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Nanoparticle Supported Bronsted Acidic Ionic Liquid Catalyzed Synthesis of Dihydro-1H-pyrazolylnaphthalene-1,4-diones

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Abstract

A novel nano-Fe3O4 supported Bronsted acidic ionic liquid ([nano-Fe3O4@BenzImi]SO3H) has been prepared by multi-step procedure and characterized by various analytical techniques. The [nano-Fe3O4@BenzImi]SO3H has been employed as a heterogeneous catalyst in the multi-component synthesis of dihydro-1H-pyrazolylnaphthalene-1,4-diones in high yields using ethanol as a green solvent. The [nano-Fe3O4@BenzImi]SO3H could be recycled up to seven catalytic cycles without a significant decrease in the yield of the products.

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Acknowledgements

We gratefully acknowledge the IIT, Bombay, NEHU, Shillong, IIT, Madras, IISc, Bangalore, Sophisticated Analytical Instrumental Facility and Common Facility Center (CFC) and Physics Instrumentation Facility Centre (PIFC), Shivaji University, Kolhapur for providing spectral facilities.

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Authors and Affiliations

  1. Department of Chemistry, Jaysingpur College, Jaysingpur, Maharashtra, 416101, India

    Wilson Chandane & Bhaskar Tamhankar

  2. Department of Chemistry, Ajara Mahavidyalaya, Ajara, Maharashtra, 416505, India

    Shivanand Gajare

  3. Department of Chemistry, Shivaji University, Kolhapur, Maharashtra, 416004, India

    Audumbar Patil & Gajanan Rashinkar

  4. Department of Chemistry, Willingdon College, Sangli, Maharashtra, 416415, India

    Bhaskar Tamhankar

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  1. Wilson Chandane
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Chandane, W., Gajare, S., Patil, A. et al. Nanoparticle Supported Bronsted Acidic Ionic Liquid Catalyzed Synthesis of Dihydro-1H-pyrazolylnaphthalene-1,4-diones. Catal Lett 153, 3357–3370 (2023). https://doi.org/10.1007/s10562-022-04243-5

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