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Pd@UiO-66: An Efficient Catalyst for Suzuki–Miyaura Coupling Reaction at Mild Condition

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Abstract

In this paper, the palladium nanoparticles were successfully encapsulated in metal–organic framework material, UiO-66, by a facile approach. Based on the microwave-assisted method, the pores of UiO-66 were activated and the metal precursors were reduced at the same time in the presence of reducing agent. The obtained Pd@UiO-66 was characterized via transmission electron microscopy, powder X-ray diffraction, N2 adsorption and X-ray photoelectron spectroscopy. The Pd@UiO-66 exhibited efficient catalytic activity for the Suzuki–Miyaura coupling reactions at mild condition.

Graphical Abstract

The palladium nanoparticles were successfully encapsulated in metal–organic framework material, UiO-66, by a facile approach. Based on the microwave-assisted method, the pores of UiO-66 were activated and the metal precursors were reduced at the same time in the presence of reducing agent. The obtained Pd@UiO-66 exhibited efficient catalytic activity for the Suzuki–Miyaura coupling reactions at mild condition.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Nos. 31171698, 31471643), the Innovation Research Program of Department of Education of Hebei for Hebei Provincial Universities (LJRC009), Natural Science Foundation of Hebei Province (B2015204003) and the Natural Science Foundation of Agricultural University of Hebei (ZD201506, LG201404).

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Authors and Affiliations

  1. College of Science, Agricultural University of Hebei, Baoding, 071001, Hebei, China

    Wenhuan Dong, Cheng Feng, Li Zhang, Ningzhao Shang, Shutao Gao, Chun Wang & Zhi Wang

Authors
  1. Wenhuan Dong
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  2. Cheng Feng
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  3. Li Zhang
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  4. Ningzhao Shang
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  5. Shutao Gao
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  6. Chun Wang
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  7. Zhi Wang
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Corresponding author

Correspondence to Chun Wang.

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Dong, W., Feng, C., Zhang, L. et al. Pd@UiO-66: An Efficient Catalyst for Suzuki–Miyaura Coupling Reaction at Mild Condition. Catal Lett 146, 117–125 (2016). https://doi.org/10.1007/s10562-015-1659-4

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  • DOI: https://doi.org/10.1007/s10562-015-1659-4

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