Abstract
Silver nanoparticles supported on modified montmorillonite clay (Ag-NPs@mont), were utilized as catalyst for the Baeyer–Villiger oxidation of various ketones with hydrogen peroxide as an oxidant under solvent free condition at room temperature. The modification of Montmorillonite K10 clay was carried out with HCl under controlled conditions for generating a high surface area porous matrix which acts as support for the in situ generation of Silver nanoparticles. The synthesized nanocomposite material was characterized by UV–Visible spectroscopy, powder XRD, SEM-EDX, TEM and N2 adsorption–desorption analysis. The catalyst can be recycled and reused several times without significant loss of their catalytic activity.
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Narayanan R (2012) Green Chem Lett Rev 5:707
Chen WW, Nguyen RV, Li CJ (2009) Tetrahedron Lett 50:2895
Zeng T, Chen WW, Cirtiu CM, Moores A, Song G, Li CJ (2010) Green Chem 12:570
Zhou X, Lu Y, Zhai LL, Zhao Y, Liu Q, Sun WY (2013) RSC Adv 3:1732
Karimi B, Gholinejad M, Khorasani M (2012) Chem Commun 48:8961
Borah SJ, Das DK (2016) Catal Lett 146:656–665
Paul M, Pal N, Mondal J, Sasidharan M, Bhaumik A (2012) Chem Eng Sci 71:564–572
Otomo R, Kosugi R, Kamiya Y, Tatsumia T, Yokoi T (2016) Catal Sci Technol 6:2787
Ten Brink GJ, Arends IW, Sheldon RA (2004) Chem Rev 104:4105–4123
Campelo JM, Luna D, Luque R, Marinas JM, Romero AA (2009) ChemSusChem 2:18–45
Templeton AC, Wuelfing WP, Murray RW (2000) Acc Chem Res 33:27–36
Rao CNR, Kulkarni GU, Thomas PJ, Edwards PP (2000) Chem Soc Rev 29:27–35
Borah BJ, Dutta D, Dutta DK (2010) Appl Clay Sci 49:317–323
Schröder F, Esken D, Cokoja M, Van den Berg MWE, Lebedev OI, Tendeloo GV, Walaszek B, Buntkowsky G, Limbach HH, Chaudret B, Fischer RA (2008) J Am Chem Soc 130:6119–6130
Rogatis LD, Cargnello M, Gombac V, Lorenzut B, Montini T, Fornasiero P (2010) ChemSusChem 3:24
Kaneda K, Mitsudome T, Mizugaki T, Jitsukawa K (2010) Molecules 15:8988
Chrobok A, Baj S, Pudlo W, Jarzebski A (2009) Appl Catal A 366:22–28
Piscopo CG, Loebbecke S, Maggi R, Sartori G (2010) Adv Synth Catal 352:1625–1629
Corma A, Nemeth MT, Renz M, Valencia S (2001) Nature 412:423–425
Corma A, Navarro MT, Renz M (2003) J Catal 219:242–246
Hara T, Hatakeyama M, Kim A, Ichikuni N, Shimazu S (2012) Green Chem 14:771
Saikia P, Sarmah PP, Borah BJ, Saikia L, Saikia K, Dutta DK (2016) Green Chem 18:2843–2850
Pillai UR, Demessie ES (2003) J Mol Catal A 191:93–100
Saito Y, Wang JJ, Smith DA, Batchelder DN (2002) Langmuir 18:2959
Lee D, Cohen RE, Rubner MF (2005) Langmuir 21:9651
Khan MAM, Kumar S, Ahamed M, Alrokayan SA, AlSalhi MS (2011) Nanoscale Res Lett 6:434
Kushal DB, Pawan JT, Kishor PD, Bhalchandra MB (2010) Catal Commun 11:1233
Safaei Ghomi J, Ghasemzadeh M (2013) J Chem Sci 125:1003
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The authors gratefully acknowledge SAIF, NEHU for the TEM analysis.
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Borah, S.J., Das, D.K. Efficient Baeyer–Villiger Oxidation Catalysed by Silver Nanoparticles Stabilized on Modified Montmorillonite. Catal Lett 148, 3669–3677 (2018). https://doi.org/10.1007/s10562-018-2566-2
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DOI: https://doi.org/10.1007/s10562-018-2566-2