Abstract
The process of disposing discarded tyre is considered as a significant environmental and economic concern. As a result, many recycling technologies have been investigated to account for their re–use. Pyrolysis is considered to be most hopeful of all these methods. Pyrolysis is the process of a waste tyre being thermally degraded at a high temperature. The value–added products of the pyrolysis process include tyre pyrolysis oil (TPO), pyrochar, and pyrogas etc. TPO corresponds to an alternative fuel for engines as well as a starting material for producing of benzene, toluene, xylene, and limonene. In process of producing carbon nanotubes (CNTs), TPO is used as a precursor. Transformation of porous carbon structure from pyrochar is utilized for absorption and energy storage in batteries and supercapacitors. Pyrogas acts as a source of hydrogen and also may be utilized as an industrial fuel. Pyrolysis may be used to turn the waste tyre into useful materials in this fashion. In this review, we collectively addressed the recent developments of the waste tyre disposal and their by–products.
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References
Karthikeyan S, Sathiskumar C, Moorthy RS (2012) Effect of process parameters on tire pyrolysis: a review. J Sci Ind Res 71:309–315
Alsaleh A, Sattler ML (2014) Waste tire pyrolysis: influential parameters and product properties. Curr Sustain Renew Energy Rep 1(4):129–135
Cunliffe AM, Williams PT (1998) Composition of oils derived from the batch pyrolysis of tyres. J Anal Appl Pyrol 44(2):131–152
Ramarad S, Khalid M, Ratnam CT, Chuah AL, Rashmi W (2015) Waste tire rubber in polymer blends: a review on the evolution, properties and future. Prog Mater Sci 72:100–140
Oikonomou N, Mavridou S (2009) The use of waste tyre rubber in civil engineering works. Sustainability of construction materials. Wood, head publishing, Elsevier, New York, pp 213–238
Rowhani A, Rainey TJ (2016) Scrap tyre management pathways and their use as a fuel—a review. Energies 9(11):888
Williams PT, Bottrill RP (1995) Sulfur–polycyclic aromatic hydrocarbons in tyre pyrolysis oil. Fuel 74(5):736–742
Murugan S, Ramaswamy MC, Nagarajan G (2008) The use of tyre pyrolysis oil in diesel engines. Waste Manage 28(12):2743–2749
Li L, Liu S, Zhu T (2010) Application of activated carbon derived from scrap tires for adsorption of Rhodamine B. J Environ Sci 22(8):1273–1280
Liu Z, Yu Q, Zhao Y, He R, Xu M, Feng S, Li S, Zhou L, Mai L (2019) Silicon oxides: a promising family of anode materials for lithium–ion batteries. Chem Soc Rev 48(1):285–309
Fazli A, Rodrigue D (2020) Recycling waste tires into ground tire rubber (GTR)/rubber compounds: a review. J. Compos. Sci. 4(3):103
Medina NF, Garcia R, Hajirasouliha I, Pilakoutas K, Guadagnini M, Raffoul S (2018) Composites with recycled rubber aggregates: properties and opportunities in construction. Constr Build Mater 188:884–897. https://doi.org/10.1016/j.conbuildmat.2018.08.069
Ramarad S, Khalid M, Ratnam C, Chuah AL, Rashmi W (2015) Waste tire rubber in polymer blends: a review on the evolution, properties and future. Prog Chem Org Nat Prod Mater Sci 72:100–140
Akiba M, Hashim AS (1997) Vulcanization and crosslinking in elastomers. Prog Chem Org Nat Prod Polym Sci. 22(3):475–521. https://doi.org/10.1016/S0079-6700(96)00015-9
Wang Z, Burra KG, Lei T et al (2019) Co–gasification characteristics of waste tire and pine bark mixtures in CO2 atmosphere. Fuel 257:116025
Quek A, Balasubramanian R (2012) Mathematical modeling of rubber tire pyrolysis. J Anal Appl Pyrolysis 95:1–13
Williams PT, Besler S (1995) Pyrolysis–thermogravimetric analysis of tyres and tyre components. Fuel 74(9):1277–1283
Bhowmick AK, Rampalli S et al (1987) J Appl Polym Sci 33:1125
Macaione DP, Sacher RE, Singler RE, Earnest CM (1988) Compositional analysis by thermogravimetry. American Society for Testing and Materials, Philadelphia
Danon B, de Villiers A, Gorgens JF (2015) Elucidation of the different devolatilisation zones of tyre rubber pyrolysis using TGA–MS. Thermochim Acta 614:59–61
Xu FF, Wang B, Yang D et al (2018) TG–FTIR and Py–GC/MS study on pyrolysis mechanism and products distribution of waste bicycle tire. Energy Convers Manage 175:288–297
Li SQ, Yao Q, Chi Y et al (2004) Pilot–scale pyrolysis of scrap tires in a continuous rotary kiln reactor. Ind Eng Chem Res 43:5133–5145
Aylon E, Callen MS, Lopez JM et al (2005) Assessment of tire devolatilization kinetics. J Anal Appl Pyrolysis 74:259–264
Slopiecka K, Bartocci P, Fantozzi F (2012) Thermogravimetric analysis and kinetic study of poplar wood pyrolysis. Appl Energy 97:491–497
Jain AA, Mehra A, Ranade VV (2016) Processing of TGA data: analysis of isoconversional and model fitting methods. Fuel 165:490–498
Chen JH, Chen KS, Tong LY (2001) On the pyrolysis kinetics of scrap automotive tires. J Hazard Mater 84:43–55
Qu W, Zhou Q, Wang YZ, Zhang J, Lan WW, Wu YH, Yang JW, Wang DZ (2006) Pyrolysis of waste tire on ZSM–5 zeolite with enhanced catalytic activities. Polym Degrad Stab 91(10):2389–2395
Murillo R, Aylón E, Navarro MV, Callén MS, Aranda A, Mastral AM (2006) The application of thermal processes to valorise waste tyre. Fuel Process Technol 87(2):143–147
Gnanaraj JS, Lee RJ, Levine AM, Wistrom JL, Wistrom SL, Li Y, Li J, Akato K, Naskar AK, Paranthaman MP (2018) Sustainable waste tire derived carbon material as a potential anode for lithium–ion batteries. Sustainability 10(8):2840
Dong Y et al (2021) Life cycle assessment of vehicle tires: a systematic review. Clean Environ Syst. 2:100033
Sun X, Liu JR, Hong JL, Lu B (2016) Life cycle assessment of Chinese radial passenger vehicle tire. Int J Life Cycle Assess 21(12):1749–1758
Feraldi R, Cashman S, Huff M, Raahauge L (2013) Comparative LCA of treatment options for US scrap tires: material recycling and tire–derived fuel combustion. Int J Life Cycle Assess 18(3):613–625
Corti A, Lombardi L (2004) End life tyres: alternative final disposal processes compared by LCA. Energy 29(12):2089–2108
Banar M (2015) Life cycle assessment of waste tire pyrolysis. Fresenius Environ Bull 24(4):1215–1226
Bockstal L, Berchem T, Schmetz Q, Richel A (2019) Devulcanisation and reclaiming of tires and rubber by physical and chemical processes: a review. J Clean Prod 236:117574
Singh S, Nimmo W, Gibbs BM, Williams PT (2009) Waste tyre rubber as a secondary fuel for power plants. Fuel 88(12):2473–2480
Adhikari B, De D, Maiti S (2000) Reclamation and recycling of waste rubber. Prog Polym Sci 25(7):909–948
Kar Y (2011) Catalytic pyrolysis of car tire waste using expanded perlite. Waste Manage 31(8):1772–1782
Williams PT, Besler S, Taylor DT (1990) The pyrolysis of scrap automotive tyres: the influence of temperature and heating rate on product composition. Fuel 69(12):1474–1482
Banar M, Akyıldız V, Özkan A, Çokaygil Z, Onay Ö (2012) Characterization of pyrolytic oil obtained from pyrolysis of TDF (tire derived fuel). Energy Convers Manage 62:22–30
Roy C, Labrecque B, de Caumia B (1990) Recycling of scrap tires to oil and carbon black by vacuum pyrolysis. Resour Conserv Recycl 4(3):203–213
Li SQ, Yao Q, Chi Y, Yan JH, Cen KF (2004) Pilot–scale pyrolysis of scrap tires in a continuous rotary kiln reactor. Ind Eng Chem Res 43(17):5133–5145
Zabaniotou AA, Stavropoulos G (2003) Pyrolysis of used automobile tires and residual char utilization. J Anal Appl Pyrol 70(2):711–722
Shah J, Jan MR, Mabood F (2009) Recovery of value–added products from the catalytic pyrolysis of waste tyre. Energy Convers Manage 50(4):991–994
Dũng NA, Mhodmonthin A, Wongkasemjit S, Jitkarnka S (2009) Effects of ITQ–21 and ITQ–24 as zeolite additives on the oil products obtained from the catalytic pyrolysis of waste tire. J Anal Appl Pyrol 85(1–2):338–344
Dũng NA, Tanglumlert W, Wongkasemjit S, Jitkarnka S (2010) Roles of ruthenium on catalytic pyrolysis of waste tire and the changes of its activity upon the rate of calcination. J Anal Appl Pyrol 87(2):256–262
İlkılıç C, Aydın H (2011) Fuel production from waste vehicle tires by catalytic pyrolysis and its application in a diesel engine. Fuel Process Technol 92(5):1129–1135
Williams PT, Brindle AJ (2003) Aromatic chemicals from the catalytic pyrolysis of scrap tyres. J Anal Appl Pyrol 67(1):143–164
Abdul-Raouf ME, Maysour NE, Abdul-Azim AAA, Amin MS (2010) Thermochemical recycling of mixture of scrap tyres and waste lubricating oil into high caloric value products. Energy Convers Manage 51(6):1304–1310
Boxiong S, Chunfei W, Cai L, Binbin G, Rui W (2007) Pyrolysis of waste tyres: the influence of USY catalyst/tyre ratio on products. J Anal Appl Pyrol 78(2):243–249
San Miguel G, Aguado J, Serrano DP, Escola JM (2006) Thermal and catalytic conversion of used tyre rubber and its polymeric constituents using Py–GC/MS. Appl Catal B 64(3–4):209–219
Saeng-Arayakul P, Jitkarnka S (2013) An attempt on using a regenerated commercial nimos/Al2O3 as a catalyst for waste tyre pyrolysis. Chem Eng Trans 35:1339–1344
Bockstal L, Berchem T, Schmetz Q, Richel A (2019) Devulcanisation and reclaiming of tires and rubber by physical and chemical processes: a review. J Clean Prod 236:117574. https://doi.org/10.1016/j.jclepro.2019.07.049
Karger-Kocsis J, Meszaros L, Barany T (2013) Ground tyre rubber (GTR) in thermoplastics, thermosets, and rubbers. J Mater Sci 48(1):1–38. https://doi.org/10.1007/s10853-012-6564-2
van Beukering PJH, Janssen MA (2001) Trade and recycling of used tyres in Western and Eastern Europe. Resour Conserv Recycl 33(4):235–265
Sunthonpagasit N, Duffey MR (2004) Scrap tires to crumb rubber: feasibility analysis for processing facilities. Resour Conserv Recycl 40(4):281–299
Asaro L, Gratton M, Seghar S, Aït Hocine N (2018) Recycling of rubber wastes by devulcanization. Resour Conserv Recycl 133:250–262. https://doi.org/10.1016/j.resconrec.2018.02.016
Wu IF, Liao YC (2021) A chemical milling process to produce water–based inkjet printing ink from waste tire carbon blacks. Waste Manage 122:64–70
Chaala A, Roy C, AitKadi A (1996) Rheological properties of bitumen modified with pyrolytic carbon black. Fuel 75:1575–1583
Feng Z, Zhao P, Li X et al (2021) Preparation and properties of bitumen modified with waste rubber pyrolytic carbon black. Constr Build Mater 282:122697
Miandad R, Barakat MA, Rehan M, Aburiazaiza AS, Gardy J, Nizami AS (2018) Effect of advanced catalysts on tire waste pyrolysis oil. Process Saf Environ Prot 116:542–552
Bunthid D, Prasassarakich P, Hinchiranan N (2010) Oxidative desulfurization of tire pyrolysis naphtha in formic acid/H2O2/pyrolysis char system. Fuel 89(9):2617–2622
Islam MN, Nahian MR (2016) Improvement of waste tire pyrolysis oil and performance test with diesel in CI engine. J Renew Energy 8:5137247
Verma P, Zare A, Jafari M, Bodisco TA, Rainey T, Ristovski ZD, Brown RJ (2018) Diesel engine performance and emissions with fuels derived from waste tyres. Sci Rep 8(1):1–13
Kim HM, Kim K, Lee CY, Joo J, Cho SJ, Yoon HS, Pejaković DA, Yoo JW, Epstein AJ (2004) Electrical conductivity and electromagnetic interference shielding of multiwalled carbon nanotube composites containing Fe catalyst. Appl Phys Lett 84(4):589–591
Parasuram B, Sundaram S, Sathiskumar C, Karthikeyan S (2018) Synthesis of multi–walled carbon nanotubes using tire pyrolysis oil as a carbon precursor by spray pyrolysis method. Inorg Nano-Metal Chem 48(2):103–106
Sathiskumar C, Karthikeyan S (2012) Synthesis of one dimensional carbon nanofibers from tire pyrolysis oil. J Environ Nanotechnol 1(1):46–49
Li X, Kang F, Bai X, Shen W (2007) A novel network composite cathode of LiFePO4/multiwalled carbon nanotubes with high rate capability for lithium ion batteries. Electrochem Commun 9(4):663–666
Zhang Y, Williams PT (2016) Carbon nanotubes and hydrogen production from the pyrolysis catalysis or catalytic–steam reforming of waste tyres. J Anal Appl Pyrol 122:490–501
Zhang Y, Wu C, Nahil MA, Williams P (2015) Pyrolysis–catalytic reforming/gasification of waste tires for production of carbon nanotubes and hydrogen. Energy Fuels 29(5):3328–3334
Pan T, Nguyen TA, Shi XM (2008) Assessment of electrical injection of corrosion inhibitor for corrosion protection of reinforced concrete. Transp Res Rec 2044:51–60
Li Y-H, Chang F-M, Huang B et al (2020) Activated carbon preparation from pyrolysis char of sewage sludge and its adsorption performance for organic compounds in sewage. Fuel 266:117053
Quek A, Balasubramanian R (2011) Preparation and characterization of low energy postpyrolysis oxygenated tire char. Chem Eng J 170:194–201
Guerrero-Esparza MM, Medina-Valtierra J, Carrasco-Marin F (2017) Chars from waste tire rubber by catalytic pyrolysis and the statistical analysis of the adsorption of Fe in potable water. Environ Prog Sustain Energy 36:1794–1801
Acosta R, Fierro V, de Yuso AM et al (2016) Tetracycline adsorption onto activated carbons produced by KOH activation of tyre pyrolysis char. Chemosphere 149:168–176
Shilpa KR, Sharma A (2018) Morphologically tailored activated carbon derived from waste tires as high–performance anode for Li–ion battery. J Appl Electrochem 48:1–13
Zhi MJ, Yang F, Meng FK et al (2014) Effects of pore structure on performance of an activated–carbon supercapacitor electrode recycled from scrap waste tires. ACS Sustain Chem Eng 2:1592–1598
Li YC, Paranthaman MP, Akato K et al (2016) Tire–derived carbon composite anodes for sodium–ion batteries. J Power Sources 316:232–238
Naskar AK, Bi ZH, Li YC et al (2014) Tailored recovery of carbons from waste tires for enhanced performance as anodes in lithium–ion batteries. RSC Adv 4:38213–38221
Formela K (2022) Waste tire rubber–based materials: processing, performance properties and development strategies. Adv Ind Eng Polym Res. https://doi.org/10.1016/j.aiepr.2022.06.003
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SS: Wrote main article; RN & YHR: reviewed the article; RN: reviewed the article and supervised the work.
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Sathish, S., Nirmala, R., Ra, Y. et al. Factors influencing the pyrolysis products of waste tyres and its practical applications: a mini topical review. J Mater Cycles Waste Manag 25, 3117–3131 (2023). https://doi.org/10.1007/s10163-023-01758-w
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DOI: https://doi.org/10.1007/s10163-023-01758-w