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Effect of Tourmaline Addition on the Catalytic Performance and SO2 Resistance of NixMn3−xO4 Catalyst for NH3-SCR Reaction at Low Temperature

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Abstract

NixMn3−xO4 and NixMn3−xO4/T (T represents tourmaline) catalysts with a double-layer hollow structure were prepared by a rigid template method for low-temperature selective catalytic reduction of NOx with NH3 (NH3-SCR). The catalytic activity and SO2 tolerance performance of NixMn3−xO4 catalyst were enhanced by the addition of 2 wt% tourmaline. The results showed the addition of tourmaline could affect the growth, shell thickness and redox property of the NixMn3−xO4 catalysts. The relative contents of Mn4+ and surface chemical oxygen were also increased by the addition of tourmaline, which were beneficial for improving the SCR activity, the catalyst showed 100% NO conversion in a low-temperature range of 125–240 °C. The mechanism of SCR reaction and SO2 tolerance were analyzed by In-situ DRIFTS. The SCR reaction process mostly follows Langmuir–Hinshelwood (L–H) mechanisms. The primary NOx adsorption materials on NixMn3−xO4/T catalyst were nitrate bidentate and bridge nitrate, which was not affected by SO2, and it had excellent SO2 tolerance at 150 ℃.

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Acknowledgements

This work described above was financially supported by National Natural Science Foundation of China (Grant No. U20A20132).

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Authors and Affiliations

  1. Institute of Power Source and Ecomaterials Science, Hebei University of Technology, Tianjin, 300130, China

    Liyin Wang, Peng Gui, Yun Shen & Gang Xue

  2. Key Laboratory of Special Functional Materials for Ecological Environment and Information (Hebei University of Technology), Ministry of Education, Tianjin, 300130, China

    Liyin Wang, Peng Gui, Yun Shen & Gang Xue

  3. Key Laboratory for New Type of Functional Materials in Hebei Province, Hebei University of Technology, Tianjin, 300130, China

    Liyin Wang, Peng Gui, Yun Shen & Gang Xue

  4. Institute of New Energy, School of Materials Science and Engineering, Tianjin University, Tianjin, 300072, People’s Republic of China

    Cairong Gong

Authors
  1. Liyin Wang
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  2. Peng Gui
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  3. Yun Shen
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  4. Cairong Gong
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  5. Gang Xue
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Contributions

Methodology: LW, PG, YS; Formal analysis and investigation: LW, CG, GX; Writing—original draft preparation: LW, PG; Funding acquisition: GX; Supervision: LW, YS, CG.

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Correspondence to Gang Xue.

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Wang, L., Gui, P., Shen, Y. et al. Effect of Tourmaline Addition on the Catalytic Performance and SO2 Resistance of NixMn3−xO4 Catalyst for NH3-SCR Reaction at Low Temperature. Catal Lett 151, 3404–3416 (2021). https://doi.org/10.1007/s10562-021-03585-w

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  • DOI: https://doi.org/10.1007/s10562-021-03585-w

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