Abstract
Recycling methods will be essential for the future circular economy in the context of declining natural resources. Nanomaterials are promising adsorbents to recover rare earth elements from wastewater, yet the practical application of nanomaterials is limited by spontaneous agglomeration, easy collapse of structures and the difficulty in collecting nanomaterials after adsorption. To solve these issues, we prepared a polyurethane sponge-supported titanium phosphate with graphene oxide, abbreviated as GO@TiP-Sponge, by in situ precipitation. GO@TiP-Sponge was characterized by X-ray diffraction, scanning electron microscope, energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy, and tested for the removal and recovery of trace dysprosium Dy(III), a rare-earth element, in water using batch experiments. Results show that the GO@TiP-Sponge showed an excellent affinity for dysprosium with theoretical capacity reaching 576.17 mg/g according to the Langmuir model. Half-equilibrium was reached in 2.5 min according to a pseudo-second-order model. GO@TiP-Sponge also displayed an adsorption ability for a wide range of pH and salinity. Such performance is explained by strong binding of phosphate with Dy(III), enhanced surface area induced by graphene oxide and less aggregation from the spongy structure. The main adsorption mechanism involves electrostatic interaction.
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References
Alharbi OM, Khattab RA, Ali I (2018) Health and environmental effects of persistent organic pollutants. J Mol Liq 263:442–453. https://doi.org/10.1016/j.molliq.2018.05.029
Ali I (2018) Microwave assisted economic synthesis of multi walled carbon nanotubes for arsenic species removal in water: batch and column operations. J Mol Liq 271:677–685. https://doi.org/10.1016/j.molliq.2018.09.021f
Ali I, Alharbi OM, Al Othman ZA, Al-Mohaimeed AM, Alwarthan A (2019) Modeling of fenuron pesticide adsorption on CNTs for mechanistic insight and removal in water. Environ Res 170:389–397. https://doi.org/10.1016/j.envres.2018.12.066
Al-Shaalan NH, Ali I, Al Othman ZA, Al-Wahaibi LH, Alabdulmonem H (2019) High performance removal and simulation studies of diuron pesticide in water on MWCNTs. J Mol Liq 289:111039. https://doi.org/10.1016/j.molliq.2019.111039
Ashour RM et al (2017) Rare earth ions adsorption onto graphene oxide nanosheets. Solvent Extr Ion Exc 35:91–103. https://doi.org/10.1080/07366299.2017.1287509
Barbaux Y, Dekiouk M, Le Maguer D, Gengembre L, Huchette D, Grimblot J (1992) Bulk and surface analysis of a Fe-PO oxydehydrogenation catalyst. Appl Catal A 90:51–60. https://doi.org/10.1016/0926-860X(92)80247-A
Basheer AA (2018) New generation nano-adsorbents for the removal of emerging contaminants in water. J Mol Liq 261:583–593. https://doi.org/10.1016/j.molliq.2018.04.021
Bortun AI, Khainakov SA, Bortun LN, Poojary DM, Rodriguez J, Garcia JR, Clearfield A (1997) Synthesis and characterization of two novel fibrous titanium phosphates Ti2O(PO4)2·2H2O. Chem Mater 9:1805–1811. https://doi.org/10.1021/cm970060c
Chao YQ et al (2016) Structure, variation, and co-occurrence of soil microbial communities in abandoned sites of a rare earth elements mine. Environ Sci Technol 50:11481–11490. https://doi.org/10.1021/acs.est.6b02284
Chen FJ, Cao YL, Jia DZ (2013) A room-temperature solid-state route for the synthesis of graphene oxide–metal sulfide composites with excellent photocatalytic activity. CrystEngComm 15:4747–4754. https://doi.org/10.1039/C3CE40079D
Chen D et al (2016) Micro–nanocomposites in environmental management. Adv Mater 28:10443–10458. https://doi.org/10.1002/adma.201601486
Chen M et al (2017) FeOOH-loaded MnO2 nano-composite: an efficient emergency material for thallium pollution incident. J Environ Manage 192:31–38. https://doi.org/10.1016/j.jenvman.2017.01.038
Crini G, Lichtfouse E, Wilson LD, Morin-Crini N (2019) Conventional and non-conventional adsorbents for wastewater treatment. Environ Chem Lett 17:195–213. https://doi.org/10.1007/s10311-018-0786-8
Dev A, Srivastava AK, Karmakar S (2018) Nanomaterial toxicity for plants. Environ Chem Lett 16:85–100. https://doi.org/10.1007/s10311-017-0667-6
Dutta T, Kim KH, Uchimiya M, Kwon EE, Jeon BH, Deep A, Yun ST (2016) Global demand for rare earth resources and strategies for green mining. Environ Res 150:182–190. https://doi.org/10.1016/j.envres.2016.05.052
Hernandez-Adame L et al (2017) Toxicity evaluation of high-fluorescent rare-earth metal nanoparticles for bioimaging applications. J Biomed Mater Res B Appl Biomater 105:605–615. https://doi.org/10.1002/jbm.b.33577
Hummers WS Jr, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339–1339. https://doi.org/10.1021/ja01539a017
Jia K et al (2008) Adsorption of Pb2+, Zn2+, and Cd2+ from waters by amorphous titanium phosphate. J Colloid Interf Sci 318:160–166. https://doi.org/10.1016/j.jcis.2007.10.043
Jowitt SM, Werner TT, Weng Z, Mudd GM (2018) Recycling of the rare earth elements. Curr Opin Green Sustain Chem 13:1–7. https://doi.org/10.1016/j.cogsc.2018.02.008
Kang JG, Gwag JS, Sohn Y (2015) Synthesis and characterization of Dy(OH)3 and Dy2O3 nanorods and nanosheets. Ceram Int 41:3999–4006. https://doi.org/10.1016/j.ceramint.2014.11.085
Kawahara M, Morita J, Rikukawa M, Sanui K, Ogata N (2000) Synthesis and proton conductivity of thermally stable polymer electrolyte: poly(benzimidazole) complexes with strong acid molecules. Electrochim Acta 45:1395–1398. https://doi.org/10.1016/S0013-4686(99)00349-7
Kim HN, Keller SW, Mallouk TE, Schmitt J, Decher G (1997) Characterization of zirconium phosphate/polycation thin films grown by sequential adsorption reactions. Chem Mater 9:1414–1421. https://doi.org/10.1021/cm970027q
Koochaki-Mohammadpour SMA, Torab-Mostaedi M, Talebizadeh-Rafsanjani A, Naderi-Behdani F (2014) Adsorption isotherm, kinetic, thermodynamic, and desorption studies of lanthanum and dysprosium on oxidized multiwalled carbon nanotubes. J Dispers Sci Technol 35:244–254. https://doi.org/10.1080/01932691.2013.785361
Lee Y, Yu K, Ravi S, Ahn W (2018) Selective adsorption of rare earth elements over functionalized Cr-MIL-101. ACS Appl Mater Inter 10:23918–23927. https://doi.org/10.1021/acsami.8b07130
Li C, Huang Y, Lin Z (2014) Fabrication of titanium phosphate@ graphene oxide nanocomposite and its super performance on Eu3+ recycling. J Mater Chem a 2:14979–14985. https://doi.org/10.1039/C4TA02983F
Li Y, Tian C, Liu W, Xu S, Xu Y, Cui R, Lin Z (2018) Carbon cloth supported nano-Mg(OH)2 for the enrichment and recovery of rare earth element Eu(III) from aqueous solution. Front Chem 6:118. https://doi.org/10.3389/fchem.2018.00118
Lin KA, Chang HA (2015) A zeolitic imidazole framework (ZIF)–sponge composite prepared via a surfactant-assisted dip-coating method. J Mater Chem A 3:20060–20064. https://doi.org/10.1039/C5TA04427H
Liu S, Xu Q, Latthe SS, Gurav AB, Xing R (2015a) Superhydrophobic/superoleophilic magnetic polyurethane sponge for oil/water separation. RSC Adv 5:68293–68298. https://doi.org/10.1039/C5RA12301A
Liu WS, Liu C, Wang ZW, Teng WK, Tang YT, Qiu RL (2015b) Limiting factors for restoration of dumping sites of ionic rare earth mine tailings. Acta Pedofil Sin 52:179–187
Liu W, Weng C, Zheng J, Peng X, Zhang J, Lin Z (2019) Emerging investigator series: treatment and recycling of heavy metals from nanosludge. Environ Sci Nano 6:1657–1673. https://doi.org/10.1039/C9EN00120D
Lo PH, Tsai WT, Lee JT, Hung MP (1994) Role of phosphorus in the electrochemical behavior of electroless Ni–P alloys in 3.5 wt.% NaCl solutions. Surf Coat Technol 67:27–34. https://doi.org/10.1016/S0257-8972(05)80023-4
Madhura L, Singh S, Kanchi S, Sabela M, Bisetty K (2019) Nanotechnology-based water quality management for wastewater treatment. Environ Chem Lett 17:65–121. https://doi.org/10.1007/s10311-018-0778-8
Madima N, Mishra SB, Inamuddin I, Mishra AK (2020) Carbon-based nanomaterials for remediation of organic and inorganic pollutants from wastewater. A review. Environ Chem Lett 18:1169–1191. https://doi.org/10.1007/s10311-020-01001-0
Mao X, Wang L, Wang C, Lichtfouse E (2018) Glutathione-functionalized melamine sponge, a mimic of a natural antidote, as a quick responsive adsorbent for efficient removal of Hg(II) from aqueous solutions. Environ Chem Lett 16:1429–1434. https://doi.org/10.1007/s10311-018-0746-3
McAllister MJ et al (2007) Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem Mater 19:4396–4404. https://doi.org/10.1021/cm0630800
Montes-Navajas P, Asenjo NG, Santamaría R, Menendez R, Corma A, García H (2013) Surface area measurement of graphene oxide in aqueous solutions. Langmuir 29:13443–13448. https://doi.org/10.1021/la4029904
Moulder JF, Stickle WF, Sobol PE, Bomben KD (1992) Handbook of X-Ray photoelectron spectroscopy, physical electronics division, Perkin Elmer Corp, Eden Prairie, MN
Ning G, Fan Z, Wang G, Gao J, Qian W, Wei F (2011) Gram-scale synthesis of nanomesh graphene with high surface area and its application in supercapacitor electrodes. Chem Commun 47:5976–5978. https://doi.org/10.1039/C1CC11159K
Nodeh HR, Ibrahim WAW, Ali I, Sanagi MM (2016) Development of magnetic graphene oxide adsorbent for the removal and preconcentration of As(III) and As(V) species from environmental water samples. Environ Sci Pollut Res 23:9759–9773. https://doi.org/10.1007/s11356-016-6137-z
Padalia BD, Lang WC, Norris PR, Watson LM, Fabian DJ (1977) X-ray photoelectron core-level studies of the heavy rare-earth metals and their oxides. Proc R Soc Lond A 354:269–290. https://doi.org/10.1098/rspa.1977.0067
Peng M et al (2019) PCN-224/rGO nanocomposite based photoelectrochemical sensor with intrinsic recognition ability for efficient p-arsanilic acid detection. Environ Sci Nano 6:207–215. https://doi.org/10.1039/C8EN00913A
Qin B et al (2019) Vacuum pyrolysis method for reclamation of rare earth elements from hyperaccumulator Dicranopteris dichotoma grown in contaminated soil. J Clean Prod 229:480–488. https://doi.org/10.1016/j.jclepro.2019.05.031
Qiu R et al (2020) Recovering full metallic resources from waste printed circuit boards: a refined review. J Clean Prod 244:118690. https://doi.org/10.1016/j.jclepro.2019.118690
Song Y, Li J, Li Y, Xu Y, Tian C, Weng C, Liu W (2019) Enrichment and recovery of low-concentration REEs from water using synthesized eco-friendly sodium alginate/nano-Mg(OH)2 composite beads. Surf Interfaces 15:232–238. https://doi.org/10.1016/j.surfin.2019.03.004
Tesh SJ, Scott TB (2014) Nano-composites for water remediation: a review. Adv Mater 26:6056–6068. https://doi.org/10.1002/adma.201401376
Tian C, Zhao J, Zhang J, Chu S, Dang Z, Lin Z, Xing B (2017) Enhanced removal of roxarsone by Fe3O4@3D graphene nanocomposites: synergistic adsorption and mechanism. Environ Sci Nano 4:2134–2143. https://doi.org/10.1039/C7EN00758B
Varshney KG, Pandith AH, Gupta U (1998) Synthesis and characterization of zirconium aluminophosphate. A new cation exchanger. Langmuir 14:7353–7358. https://doi.org/10.1021/la970464j
Yang XJ, Lin A, Li X, Wu Y, Zhou W, Chen Z (2013) China's ion-adsorption rare earth resources, mining consequences and preservation. Environ Dev 8:131–136. https://doi.org/10.1016/j.envdev.2013.03.006
Yu Q, Wu P, Xu P, Li L, Liu T, Zhao L (2008) Synthesis of cellulose/titanium dioxide hybrids in supercritical carbon dioxide. Green Chem 10:1061–1067. https://doi.org/10.1039/B806094K
Zaimes GG, Hubler BJ, Wang S, Khanna V (2015) Environmental life cycle perspective on rare earth oxide production. ACS Sustain Chem Eng 3:237–244. https://doi.org/10.1021/sc500573b
Zhang W, Koivula R, Wiikinkoski E, Xu J, Hietala S, Lehto J, Harjula R (2017) Efficient and selective recovery of trace scandium by inorganic titanium phosphate ion-exchangers from leachates of waste bauxite residue. ACS Sustain Chem Eng 5:3103–3114. https://doi.org/10.1021/acssuschemeng.6b02870
Zhao X, Lv L, Pan B, Zhang W, Zhang S, Zhang Q (2011) Polymer-supported nanocomposites for environmental application: a review. Chem Eng J 170:381–394. https://doi.org/10.1016/j.cej.2011.02.071
Zhao L et al (2015) TiO2-graphene sponge for the removal of tetracycline. J Nanopart Res 17:16. https://doi.org/10.1007/s11051-014-2825-0
Zhou S, Hao G, Zhou X, Jiang W, Wang T, Zhang N, Yu L (2016) One-pot synthesis of robust superhydrophobic, functionalized graphene/polyurethane sponge for effective continuous oil–water separation. Chem Eng J 302:155–162. https://doi.org/10.1016/j.cej.2016.05.051
Zhou X, Liu W, Tian C, Mo S, Liu X, Deng H, Lin Z (2018) Mussel-inspired functionalization of biological calcium carbonate for improving Eu(III) adsorption and the related mechanisms. Chem Eng J 351:816–824. https://doi.org/10.1016/j.cej.2018.06.142
Zhu Q, Chu Y, Wang Z, Chen N, Lin L, Liu F, Pan Q (2013) Robust superhydrophobic polyurethane sponge as a highly reusable oil-absorption material. J Mater Chem A 1:5386–5393. https://doi.org/10.1039/C3TA00125C
Acknowledgements
The authors would like to express thanks to the support by the National Key Research and Development Program of China (No. 2019YFA0210400), the Guangdong Innovative and Entrepreneurial Research Team Program (No. 2016ZT06N569), the Guangdong Science and Technology Program (No. 2020B121201003), the Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program (No. 2019TQ05L153) and the Guangzhou Science and Technology Project (No. 201804010189).
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Peng, X., Mo, S., Li, R. et al. Effective removal of the rare earth element dysprosium from wastewater with polyurethane sponge-supported graphene oxide–titanium phosphate. Environ Chem Lett 19, 719–728 (2021). https://doi.org/10.1007/s10311-020-01073-y
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DOI: https://doi.org/10.1007/s10311-020-01073-y