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Preparation of COFs Supported Pd as an Efficient Catalyst for the Hydrogenation of Aromatic Nitro

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Abstract

The preparation of high-performance supported Pd catalysts for the hydrogenation of aromatic nitro is of great importance. In this paper, covalent-triazine framework (CTF), an organic porous crystalline material connected by covalent bonds, was employed as the support for the preparation of Pd heterogeneous catalyst. The framework of CTF was maintained due to the utilization of cyclohexene as a moderate reductant for PdCl2. The catalysts were characterized by transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The influence of reaction conditions (temperature, pressure, reaction time, concentration substrate and catalyst dosage) were investigated. At very mild reaction conditions (30 °C, 0.1 MPa H2, 2 mg Pd/CTF), the nitrobenzene was nearly stoichiometric hydrogenated to aniline. The Pd/CTF was effective for the conversion of a series of aromatic nitro compounds to the corresponding aromatic amines with good yield. The results showed that Pd/CTF has good catalytic activity and stability in the heterogeneous catalytic hydrogenation.

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Acknowledgements

We are grateful to the National Natural Science Foundation of China (21802125 and 21902071) and the Henan Science and Technology Project (202102210007, 172102210490).

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Authors and Affiliations

  1. School of Chemical Engineering, Zhengzhou University, 100 Kexue Road, Zhengzhou, 450001, China

    Pan Guo, Yuzhong Zhan & Tianliang Lu

  2. Henan Key Laboratory of Function-Oriented Porous Material, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471934, China

    Yanliang Yang

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  1. Pan Guo
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  2. Yuzhong Zhan
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  4. Tianliang Lu
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Correspondence to Yanliang Yang or Tianliang Lu.

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Guo, P., Zhan, Y., Yang, Y. et al. Preparation of COFs Supported Pd as an Efficient Catalyst for the Hydrogenation of Aromatic Nitro. Catal Lett 152, 3725–3732 (2022). https://doi.org/10.1007/s10562-022-03941-4

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  • DOI: https://doi.org/10.1007/s10562-022-03941-4

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