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Cage Like Al-KIT-5 Mesoporous Materials for C–C Bond Formation Reactions Under Solvent Free Conditions

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Abstract

The C–C bond forming reactions are of fundamental importance in chemistry. As a result there is ever growing interest for chemists to develop new methods for C–C bond formation. We report here three dimensional nano-cage mesoporous aluminosilicate materials Al-KIT-5 which exhibited very good catalytic activity for Mukaiyama-aldol and Mukaiyama–Michael reactions under solvent free condition. Mukaiyama-aldol and Mukaiyama–Michael reactions of silyl ketene acetal with aldehyde and α, β-unsaturated carbonyl compounds produced β-hydroxy esters and 1, 5-dicarbonyl compounds, respectively in good yields. The product selectivity was found to be 100 % in a short reaction period. The high acidity, 3D pores, and a huge space in the nano-cages materials make them attractive candidate for carrying out important organic reactions. The catalyst provide a simple, easy to handle method, and could be used to solve the problems of corrosion, toxicity, waste production, and high cost that are being currently encountered by the conventional homogeneous catalysts.

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Acknowledgments

The authors are grateful to Prof. M. Deka, Head of Department, Applied Sciences, Gauhati University, Assam, India, for his constant support and encouragement. PKB is thankful to DST, Govt. of India for research funding (Grant No. SB/FT/CS-100/2012) under Fast Track Scheme.

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Authors and Affiliations

  1. Department of Applied Sciences, Gauhati University, GUIST, Guwahati, 781014, Assam, India

    Pranjal K. Baruah & Prantu Dutta

  2. Energy Environment Technology Division, The Energy and Resources Institute, Darbari Seth Block, India Habitat Centre, Lodhi Road, New Delhi, 110 003, India

    Pranjal Kalita

Authors
  1. Pranjal K. Baruah
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  2. Prantu Dutta
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  3. Pranjal Kalita
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Correspondence to Pranjal K. Baruah or Pranjal Kalita.

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Baruah, P.K., Dutta, P. & Kalita, P. Cage Like Al-KIT-5 Mesoporous Materials for C–C Bond Formation Reactions Under Solvent Free Conditions. Catal Lett 145, 2037–2045 (2015). https://doi.org/10.1007/s10562-015-1611-7

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