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Effect of Supercooling and Shear Stress on the Properties of Polyamide-12

  • MATERIALS SCIENCE. CORROSION PROTECTION
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Chemical and Petroleum Engineering Aims and scope

The influence of the dynamics of the polymer materials crystallization process on its properties was investigated. The crystallization process was studied in two cases: during supercooling, and during supercooling together with applied shear stress. The impact of shear stress and supercooling on the crystallization kinetics was studied. The experiment was carried out using two techniques: differential scanning calorimetry and rheometry. Polyamide-12 was chosen as the object of research. The data were processed by the method developed by the authors. The following parameters were determined: induction period, rates of nucleation and growth.

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References

  1. C. J. G. Plummer, J. E. Zanetto, P. E. Bourban, and J. A. E. Manson, “The crystallization kinetics of polyamide-12,” Colloid Polym. Sci.,279, No. 4, 312–322 (2001).

    Article  CAS  Google Scholar 

  2. A. Amado, K. Wegener, M. Schmid, and G. Levy, “Characterization and model ing of non-isothermal crystallization of Polyamide 12 and co-Polypropylene during the SLS process,” in: Proceedings of the 5th International Polymers & Moulds Innovations Conf., Ghent, Belgium, 12–14 September (2012), pp. 207–216.

  3. F. Neugebauer, V. Ploshikhin, J. Ambrosy, and G. Witt, “Isothermal and non-isothermal crystallization kinetics of polyamide 12 used in laser sintering,” J. Therm. Anal. Calorim.,124, 925–933 (2016).

    Article  CAS  Google Scholar 

  4. Z. Meng, K. Wudy, and D. Drummer, “Crystallization kinetics of polyamide 12 during selective laser sintering,” Polymers,10, No. 2, 168–182 (2018).

  5. M. Liu, Q. Zhao, Y. Wang, et al., “Melting behaviors, isothermal and non-isothermal crystallization kinetics of nylon 1212,” Polymer,44, No. 8, 2537–2545 (2003).

  6. N. McFerran, C. Armstrong, and T. McNally, “Nonisothermal and isothermal crystallization kinetics of nylon-12,” J. Appl. Polym. Sci.,110, No. 2, 1043–1058 (2008).

    Article  CAS  Google Scholar 

  7. A. Ya. Malkin and A. I. Isaev, Rheology: Conceptions, Methods, Applications [English translation], Professiya, St. Petersburg (2007).

  8. T. W. Haas and B. Maxwell, “Effects of shear stress on the crystallization of linear polyethylene and polybutene-1,” Polym. Eng. Sci.,9, No. 4, 225–241 (1969).

    Article  CAS  Google Scholar 

  9. Yu. A. Taran, M. K. Zakharov, A. L. Taran, and R. N. Ivanov, “Experimental determination of the rates of nucleation and growth of phase transformation centers,” Tonkie Khimicheskie Tekhnologii,11, No. 6, 43–54 (2016).

  10. N. Devaux, B. Monasse, J. M. Haudin, et al., “Rheooptical study of the early stages of f low enhanced crystallization in isotactic polypropylene,” Rheol. Acta,43, No. 3, 210–222 (2004).

    Article  CAS  Google Scholar 

  11. W. Junyang, B. Jing, Z. Yaqiong, et al., “Shear-induced enhancements of crystallization kinetics and morphological transformation for long chain branched polylactides with different branching degrees,” Sci. Rep.,6, 26560 (2016).

    Article  Google Scholar 

  12. C. Block, A. K. Ghosh, B. Van Mele, and G. Van Assche, “RheoDSC: Design optimisation by heat transfer modeling,” Thermochim. Acta.,547, 130–140 (2012).

    Article  CAS  Google Scholar 

  13. V. Janssens, C. Block, G. Van Assche, et al., “RheoDSC: design and validation of a new hybrid measurement technique,” J. Therm. Anal. Calorim.,98, No. 3, 675–681 (2009).

    Article  CAS  Google Scholar 

  14. B. Wunderlich, Macromolecular Physics [Russian translation], 2, Mir, Moscow (1979).

  15. A. L. Taran, Powder and Melt Granulation: Theory and Practice [in Russian], Doctoral Dissertation, MITHT, Moscow (2001).

  16. Yu. A. Taran, A. V. Kozlov, and A. L. Taran, “The formation of deposits on the walls of the pores in the filtering process,” Tonkie Khimicheskie Tekhnologii,14, No. 2, 15–22 (2019).

  17. GOST R 56757–2015 (ISO 11357-7: 2002) Plastics. Differential Scanning Calorimetry (DSC), Part 7. Determination of Crystallization Kinetics [in Russian].

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Authors and Affiliations

  1. Russian Technological University (MIREA), M. V. Lomonosov Moscow State Academy of Fine Chemical Technology, Moscow, Russia

    Yu. A. Taran & A. A. Solovyev

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  1. Yu. A. Taran
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  2. A. A. Solovyev
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Correspondence to Yu. A. Taran.

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Translated from Khimicheskoe i Neftegazovoe Mashinostroenie, Vol. 56, No. 1, pp. 35−38, January 2020.

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Taran, Y.A., Solovyev, A.A. Effect of Supercooling and Shear Stress on the Properties of Polyamide-12. Chem Petrol Eng 56, 59–65 (2020). https://doi.org/10.1007/s10556-020-00741-8

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  • DOI: https://doi.org/10.1007/s10556-020-00741-8

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