Abstract
In this work, NiCo2O4 with a hierarchical porous flower-like structure was fabricated and used as catalyst support for Pd nanoparticles. The NiCo2O4 was composed of porous nanoplates without overlapping, and the Pd nanoparticles were uniformly distributed on these nanoplates. Pd–NiCo2O4 with the Pd loading of 2.0 wt% showed extremely high activity and stability, methane (1.0% CH4/Air) can be totally oxidized at 330 °C and the T90 is 309 °C, which is much lower than that of pure NiCo2O4 (T90 = 405 °C). At wet condition with the presence of 10 vol% water vapor, the catalytic activity was still acceptable with the T90 of 366 °C, and no activity decrease or permanent damage for the catalyst was observed after 35 h reaction, showing high stability. A series of techniques including TEM, SEM, XRD, H2-TPR, BET and especially quasi in situ XPS combined with in situ MS were used to characterize the catalysts and investigate the catalysis mechanism. Two pathways of CHO evolution were proved by the quasi in situ XPS and in situ MS results: OCHO intermediate dehydrogenation pathway at lower temperature and CO oxidation pathway of CHO at higher temperature.
Graphical Abstract
Similar content being viewed by others
References
Lelieveld J, Crutzen PJ, Dentener FJ (1998) Changing concentration, lifetime and climate forcing of atmospheric methane. Tellus Ser B 50:128–150. https://doi.org/10.1034/j.1600-0889.1998.t01-1-00002.x
Ju Y, Sun Y, Sa Z et al (2016) A new approach to estimate fugitive methane emissions from coal mining in China. Sci Total Environ 543:514–523. https://doi.org/10.1016/j.scitotenv.2015.11.024
Nisbet EG, Dlugokencky EJ, Manning MR et al (2016) Rising atmospheric methane: 2007–2014 growth and isotopic shift. Global Biogeochem Cycles 30:1356–1370. https://doi.org/10.1002/2016GB005406
National Development and Reform Commission (2012) Second national communication on climate change of the People’s Republic of China. National Development and Reform Commission, Beijing
Yang Z, Grace JR, Lim CJ, Zhang L (2011) Combustion of low-concentration coal bed methane in a fluidized bed. Energy Fuels 25:975–980. https://doi.org/10.1021/ef101573y
Kalantar Neyestanaki A, Klingstedt F, Salmi T, Murzin DY (2004) Deactivation of postcombustion catalysts, a review. Fuel 83:395–408. https://doi.org/10.1016/j.fuel.2003.09.002
Venezia AM, Di Carlo G, Pantaleo G et al (2009) Oxidation of CH4 over Pd supported on TiO2-doped SiO2: effect of Ti(IV) loading and influence of SO2. Appl Catal B 88:430–437
Corro G, Cano C, Fierro JLG (2010) A study of Pt–Pd/γ-Al2O3 catalysts for methane oxidation resistant to deactivation by sulfur poisoning. J Mol Catal A 315:35–42
Cargnello M, Jaen JJD, Garrido JCH et al (2012) Exceptional activity for methane combustion over modular Pd@CeO2 subunits on functionalized Al2O3. Science 337:713–717. https://doi.org/10.1126/science.1222887
Eguchi K, Arai H (2001) Low temperature oxidation of methane over Pd-based catalysts—effect of support oxide on the combustion activity. Appl Catal A 222:359–367. https://doi.org/10.1016/S0926-860X(01)00843-2
Hu L, Peng Q, Li Y (2008) Selective synthesis of Co3O4 nanocrystal with different shape and crystal plane effect on catalytic property for methane combustion. J Am Chem Soc 130:16136–16137. https://doi.org/10.1021/ja806400e
Barbato PS, Di Benedetto A, Di Sarli V et al (2012) High-pressure methane combustion over a perovskyte catalyst. Ind Eng Chem Res 51:7547–7558. https://doi.org/10.1021/ie201736p
Barbato PS, Di Sarli V, Landi G, Di Benedetto A (2015) High pressure methane catalytic combustion over novel partially coated LaMnO3-based monoliths. Chem Eng J 259:381–390. https://doi.org/10.1016/j.cej.2014.07.123
Di Benedetto A, Landi G, Di Sarli V et al (2012) Methane catalytic combustion under pressure. Catal Today 197:206–213. https://doi.org/10.1016/j.cattod.2012.08.032
Shao C, Li W, Lin Q et al (2017) Low temperature complete combustion of lean methane over cobalt-nickel mixed-oxide catalysts. Energy Technol 5:604–610. https://doi.org/10.1002/ente.201600402
Yashnik SA, Surovtsova TA, Ishchenko AV et al (2016) Structure and properties of Pd–Mn hexaaluminate catalysts modified with platinum for the high-temperature oxidation of methane. Kinet Catal 57:528–539
Schwartz WR, Pfefferle LD (2012) Combustion of methane over palladium-based catalysts: support interactions. J Phys Chem C 116:8571–8578. https://doi.org/10.1021/jp2119668
Murata K, Mahara Y, Ohyama J et al (2017) The metal-support interaction concerning the particle size effect of Pd/Al2O3 on methane combustion. Angew Chem Int Ed 8520:15993–15997. https://doi.org/10.1002/anie.201709124
Li Z, Hoflund GB (2003) A review on complete oxidation of methane at low temperatures. J Nat Gas Chem 12:153–160
Li Z, Hoflund GB (1999) Catalytic oxidation of methane over Pd/Co3O4. React Kinet Catal Lett 66:367–374. https://doi.org/10.1007/BF02475814
Kucharczyk B, Tylus W (2008) Effect of washcoat modification with metal oxides on the activity of a monolithic Pd-based catalyst for methane combustion. Catal Today 137:324–328. https://doi.org/10.1016/j.cattod.2008.05.018
Hu L, Peng Q, Li Y (2011) Low-temperature CH4 catalytic combustion over Pd catalyst supported on Co3O4 nanocrystals with well-defined crystal planes. ChemCatChem 3:868–874. https://doi.org/10.1002/cctc.201000407
Tao FF, Shan J, Nguyen L et al (2015) Understanding complete oxidation of methane on spinel oxides at a molecular level. Nat Commun 6:7798. https://doi.org/10.1038/ncomms8798
Di Sarli V, Landi G, Lisi L, Di Benedetto A (2017) Ceria-coated diesel particulate filters for continuous regeneration. AIChE J 63(8):3442–3449
Di Sarli V, Landi G, Lisi L, Saliva A, Di Benedetto A (2016) Catalytic diesel particulate filters with highly dispersed ceria: Effect of the soot-catalyst contact on the regeneration performance. Appl Catal B: Environ 197:116–124
Xu Q, Kharas KC, Croley BJ, Datye AK (2011) The sintering of supported Pd automotive catalysts. ChemCatChem 3:1004–1014. https://doi.org/10.1002/cctc.201000392
De Rogatis L, Cargnello M, Gombac V et al (2010) Embedded phases: a way to active and stable catalysts. ChemSusChem 3:24–42
Cargnello M, Wieder NL, Montini T et al (2010) Synthesis of dispersible Pd @ CeO2 core-shell nanostructures by self-assembly. J Am Chem Soc 132:1402–1409. https://doi.org/10.1039/b916035c.(20)
Bakhmutsky K, Wieder NL, Cargnello M et al (2012) A versatile route to core-shell catalysts: synthesis of dispersible M@oxide (M = Pd, Pt; oxide = TiO2, ZrO2) nanostructures by self-assembly. ChemSusChem 5:140–148. https://doi.org/10.1002/cssc.201100491
Lee Y, Garcia MA, Frey Huls NA, Sun S (2010) Synthetic tuning of the catalytic properties of Au–Fe3O4 nanoparticles. Angew Chem 122:1293–1296. https://doi.org/10.1002/ange.200906130
Gu H, Yang Z, Gao J et al (2005) Heterodimers of nanoparticles: formation at a liquid–liquid interface and particle-specific surface modification by functional molecules. J Am Chem Soc 127:34–35
Huang Q, Li W, Lin Q et al (2016) A review of significant factors in the synthesis of hetero-structured dumbbell-like nanoparticles. Chinese J Catal 37:681–691. https://doi.org/10.1016/S1872-2067(15)61069-5
Huang Q, Li W, Lin Q et al (2017) Catalytic performance of Pd-NiCo2O4/SiO2 in lean methane combustion at low temperature. J Energy Inst. https://doi.org/10.1016/j.joei.2017.05.008
Lee JH, Trimm DL (1995) Catalytic combustion of methane. Fuel Process Technol 42:339–359
Li L, Cheah Y, Ko Y et al (2013) The facile synthesis of hierarchical porous flower-like NiCo2O4 with superior lithium storage properties. J Mater Chem A 1:10935–10941. https://doi.org/10.1039/c3ta11549f
Luo L, Tang X, Wang W et al (2013) Methyl radicals in oxidative coupling of methane directly confirmed by synchrotron VUV photoionization mass spectroscopy. Sci Rep 3:1–7. https://doi.org/10.1038/srep01625
Qi F, Yang R, Yang B et al (2006) Isomeric identification of polycyclic aromatic hydrocarbons formed in combustion with tunable vacuum ultraviolet photoionization. Rev Sci Instrum 77:84101. https://doi.org/10.1063/1.2234855
Wang Y, Zhu Y, Zhou Z et al (2016) Pyrolysis study on solid fuels: from conventional analytical methods to synchrotron vacuum ultraviolet photoionization mass spectrometry. Energy Fuels 30:1534–1543
Zhu Y, Chen X, Wang Y et al (2015) Online study on the catalytic pyrolysis of bituminous coal over HUSY and HZSM-5 with photoionization time-of-flight mass spectrometry. Energy Fuels 30:1598–1604
Fujimoto K-I, Ribeiro FH, Avalos-Borja M, Iglesia E (1998) Structure and reactivity of PdOx/ZrO2 catalysts for methane oxidation at low temperatures. J Catal 179:431–442. https://doi.org/10.1006/jcat.1998.2178
Pi D, Li WZ, Lin QZ et al (2016) Highly active and thermally stable supported Pd@SiO2 core-shell catalyst for catalytic methane combustion. Energy Technol 4:943–949. https://doi.org/10.1002/ente.201600006
Bitter JH, Seshan K, Lercher JA (2000) On the contribution of X-ray absorption spectroscopy to explore structure and activity relations of Pt/ZrO2 catalysts for CO2/CH4 reforming. Top Catal 10:295–305
Sekizawa K, Widjaja H, Maeda S et al (2000) Low temperature oxidation of methane over Pd/SnO2 catalyst. Appl Catal A 200:211–217. https://doi.org/10.1016/S0926-860X(00)00634-7
Yamamoto H, Uchida H (1998) Oxidation of methane over Pt and Pd supported on alumina in lean-burn natural-gas engine exhaust. Catal Today 45:147–151. https://doi.org/10.1016/S0920-5861(98)00265-X
Piqueras C, Bottini S, Damiani D (2006) Sunflower oil hydrogenation on Pd/Al2O3 catalysts in single-phase conditions using supercritical propane. Appl Catal A 313:177–188. https://doi.org/10.1016/j.apcata.2006.07.023
Anderson JR (1975) Structure of metallic catalysts. Academic Press, New York
Liang D, Gao J, Wang J et al (2009) Selective oxidation of glycerol in a base-free aqueous solution over different sized Pt catalysts. Catal Commun 10:1586–1590. https://doi.org/10.1016/j.catcom.2009.04.023
Lambert S, Job N, D’Souza L et al (2009) Synthesis of very highly dispersed platinum catalysts supported on carbon xerogels by the strong electrostatic adsorption method. J Catal 261:23–33. https://doi.org/10.1016/j.jcat.2008.10.014
Yuranov I, Moeckli P, Suvorova E et al (2003) Pd/SiO2 catalysts: synthesis of Pd nanoparticles with the controlled size in mesoporous silicas. J Mol Catal A 192:239–251. https://doi.org/10.1016/S1381-1169(02)00441-7
Hoffmann M, Kreft S, Georgi G et al (2015) Improved catalytic methane combustion of Pd/CeO2 catalysts via porous glass integration. Appl Catal B 179:313–320
Schwartz WR, Ciuparu D, Pfefferle LD (2012) Combustion of methane over palladium-based catalysts: catalytic deactivation and role of the support. J Phys Chem C 116:8587–8593. https://doi.org/10.1021/jp212236e
Xu W, Liu X, Ren J et al (2010) A novel mesoporous Pd/cobalt aluminate bifunctional catalyst for aldol condensation and following hydrogenation. Catal Commun 11:721–726. https://doi.org/10.1016/j.catcom.2010.02.002
Liotta LF, Di Carlo G, Pantaleo G et al (2007) Pd/Co3O4 catalyst for CH4 emissions abatement: study of SO2 poisoning effect. Top Catal 42:425–428. https://doi.org/10.1007/s11244-007-0218-7
Gou Y, Liang X, Chen B (2013) Porous Ni–Co bimetal oxides nanosheets and catalytic properties for CO oxidation. J Alloys Compd 574:181–187. https://doi.org/10.1016/j.jallcom.2013.04.053
Trivedi S, Prasad R (2017) Selection of cobaltite and effect of preparation method of NiCo2O4 for catalytic oxidation of CO–CH4 mixture. Asia-Pacific J Chem Eng 12:440–453. https://doi.org/10.1002/apj.2087
Luo MF, Hou ZY, Yuan XX, Zheng XM (1998) Characterization study of CeO2 supported Pd catalyst for low-temperature carbon monoxide oxidation. Catal Lett 50:205–209. https://doi.org/10.1023/A:1019023220271
Klissurski D, Uzunova E (1991) Synthesis of nickel cobaltite spinel from coprecipitated nickel-cobalt hydroxide carbonate. Chem Mater 3:1060–1063
Marco JF, Gancedo JR, Gracia M et al (2001) Cation distribution and magnetic structure of the ferrimagnetic spinel NiCo2O4. J Mater Chem 11:3087–3093
Ciuparu D, Bozon-Verduraz F, Pfefferle L (2002) Oxygen exchange between palladium and oxide supports in combustion catalysts. J Phys Chem B 106:3434–3442. https://doi.org/10.1021/jp013577r
Liang J, Fan Z, Chen S et al (2014) Hierarchical NiCO2O4nanosheets@halloysite nanotubes with ultrahigh capacitance and long cycle stability as electrochemical pseudocapacitor materials. Chem Mater 26:4354–4360. https://doi.org/10.1021/cm500786a
Zhang S, Shan J, Nie L et al (2016) In situ studies of surface of NiFe2O4 catalyst during complete oxidation of methane. Surf Sci 648:156–162. https://doi.org/10.1016/j.susc.2015.12.011
Luciu I, Bartali R, Laidani N (2012) Influence of hydrogen addition to an Ar plasma on the structural properties of TiO2–x thin films deposited by RF sputtering. J Phys D 45:345302
Chin Y-H, Buda C, Neurock M, Iglesia E (2013) Consequences of metal–oxide interconversion for C–H bond activation during CH4 reactions on Pd catalysts. J Am Chem Soc 135:15425–15442
Mudiyanselage K, Senanayake SD, Feria L et al (2013) Importance of the metal–oxide interface in catalysis: in situ studies of the water–gas shift reaction by ambient-pressure X-ray photoelectron spectroscopy. Angew Chem Int Ed 52:5101–5105
Acknowledgements
This work is supported by the National Natural Science Foundation of China (No. 51376171), the Science and Technological Fund of Anhui Province for Outstanding Youth (1508085J01) and the National Key Technology R&D Program of China (No. 2015BAD15B06).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Huang, Q., Li, W., Lei, Y. et al. Catalytic Performance of Novel Hierarchical Porous Flower-Like NiCo2O4 Supported Pd in Lean Methane Oxidation. Catal Lett 148, 2799–2811 (2018). https://doi.org/10.1007/s10562-018-2397-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-018-2397-1