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Fe Exchanged Supported Phosphomolybdic Acid: Synthesis, Characterization and Low Temperature Water Mediated Hydrogenation of Cyclohexene

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Abstract

In this article, first time we are reporting two steps synthesis of Fe exchanged phosphomolybdic acid supported on zirconia (Fe-PMA/ZrO2) by incipient wet impregnation and ion exchange method. The obtained material was well characterized by EDX mapping, ICP, FT-IR, Raman, 31P MAS NMR, ESR, XPS and powder XRD. The catalytic evaluation was explored for cyclohexene hydrogenation at low temperature using water as a solvent. The obtained results demonstrate remarkable efficiency of the synthesized material as a sustainable heterogeneous catalyst with very low amount of active species (Fe: 0.024 mol%), 90% conversion, high substrate/catalyst ratio (4157/1) as well as TON (3742) for 3 catalytic cycles. The present synthetic approach is highly green as it does not involve use of any noble metal, with no waste generation (E-factor = 0) as well as high reaction mass efficiency (92.20%).

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References

  1. Hill CL (1998) Chem Rev 98:1

    Article  CAS  PubMed  Google Scholar 

  2. Mizuno N, Yamaguchi K, Kamata K (2005) Coord Chem Rev 249:1944

    Article  CAS  Google Scholar 

  3. Neumann R, Polyoxometalate complexes in organic oxidation chemistry, 1998.

  4. Pope MT (1984) Heteropoly and isopoly oxometalates. Springer-Verlag, Berlin Heidelberg

    Google Scholar 

  5. Mallick S, Rana S, Parida K (2012) Ind Eng Chem Res 51:7859

    Article  CAS  Google Scholar 

  6. Ibrahim AA, Hassan SM, Mannaa MA (2020) Colloids Surfaces A Physicochem Eng Asp 586:124248

    Article  CAS  Google Scholar 

  7. Maleki B, Eshghi H, Khojastehnezhad A, Tayebee R, Ashrafi SS, Kahoo GE, Moeinpour F (2015) RSC Adv 5:64850

    Article  CAS  Google Scholar 

  8. Shen L, Feng Y, Yin H, Wang A, Yu L, Jiang T, Shen Y, Wu Z (2011) J Ind Eng Chem 17:484

    Article  CAS  Google Scholar 

  9. Avendaño C, Briceño A, Méndez FJ, Brito JL, González G, Cañizales E, Atencio R, Dieudonné P (2013) Dalt Trans 42:2822

    Article  Google Scholar 

  10. Rohaniyan M, Davoodnia A, Beyramabadi SA, Khojastehnezhad A (2019) Appl Organomet Chem 33:1

    Article  CAS  Google Scholar 

  11. Gao W, Sun X, Niu H, Song X, Li K, Gao H, Zhang W, Yu J, Jia M (2015) Microporous Mesoporous Mater 213:59

    Article  CAS  Google Scholar 

  12. Zhang X, Zhang Z, Zhang B, Yang X, Chang X, Zhou Z, Wang DH, Zhang MH, Bu XH (2019) Appl Catal B Environ 256:117804

    Article  CAS  Google Scholar 

  13. Zhang Q, Liu X, Yang T, Yue C, Pu Q, Zhang Y (2019) RSC Adv 9:8113

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  14. Yu D, Gao W, Xing S, Lian L, Zhang H, Wang X, Lou D (2019) RSC Adv 9:4884

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  15. Patel A, Pathan S (2012) Ind Eng Chem Res 51:732

    Article  CAS  Google Scholar 

  16. Sharma P, Patel A (2009) J Mol Catal A Chem 299:37

    Article  CAS  Google Scholar 

  17. Bryzhin AA, Gantman MG, Buryak AK, Tarkhanova IG (2019) Appl Catal B Environ 257:117938

    Article  CAS  Google Scholar 

  18. Liu X, Li J, Wang R (2017) Chem Eng J 316:171

    Article  CAS  Google Scholar 

  19. Li X, Cao R, Lin Q (2015) Catal Commun 63:79

    Article  CAS  Google Scholar 

  20. Song X, Zhu W, Yan Y, Gao H, Gao W, Zhang W, Jia M (2016) J Mol Catal A Chem 413:32

    Article  CAS  Google Scholar 

  21. Narkhede N, Patel A, Singh S (2014) Dalton Trans 43:2512

    Article  CAS  PubMed  Google Scholar 

  22. Das B, Kumar RA, Thirupathi P, Srinivas Y (2009) Synth Commun 39:3305

    Article  CAS  Google Scholar 

  23. Abd El-Wahab MMM, Said AA (2005) J Mol Catal A Chem 240:109

    CAS  Google Scholar 

  24. Singh S, Narkhedea N, Patel A (2015) RSC Adv 5:36270

    Article  CAS  Google Scholar 

  25. Armatas GS, Bilis G, Louloudi M (2011) J Mater Chem 21:2997

    Article  CAS  Google Scholar 

  26. Mallik S, Dash SS, Parida KM, Mohapatra BK (2006) J Colloid Interface Sci 300:237

    Article  CAS  PubMed  Google Scholar 

  27. Sharma P, Patel A (2009) Appl Surf Sci 255:7635

    Article  CAS  Google Scholar 

  28. Pathana S, Patel A (2011) Dalton Trans 40:348

    Article  Google Scholar 

  29. Pathana S, Patel A (2014) Chem Eng J 243:183

    Article  CAS  Google Scholar 

  30. Bin Z, Hiroyuki A, Jia Z, Jiaguang Z, Sudipta D, Ning Y (2016) Angew Chem Int Ed 55:1

    Article  CAS  Google Scholar 

  31. Bin Z, Geng S, Shipeng D, Hiroyuki A, Jia Z, Philippe S, Ning Y (2019) J Am Chem Soc 141:8185

    Article  CAS  Google Scholar 

  32. Max JH, Bin Z, Zhirui M, Hiroyuki A, David AD, Wei C, Tsunehiro T, Peng Z, Zili W, Ning Y (2019) Nat Commun 10:1330

    Article  CAS  Google Scholar 

  33. Hudson R, Rivière A, Cirtiu CM, Luska KL, Moores A (2012) Chem Commun 48:3360

    Article  CAS  Google Scholar 

  34. Shesterkina AA, Kustov LM, Strekalova AA, Kazansky VB (2020) Catal Sci Technol 10:3160

    Article  CAS  Google Scholar 

  35. Patel A, Patel A (2019) Catal Lett 149:1476

    Article  CAS  Google Scholar 

  36. Patel S, Purohit N, Patel A (2003) J Mol Catal A Chem 192:195

    Article  CAS  Google Scholar 

  37. Patel A, Patel A (2019) RSC Adv 9:1460

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  38. Patel A, Patel J (2020) RSC Adv 10:22146

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  39. Hernández-Cortez JG, Manríquez M, Lartundo-Rojas L, López-Salinas E (2014) Catal Today 220:32

    Article  CAS  Google Scholar 

  40. Guo H, Yin G (2011) J Phys Chem C 115:17516

    Article  CAS  Google Scholar 

  41. Mizuno N, Min JS, Taguchi A (2004) Chem Mater 16:2819

    Article  CAS  Google Scholar 

  42. Yu H, Cao G, Chen F, Wang X, Yu J, Lei M (2014) Appl Catal B Environ 160:658

    Article  CAS  Google Scholar 

  43. Zhu Y, Wang WD, Sun X, Fan M, Hu X, Dong Z (2020) ACS Appl Mater Interfaces 12:7285

    Article  CAS  PubMed  Google Scholar 

  44. Patel A, Patel J (2021) Mol Catal 513:111827

    Article  CAS  Google Scholar 

  45. Phua PH, Lefort L, Boogers JAF, Tristany M, De Vries JG, (2009) Chem Commun 374.

  46. Rangheard C, de Julián FC, Phua PH, Hoorn J, Lefort L, de Vries JG (2010) Dalton Trans 39:8464

    Article  CAS  PubMed  Google Scholar 

  47. Stein M, Wieland J, Steurer P, Tölle F, Mülhaupt R, Breit B (2011) Adv Synth Catal 353:523

    Article  CAS  Google Scholar 

  48. Kelsen V, Wendt B, Werkmeister S, Junge K, Beller M, Chaudret B (2013) Chem Commun 49:3416

    Article  CAS  Google Scholar 

Download references

Acknowledgements

AP and JP is thankful to Science and Engineering Research Board (SERB), Project No. EMR/2016/005718, New Delhi for the financial support. We are thankful to the Department of chemistry and Physics for BET surface area analysis and FT-Raman analysis, The Maharaja Sayajirao University of Baroda, respectively.

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  1. Polyoxometalates and Catalysis Laboratory, Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara, 390002, Gujarat, India

    Anjali Patel & Jay Patel

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  1. Anjali Patel
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  2. Jay Patel
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Correspondence to Anjali Patel.

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Patel, A., Patel, J. Fe Exchanged Supported Phosphomolybdic Acid: Synthesis, Characterization and Low Temperature Water Mediated Hydrogenation of Cyclohexene. Catal Lett 152, 2716–2728 (2022). https://doi.org/10.1007/s10562-021-03838-8

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