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Single-Site CrO x Moieties on Silicalite: Highly Active and Stable for Ethane Dehydrogenation with CO2

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Abstract

Silicalite-1 supported CrO x is highly active and stable for the ethane dehydrogenation with CO2, whose ethylene yield reached 37.8%, and only 9.5% of its initial activity was lost after 6 h, which can be attributed to the formation of single-site CrO x moieties embedded in the framework vacancy defects of zeolite. The strong interaction with silicalite-1 surface as well as the geometry isolation effect may account for the excellent activity and stability of single-site CrO x moieties.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (91645201), the National Key R&D Program of China (2017YFB0602204) and the Science & Technology Commission of Shanghai Municipality (13DZ2275200).

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Authors and Affiliations

  1. Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200433, People’s Republic of China

    Yanhu Cheng, Tianqi Lei, Weiming Hua, Yinghong Yue & Zi Gao

  2. Shanghai Research Institute of Petrochemical Technology, Shanghai, 201208, People’s Republic of China

    Changxi Miao

Authors
  1. Yanhu Cheng
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  2. Tianqi Lei
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  3. Changxi Miao
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  4. Weiming Hua
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  5. Yinghong Yue
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Correspondence to Yinghong Yue.

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Cheng, Y., Lei, T., Miao, C. et al. Single-Site CrO x Moieties on Silicalite: Highly Active and Stable for Ethane Dehydrogenation with CO2. Catal Lett 148, 1375–1382 (2018). https://doi.org/10.1007/s10562-018-2348-x

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  • DOI: https://doi.org/10.1007/s10562-018-2348-x

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