutions in Shanxi of China (2020L0018).

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Authors and Affiliations

  1. Engineering Research Center of Ministry of Education for Fine Chemicals, Shanxi University, Taiyuan, 030006, China

    Liping Zhao, Changzhen Wang, Juan Bai, Ruifang Wu, Haitao Li & Yongxiang Zhao

  2. Department of Applied Chemistry, Yuncheng University, Yuncheng, 044000, China

    Liping Zhao

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  1. Liping Zhao
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  2. Changzhen Wang
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  3. Juan Bai
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Correspondence to Changzhen Wang, Haitao Li or Yongxiang Zhao.

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Zhao, L., Wang, C., Bai, J. et al. Hydrogenation of 2-Hydroxytetrahydrofuran to 1,4-Butanediol Over Ni–Fe/SiO2 Bimetallic Catalysts. Catal Lett 154, 448–460 (2024). https://doi.org/10.1007/s10562-023-04325-y

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