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15-Membered Macrocyclic Schiff-Base-Pd(0) Complex Immobilized on Fe3O4 MNPs: An Novel Nanomagnetic Catalyst for the One-Pot Three-Component C–H Chalcogenation of Azoles by S8 and Aryl Iodides

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Abstract

This fact that diaryl sulfides are important structural components in polymers, agrochemicals, natural products, and pharmaceutical intermediates has increased the attention of chemists to synthesize these compounds. In recent times, the research on the preparation of diaryl sulfides using magnetically reusable catalysts have received profound attention in organic chemistry. In this paper, we describe the fabrication and characterization of a magnetically reusable palladium nanomaterial and evaluate its catalytic activity for the preparation of diaryl sulfides through one-pot three-component coupling reaction of azoles, S8 and aryl iodides. The structure of palladium supported on magnetic nanoparticles was well characterized by a series of spectroscopic techniques including FT-IR, SEM, TEM, EDX, XRD, VSM, TGA, ICP-OES. To the best of our knowledge, it is the first report on the utilization of Pd nanomagnetic catalyst for the one-pot three-component coupling reaction of azoles, S8 and aryl iodides.

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Acknowledgements

Open fund project of Hubei Key Laboratory of Kidney Disease Pathogenesis and Intervention (SB202120), Scientific research project of Hubei Provincial Health Commission (WJ2021F028), Scientific research project of Hubei Polytechnic University (22XJZ04Y), Hubei University laboratory research project (HBSY2019-36).

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Authors and Affiliations

  1. Department of Pharmacy, School of Medicine, Hubei Polytechnic University, Huangshi, 435003, Hubei, China

    Jin Liu, Sanhai Qin, Jingjing Du, Yingxing Zhou & Bingcun Cui

  2. Hubei Key Laboratory of Kidney Disease Pathogenesis and Intervention, School of Medicine, Hubei Polytechnic University, Huangshi, 435003, Hubei, China

    Jin Liu, Sanhai Qin, Jingjing Du, Yingxing Zhou & Bingcun Cui

  3. Graduate School of Hubei Normal University, Huangshi, 435002, Hubei, China

    Shaofen Jin

  4. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China

    Xing Kang

  5. Huangshi Shi Xing Pharmaceutical Co., Ltd, Huangshi, 435111, China

    Xiangyang Zhang

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Liu, J., Jin, S., Qin, S. et al. 15-Membered Macrocyclic Schiff-Base-Pd(0) Complex Immobilized on Fe3O4 MNPs: An Novel Nanomagnetic Catalyst for the One-Pot Three-Component C–H Chalcogenation of Azoles by S8 and Aryl Iodides. Catal Lett 153, 2581–2591 (2023). https://doi.org/10.1007/s10562-022-04194-x

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