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Co-SBA-15-Immobilized NDHPI as a New Composite Catalyst for Toluene Aerobic Oxidation

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Abstract

A new composite catalyst was constructed by immobilizing active site N,N-dihydroxypyromellitimide (NDHPI) on the co-catalyst Co-doped mesoporous sieve SBA-15 through the chemical bond with the 3-(glycidoxypropyl) trimethoxysilicane used as the silylation agent. The catalyst was characterized by various means. The new catalyst showed significantly higher activity in toluene aerobic oxidation at 90 °C with acetonitrile as a solvent or under solvent-free condition compared with the NDHPI and co-catalyst independent system. The effects of the reaction conditions such as temperature, oxygen pressure, catalyst amount on the toluene oxidation over the immobilized catalyst were also investigated. After reuse for three times, the composite catalyst kept the activity without loss of Co from SBA-15.

Graphical Abstract

A new composite catalyst was constructed by immobilizing active site N,N-dihydroxypyromellitimide (NDHPI) on the co-catalyst Co-doped mesoporous sieve SBA-15 through the chemical bond with the 3-(glycidoxypropyl) trimethoxysilicane used as the silylation agent. The catalyst was characterized by various means. The catalytic performance of the composite was evaluated in toluene aerobic oxidation and the reuseability of the catalyst was also investigated.

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Acknowledgements

This study was financially supported by the National Natural Science Foundation of China (No. 21376200) and Hunan 2011 Collaborative Innovation Center of Chemical Engineering & Technology with Environmental Benignity and Effective Resource Utilization.

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Authors and Affiliations

  1. College of Chemical Engineering, Xiangtan University, Xiangtan, 411105, Hunan, China

    Xingxing Li, Lulu Guo, Pengcheng He & Xia Yuan

  2. School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, Hunan, China

    Feipeng Jiao

Authors
  1. Xingxing Li
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  2. Lulu Guo
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  3. Pengcheng He
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  4. Xia Yuan
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  5. Feipeng Jiao
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Corresponding authors

Correspondence to Xia Yuan or Feipeng Jiao.

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Li, X., Guo, L., He, P. et al. Co-SBA-15-Immobilized NDHPI as a New Composite Catalyst for Toluene Aerobic Oxidation. Catal Lett 147, 856–864 (2017). https://doi.org/10.1007/s10562-016-1967-3

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  • DOI: https://doi.org/10.1007/s10562-016-1967-3

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