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A High Loading and Recyclable Pentaerythritol Supported Imidazolidin-4-one Catalyst for Enantioselective Diels–Alder Reactions

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Abstract

The synthesis of high loading and recyclable pentaerythritol supported imidazolidin-4-one catalyst I and its application in enantioselective Diels–Alder reactions of cyclopentadiene and α,β-unsaturated aldehydes with high performance were described. Especially noteworthy, the pentaerythritol supported imidazolidin-4-one with high loading capacity can be recovered by simple precipitation and filtration, and recycled for up to four runs without observing significant decrease in catalytic activity.

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Acknowledgments

We gratefully acknowledge the National Natural Sciences Foundation of China (No. 21342002 and 31330029) and the science and technology support project of Hubei province in China (No. 2015BCA243) for financial support.

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Authors and Affiliations

  1. Hubei Collaborative Innovation Center for Advanced Organochemical Materials & Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan, 430062, China

    Kaitao Du, Cuifen Lu, Zuxing Chen, Junqi Nie & Guichun Yang

Authors
  1. Kaitao Du
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  2. Cuifen Lu
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  3. Zuxing Chen
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  4. Junqi Nie
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  5. Guichun Yang
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Corresponding authors

Correspondence to Cuifen Lu or Guichun Yang.

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Du, K., Lu, C., Chen, Z. et al. A High Loading and Recyclable Pentaerythritol Supported Imidazolidin-4-one Catalyst for Enantioselective Diels–Alder Reactions. Catal Lett 146, 1107–1112 (2016). https://doi.org/10.1007/s10562-016-1724-7

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  • DOI: https://doi.org/10.1007/s10562-016-1724-7

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